Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants

The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. We present a strategy that enables the fine-tuning of a specific combinat...

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Published in:Chemistry : a European journal Vol. 23; no. 13
Main Authors: Barroux, Hugo, Jiang, Tengfei, Paul, Camille, Massuyeau, Florian, Génois, Romain, Gordon, Elijah E., Whangbo, Myung-Hwan, Jobic, Stéphane, Gautier, Romain
Format: Journal Article
Language:English
Published: United States ChemPubSoc Europe 26-01-2017
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Abstract The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. We present a strategy that enables the fine-tuning of a specific combination of properties by controlling the reduction of dopants. The feasibility of this approach was demonstrated by optimizing the near-IR photoluminescence of strontium titanate SrTiO3:Ni for potential applications in biomedicine for a range of absorbance in the visible/near-IR region. We discussed how material properties, such as luminescence, conductivity, or photocatalytic properties can be designed by carefully controlling the ratio of dopants in different oxidation states.
AbstractList The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the properties are influenced simultaneously by this single parameter. We present a strategy that enables the fine-tuning of a specific combination of properties by controlling the reduction of dopants. The feasibility of this approach was demonstrated by optimizing the near-IR photoluminescence of strontium titanate SrTiO3:Ni for potential applications in biomedicine for a range of absorbance in the visible/near-IR region. We discussed how material properties, such as luminescence, conductivity, or photocatalytic properties can be designed by carefully controlling the ratio of dopants in different oxidation states.
Author Génois, Romain
Gordon, Elijah E.
Jobic, Stéphane
Massuyeau, Florian
Barroux, Hugo
Jiang, Tengfei
Whangbo, Myung-Hwan
Paul, Camille
Gautier, Romain
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  fullname: Barroux, Hugo
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  fullname: Jiang, Tengfei
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
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  fullname: Paul, Camille
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
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  fullname: Massuyeau, Florian
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
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  fullname: Génois, Romain
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
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  fullname: Gordon, Elijah E.
  organization: North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
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  fullname: Whangbo, Myung-Hwan
  organization: North Carolina State Univ., Raleigh, NC (United States). Dept. of Chemistry
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  fullname: Jobic, Stéphane
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
– sequence: 9
  fullname: Gautier, Romain
  organization: Centre National de la Recherche Scientifique (CNRS), Nantes Cedex (France)
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Snippet The physical properties of doped multifunctional compounds are commonly tuned by controlling the amount of dopants, but this control is limited because all the...
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SourceType Open Access Repository
SubjectTerms biomedicine
chemistry
dopants
luminescence
MATERIALS SCIENCE
multifunctional materials
visible/near-IR absorption
Title Fine-Tuning the Properties of Doped Multifunctional Materials by Controlled Reduction of Dopants
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