Stretchable Metamaterials with Tunable Infrared Emissivity for Dynamic Thermal Management

• Published in: ACS applied materials & interfaces Vol. 16; no. 36; pp. 47639 - 47645
• Main Authors: Li, Zhaoran, Long, Linshuang, Tang, Zhipeng, Chen, Xiaopeng, Huang, Zizhen, Ren, Yuan, Liu, Yuchi, Ye, Hong
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 11-09-2024
• Subjects: Energy, Environmental, and Catalysis Applications; dynamic modulation; plasmon resonance; stretchable; thermal management; infrared emissivity
• ISSN: 1944-8244; 1944-8252; 1944-8252
• DOI: 10.1021/acsami.4c09758

Manipulation of infrared emissivity, which is closely related to surface structure and optical parameters of materials, is a crucial approach for realizing dynamic thermal management. In this study, we design a metamaterial consisting of an array of aluminum disks embedded on a surface of a stretchable elastomeric substrate. Mechanical stretching-induced deformation allows dynamic modification of the surface structure and equivalent optical parameters, thus enabling dynamic control of the emissivity. By utilizing the elastomer polydimethylsiloxane (PDMS) as the substrate, the microstructure interdisk gap can be altered by stretching the PDMS. Through theoretical calculations, the plausibility of this approach is explained by the excitation of plasmon resonance and the variation in the exposed area of highly absorbent PDMS, and the optimal structures for tuning the infrared emissivity are revealed to be 6 μm in diameter and 100 nm in height. Based on this design, we prepare samples with periods of 7 and 7.9 μm and experimentally demonstrate that a change in the period can cause a change in the emissivity and thus tunability in thermal control performance. The temperature difference between the two samples reaches 44.1 °C at a heating power of 0.28 W/cm2 for both samples. Furthermore, we construct a stretching platform that enables in situ mechanical stretching to realize dynamic changes in emissivity. The integral infrared emissivity of the sample increases from 0.32 to 0.5 at a biaxial tensile strain of 13%, achieving a 56% modulation rate of the integral infrared emissivity. The material is expected to enable dynamic thermal management.