Tetrathiafulvalene-containing polymers for simultaneous non-covalent modification and electronic modulation of MoS2 nanomaterials† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc00305b

• Published in: Chemical science (Cambridge) Vol. 7; no. 7; pp. 4698 - 4705
• Main Authors: Selhorst, Ryan C., Puodziukynaite, Egle, Dewey, Jeffrey A., Wang, Peijian, Barnes, Michael D., Ramasubramaniam, Ashwin, Emrick, Todd
• Format: Journal Article
• Language: English
• Published: Royal Society of Chemistry 19-04-2016
• Subjects: Chemistry
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/c6sc00305b

Polymers with pendent tetrathiafulvalene groups for solubilization and electronic modification of MoS
2
nanosheets.
Transition metal dichalcogenides (TMDCs) such as MoS
2
comprise an important class of 2D semiconductors with numerous interesting electronic and mechanical features. Full utilization of TMDCs in materials and devices, however, necessitates robust functionalization methods. We report well-defined tetrathiafulvalene (TTF)-based polymers, exploiting synthetic routes that overcome challenges previously associated with these systems. These platforms enable basal plane coordinative interactions with MoS
2
, conceptually in parallel with pyrene-containing platforms for graphene and carbon nanotube modification. Not yet reported for TMDCs, these non-covalent interactions are universal and effective for MoS
2
irrespective of the lattice structure, affording significantly enhanced solution stabilization of the nanosheets. Additionally, the TTF-functionalized polymers offer electronic structure modulation of MoS
2
by ground state charge transfer and work function reduction, demonstrated using Kelvin probe force microscopy (KPFM). Notably, coordination and electronic effects are amplified for the TTF–polymers over TTF itself. Experiments are supported by first-principles density functional theory (DFT) calculations that probe polymer–TTF surface interactions with MoS
2
and the resultant impact on electronic properties.