High-performance Hypoiodite/Hydrogen Peroxide Catalytic System for the Oxylactonization of Aliphatic [gamma]-Oxocarboxylic Acids

Highly efficient hypoiodite-catalyzed oxylactonization of aliphatic [gamma]-oxocarboxylic acids to the corresponding [gamma]-acyl-[gamma]-butyrolactones was developed. Highly dilute reaction conditions and slow addition of the oxidant are both highly effective for promoting the high-performance hypo...

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Published in:Chemistry letters Vol. 44; no. 3; p. 387
Main Authors: Uyanik, Muhammet, Suzuki, Daisuke, Watanabe, Mizu, Tanaka, Hiroyasu, Furukawa, Kikuo, Ishihara, Kazuaki
Format: Journal Article
Language:English
Published: Tokyo Chemical Society of Japan 01-03-2015
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Abstract Highly efficient hypoiodite-catalyzed oxylactonization of aliphatic [gamma]-oxocarboxylic acids to the corresponding [gamma]-acyl-[gamma]-butyrolactones was developed. Highly dilute reaction conditions and slow addition of the oxidant are both highly effective for promoting the high-performance hypoiodite/hydrogen peroxide catalytic oxidation system.
AbstractList Highly efficient hypoiodite-catalyzed oxylactonization of aliphatic [gamma]-oxocarboxylic acids to the corresponding [gamma]-acyl-[gamma]-butyrolactones was developed. Highly dilute reaction conditions and slow addition of the oxidant are both highly effective for promoting the high-performance hypoiodite/hydrogen peroxide catalytic oxidation system.
Author Furukawa, Kikuo
Ishihara, Kazuaki
Suzuki, Daisuke
Watanabe, Mizu
Tanaka, Hiroyasu
Uyanik, Muhammet
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  surname: Furukawa
  fullname: Furukawa, Kikuo
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  givenname: Kazuaki
  surname: Ishihara
  fullname: Ishihara, Kazuaki
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Snippet Highly efficient hypoiodite-catalyzed oxylactonization of aliphatic [gamma]-oxocarboxylic acids to the corresponding [gamma]-acyl-[gamma]-butyrolactones was...
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