Dynamics of CO2 Absorption and Desorption Processes in Alkanolamine with Cosolvent Polyethylene Glycol

• Published in: Industrial & engineering chemistry research Vol. 51; no. 37; pp. 12081 - 12088
• Main Authors: Li, Jun, You, Chenjia, Chen, Lifang, Ye, Yinmei, Qi, Zhiwen, Sundmacher, Kai
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 19-09-2012
• Subjects: Absorption, stripping; Applied sciences; Chemical engineering; Exact sciences and technology; Gas absorption; Cosolvent; Desorption; Carbon dioxide
• ISSN: 0888-5885; 1520-5045
• DOI: 10.1021/ie301164v

To reduce the high energy consumption and equipment corrosion in conventional processes of CO2 capture with aqueous amine solutions, the mixed nonaqueous solvents of monoethanolamine (MEA), diethanolamine (DEA), and diglycolamine (DGA) with polyethylene glycol (PEG) as cosolvent were explored for CO2 capture. The dynamic experiments of CO2 absorption and desorption were carried out to evaluate the performance of the studied nonaqueous solutions. It demonstrated that the mixed solutions of amines and PEG exhibited higher CO2 cyclic capacity and regeneration efficiency compared with the only aqueous amine solutions. Especially, the solution of 3 mol/L DGA-PEG200 exhibits a high cyclic capacity of 0.438 mol CO2/mol DGA and a high regeneration efficiency of 94.6%, which indicates its great potential in industrial application. Moreover, the very low vapor pressure of PEG helps the mixed solution for CO2 capture with reduced corrosion, energy consumption, and environmental pollution.