高Zn含量Al-Zn-Mg-Cu合金中应力腐蚀开裂、晶界微化学成分及Zn含量之间的关系

通过应力腐蚀开裂测试、晶间腐蚀测试实验结合扫描电镜以及高角度环形暗场像扫描透射电镜观测,研究Al-Zn-Mg-Cu合金中腐蚀行为、晶界中微化学成分以及合金Zn含量之间的关系.结果表明,高Zn含量Al-Zn-Mg-Cu合金抗拉强度的提高主要归因于基体中形成的高密度纳米析出相.含11.0%Zn合金比含7.9%Zn(质量分数)合金的应力腐蚀平台速率高大约一个数量级,其主要原因是形成高Zn含量的晶界析出相和较宽的无沉淀析出带.基于合金的腐蚀断裂形貌、晶界微化学成分以及电化学性能,讨论不同Zn含量合金的应力腐蚀开裂机制....

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Published in:中国有色金属学报(英文版) Vol. 31; no. 8; pp. 2220 - 2231
Main Authors: 袁丁玲, 陈送义, 陈康华, 黄兰萍, 昌江郁, 周亮, 丁云峰
Format: Journal Article
Language:Chinese
Published: 中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083%中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083 2021
中南大学 轻合金研究院,长沙 410083
中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083
中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083%中南大学 轻合金研究院,长沙 410083
中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083
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Abstract 通过应力腐蚀开裂测试、晶间腐蚀测试实验结合扫描电镜以及高角度环形暗场像扫描透射电镜观测,研究Al-Zn-Mg-Cu合金中腐蚀行为、晶界中微化学成分以及合金Zn含量之间的关系.结果表明,高Zn含量Al-Zn-Mg-Cu合金抗拉强度的提高主要归因于基体中形成的高密度纳米析出相.含11.0%Zn合金比含7.9%Zn(质量分数)合金的应力腐蚀平台速率高大约一个数量级,其主要原因是形成高Zn含量的晶界析出相和较宽的无沉淀析出带.基于合金的腐蚀断裂形貌、晶界微化学成分以及电化学性能,讨论不同Zn含量合金的应力腐蚀开裂机制.
AbstractList 通过应力腐蚀开裂测试、晶间腐蚀测试实验结合扫描电镜以及高角度环形暗场像扫描透射电镜观测,研究Al-Zn-Mg-Cu合金中腐蚀行为、晶界中微化学成分以及合金Zn含量之间的关系.结果表明,高Zn含量Al-Zn-Mg-Cu合金抗拉强度的提高主要归因于基体中形成的高密度纳米析出相.含11.0%Zn合金比含7.9%Zn(质量分数)合金的应力腐蚀平台速率高大约一个数量级,其主要原因是形成高Zn含量的晶界析出相和较宽的无沉淀析出带.基于合金的腐蚀断裂形貌、晶界微化学成分以及电化学性能,讨论不同Zn含量合金的应力腐蚀开裂机制.
Abstract_FL The correlations among the corrosion behaviour, grain-boundary microchemistry, and Zn content in Al-Zn-Mg-Cu alloys were studied using stress corrosion cracking (SCC) and intergranular corrosion (IGC) tests, combined with scanning electron microscopy (SEM) and high-angle angular dark field scanning transmission electron microscopy (HAADF-STEM) microstructural examinations. The results showed that the tensile strength enhancement of high Zn-containing Al-Zn-Mg-Cu alloys was mainly attributed to the high density nano-scale matrix precipitates. The SCC plateau velocity for the alloy with 11.0 wt.% Zn was about an order of magnitude greater than that of the alloy with 7.9 wt.% Zn, which was mainly associated with Zn enrichment in grain boundary precipitates and wide precipitates-free zones. The SCC mechanisms of different Zn-containing alloys were discussed based on fracture features, grain-boundary microchemistry, and electrochemical properties.
Author 陈康华
昌江郁
陈送义
袁丁玲
周亮
丁云峰
黄兰萍
AuthorAffiliation 中南大学 轻合金研究院,长沙 410083;中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083%中南大学 轻合金研究院,长沙 410083;中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083;中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083%中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083;中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083
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Author_FL Yun-feng DING
Ding-ling YUAN
Jiang-yu CHANG
Lan-ping HUANG
Song-yi CHEN
Liang ZHOU
Kang-hua CHEN
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DocumentTitle_FL Correlations among stress corrosion cracking, grain-boundary microchemistry, and Zn content in high Zn-containing Al-Zn-Mg-Cu alloys
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  funderid: (The authors are grateful for the financial supports from the National Key Research and Development Program of China); (the State Key Laboratory of High Performance Complex Manufacturing of Central South University,China); (and the National Key Laboratory of Science and Technology for National Defence on High-strength Lightweight Structural Materials of China)
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Issue 8
Keywords Al-Zn-Mg-Cu合金
grain-boundary microchemistry
锌含量
Zn content
应力腐蚀开裂
stress corrosion cracking
晶界微化学成分
Al-Zn-Mg-Cu alloy
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PublicationTitle 中国有色金属学报(英文版)
PublicationTitle_FL Transactions of Nonferrous Metals Society of China
PublicationYear 2021
Publisher 中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083%中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083
中南大学 轻合金研究院,长沙 410083
中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083
中南大学 有色金属先进结构材料与制造协同创新中心,长沙 410083%中南大学 轻合金研究院,长沙 410083
中南大学 轻质高强结构材料国家级科技重点实验室,长沙 410083
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Title 高Zn含量Al-Zn-Mg-Cu合金中应力腐蚀开裂、晶界微化学成分及Zn含量之间的关系
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