Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands† †Electronic supplementary information (ESI) available: Synthetic procedures, crystallographic details, additional magnetic data, experimental details on EPR measurements. CCDC 1526314–1526340. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00135e

Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands† †Electronic supplementary information (ESI) available: Synthetic procedures, crystallographic details, additional magnetic data, experimental details on EPR measurements. CCDC 1526314–1526340. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00135e

Tetragonal lanthanide complexes of Pd and Pt metalloligands with tuneable geometries demonstrate how the electronic structure of lanthanide centres can be engineered. Exploitation of HSAB preferences allows for high-yield, one-pot syntheses of lanthanide complexes chelated by two Pd or Pt metallolig...

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Bibliographic Details
Published in:Chemical science (Cambridge) Vol. 8; no. 5; pp. 3566 - 3575
Main Authors: Sørensen, Mikkel A., Weihe, Høgni, Vinum, Morten G., Mortensen, Jesper S., Doerrer, Linda H., Bendix, Jesper
Format: Journal Article
Language:English
Published: Royal Society of Chemistry 28-02-2017
Subjects:
Chemistry
Online Access:Get full text
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