Nucleophilic Iron Complexes in Proton‐Transfer Catalysis: AnIron‐Catalyzed Dimroth Cyclocondensation

The nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is an active catalyst in C−H‐amination but also in proton‐transfer catalysis. Herein, we describe the successful use of this complex as a proton‐transfer catalyst in the cyclocondensation reaction between azides and ketones to the correspondi...

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Bibliographic Details

Published in:	Chemistry, an Asian journal Vol. 14; no. 17; pp. 3003 - 3010
Main Authors:	Baykal, Aslihan, Zhang, Dihan, Knelles, Jakob, Alt, Isabel T, Plietker, Bernd
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 01-09-2019
Subjects:	Catalysis Catalysts Chemistry Coordination compounds Heterocyclic compounds Iron Ketones Protons Triazoles
Online Access:	Get full text
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