Poly[(μ 4 -decanedioato)cobalt(II)]
In the title compound, [Co(C 10 H 16 O 4 )] n , the Co II atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network co...
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| Published in: | Acta crystallographica. Section E, Structure reports online Vol. 70; no. 5; p. m159 |
|---|---|
| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
01-05-2014
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| Online Access: | Get full text |
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| Abstract | In the title compound, [Co(C
10
H
16
O
4
)]
n
, the Co
II
atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co
II
atoms, one with the Co
II
atoms lying parallel to (100) [Co...Co = 4.653 (1) Å], the other lying parallel to (010) [Co...Co = 4.764 (1) Å]. |
|---|---|
| AbstractList | In the title compound, [Co(C
10
H
16
O
4
)]
n
, the Co
II
atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging sebacate dications, comprising two separate half-ligands which lie across crystallographic inversion centres. In the three-dimensional network coordination polymer, there are two different spatial extensions of Co
II
atoms, one with the Co
II
atoms lying parallel to (100) [Co...Co = 4.653 (1) Å], the other lying parallel to (010) [Co...Co = 4.764 (1) Å]. |
| Author | Alessandro, Saccà Francesco, Nicolò Giovanni, Grassi Mollica Nardo, Viviana Giuseppe, Bruno |
| Author_xml | – sequence: 1 givenname: Bruno surname: Giuseppe fullname: Giuseppe, Bruno – sequence: 2 givenname: Nicolò surname: Francesco fullname: Francesco, Nicolò – sequence: 3 givenname: Grassi surname: Giovanni fullname: Giovanni, Grassi – sequence: 4 givenname: Saccà surname: Alessandro fullname: Alessandro, Saccà – sequence: 5 givenname: Viviana surname: Mollica Nardo fullname: Mollica Nardo, Viviana |
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| Cites_doi | 10.1016/S0010-8545(03)00021-3 10.1107/S1600536801000794 10.1021/cg015576u 10.1021/ja973738y 10.1107/S0108767307043930 10.1107/S1600536810005714 10.1021/ar00046a004 10.1021/cg800594m 10.1016/S0022-2860(03)00354-5 10.1107/S0108270104003427 10.1021/cg060329h |
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| PublicationTitle | Acta crystallographica. Section E, Structure reports online |
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| References | Desiraju (zs2284_bb6) 2003; 656 Thuéry (zs2284_bb13) 2008; 11 zs2284_bb5 Sheldrick (zs2284_bb12) 2008; 64 zs2284_bb9 Borkowski (zs2284_bb4) 2006; 10 Sarma (zs2284_bb10) 2002; 2 Biradha (zs2284_bb1) 1998; 120 Bond (zs2284_bb2) 2001; 57 Borkowski (zs2284_bb3) 2004; 60 Gavezzotti (zs2284_bb7) 1994; 27 Hosseini (zs2284_bb8) 2003; 240 zs2284_bb11 Zhou (zs2284_bb14) 2010; 66 |
| References_xml | – volume: 240 start-page: 157 year: 2003 ident: zs2284_bb8 publication-title: Coord. Chem. Rev. doi: 10.1016/S0010-8545(03)00021-3 contributor: fullname: Hosseini – ident: zs2284_bb9 – volume: 57 start-page: o141 year: 2001 ident: zs2284_bb2 publication-title: Acta Cryst. E doi: 10.1107/S1600536801000794 contributor: fullname: Bond – volume: 2 start-page: 93 year: 2002 ident: zs2284_bb10 publication-title: Cryst. Growth Des. doi: 10.1021/cg015576u contributor: fullname: Sarma – volume: 120 start-page: 11894 year: 1998 ident: zs2284_bb1 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja973738y contributor: fullname: Biradha – volume: 64 start-page: 112 year: 2008 ident: zs2284_bb12 publication-title: Acta Cryst. A doi: 10.1107/S0108767307043930 contributor: fullname: Sheldrick – volume: 66 start-page: m405 year: 2010 ident: zs2284_bb14 publication-title: Acta Cryst. E doi: 10.1107/S1600536810005714 contributor: fullname: Zhou – volume: 27 start-page: 309 year: 1994 ident: zs2284_bb7 publication-title: Acc. Chem. Res. doi: 10.1021/ar00046a004 contributor: fullname: Gavezzotti – volume: 11 start-page: 4132 year: 2008 ident: zs2284_bb13 publication-title: Cryst. Growth Des. doi: 10.1021/cg800594m contributor: fullname: Thuéry – volume: 656 start-page: 5 year: 2003 ident: zs2284_bb6 publication-title: J. Mol. Struct. doi: 10.1016/S0022-2860(03)00354-5 contributor: fullname: Desiraju – ident: zs2284_bb11 – volume: 60 start-page: m159 year: 2004 ident: zs2284_bb3 publication-title: Acta Cryst. C doi: 10.1107/S0108270104003427 contributor: fullname: Borkowski – volume: 10 start-page: 2241 year: 2006 ident: zs2284_bb4 publication-title: Cryst. Growth Des. doi: 10.1021/cg060329h contributor: fullname: Borkowski – ident: zs2284_bb5 |
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| Snippet | In the title compound, [Co(C
10
H
16
O
4
)]
n
, the Co
II
atom is bonded in a slightly distorted tetrahedral environment by four O atoms from the bridging... |
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| Title | Poly[(μ 4 -decanedioato)cobalt(II)] |
| Volume | 70 |
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