A discussion on the physics and chemistry of biological recognition - Water structure and hydration
Possible structures adopted by bulk water are discussed with special reference to the possible presence of monomeric water and the detection of ‘free’ -OH groups. The way in which water tends to accommodate small hydrophobic molecules is considered, with particular reference to the clathrate theory...
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| Published in: | Philosophical transactions of the Royal Society of London. Series B, Biological sciences Vol. 272; no. 915; pp. 13 - 28 |
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| Main Author: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
London
The Royal Society
06-11-1975
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| Online Access: | Get full text |
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| Abstract | Possible structures adopted by bulk water are discussed with special reference to the possible presence of monomeric water and the detection of ‘free’ -OH groups. The way in which water tends to accommodate small hydrophobic molecules is considered, with particular reference to the clathrate theory and the phenomenon of ‘structure making’. Cage-pairing and cage-sharing processes are described. Consideration of the way water solvates cations and anions is followed by a discussion of the way these solvated ions interact with the bulk medium. Large symmetrical alkylammonium ions probably encourage clathrate cage formation, at least at low temperatures. Particular reference is made to the use of infrared, Raman, ultraviolet, n.m.r. and e.s.r. spectroscopic techniques to the study of water and aqueous solutions. |
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| AbstractList | Possible structures adopted by bulk water are discussed with special reference to the possible presence of monomeric water and the detection of ‘free’ -OH groups. The way in which water tends to accommodate small hydrophobic molecules is considered, with particular reference to the clathrate theory and the phenomenon of ‘structure making’. Cage-pairing and cage-sharing processes are described. Consideration of the way water solvates cations and anions is followed by a discussion of the way these solvated ions interact with the bulk medium. Large symmetrical alkylammonium ions probably encourage clathrate cage formation, at least at low temperatures. Particular reference is made to the use of infrared, Raman, ultraviolet, n.m.r. and e.s.r. spectroscopic techniques to the study of water and aqueous solutions. |
| Author | Symons, Martyn Christian Raymond |
| Author_xml | – sequence: 1 givenname: Martyn Christian Raymond surname: Symons fullname: Symons, Martyn Christian Raymond organization: Department of Chemistry, The University, Leicester LE1 7RH |
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| DOI | 10.1098/rstb.1975.0067 |
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| EndPage | 28 |
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| Notes | ark:/67375/V84-73WVJGDQ-G This text was harvested from a scanned image of the original document using optical character recognition (OCR) software. As such, it may contain errors. Please contact the Royal Society if you find an error you would like to see corrected. Mathematical notations produced through Infty OCR. istex:AFF843A0CC01489E688EA9B1DFF06EA78C0397BF |
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| PublicationTitle | Philosophical transactions of the Royal Society of London. Series B, Biological sciences |
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| Snippet | Possible structures adopted by bulk water are discussed with special reference to the possible presence of monomeric water and the detection of ‘free’ -OH... |
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| Title | A discussion on the physics and chemistry of biological recognition - Water structure and hydration |
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