Stereochemistry of base-catalyzed ring opening of 1,3,2-oxathiaphospholanes. Absolute configuration of 2-{N-[(Rc)-1-(α-naphthyl)ethyl]amino}-2-thiono-1,3,2-oxathio-phospholanes and O,S-dimethyl N-[(Rc)-1-(α-naphthyl)ethyl]phosphoramidothiolates

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Published in:	Journal of the American Chemical Society Vol. 114; no. 26; pp. 10197 - 10202
Main Authors:	UZNANSKI, B, GRAJKOWSKI, A, KRZYZANOWSKA, B, KAZMIERKOWSKA, A, STEC, W. J, WIECZOREK, M. W, BLASZCZYK, J
Format:	Journal Article
Language:	English
Published:	Washington, DC American Chemical Society 1992
Subjects:	Chemical reactivity Chemistry Exact sciences and technology Organic chemistry Reactivity and mechanisms Five membered ring Base catalysis Regioselectivity Molecular structure Experimental study X ray diffraction Phosphorus Organic compounds Ring cleavage Stereoselectivity Absolute configuration Oxygen sulfur phosphorus heterocycle Organic thioamidophosphate Crystalline structure
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Author	BLASZCZYK, J UZNANSKI, B STEC, W. J WIECZOREK, M. W KAZMIERKOWSKA, A KRZYZANOWSKA, B GRAJKOWSKI, A
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Keywords	Five membered ring Base catalysis Regioselectivity Molecular structure Experimental study X ray diffraction Phosphorus Organic compounds Ring cleavage Stereoselectivity Absolute configuration Oxygen sulfur phosphorus heterocycle Organic thioamidophosphate Crystalline structure
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SubjectTerms	Chemical reactivity Chemistry Exact sciences and technology Organic chemistry Reactivity and mechanisms
Title	Stereochemistry of base-catalyzed ring opening of 1,3,2-oxathiaphospholanes. Absolute configuration of 2-{N-[(Rc)-1-(α-naphthyl)ethyl]amino}-2-thiono-1,3,2-oxathio-phospholanes and O,S-dimethyl N-[(Rc)-1-(α-naphthyl)ethyl]phosphoramidothiolates
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