IP determination and 1+1 REMPI spectrum of SiO at 210-220 nm with implications for SiO$^{+}$ ion trap loading

Journal of Molecular Spectroscopy Volume 355, January 2019, Pages 40-45 The 1+1 REMPI spectrum of SiO in the 210-220 nm range is recorded. Observed bands are assigned to the $A-X$ vibrational bands $(v``=0-3, v`=5-10)$ and a tentative assignment is given to the 2-photon transition from $X$ to the n=...

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Main Authors: Stollenwerk, Patrick R, Antonov, Ivan O, Odom, Brian C
Format: Journal Article
Language:English
Published: 24-10-2017
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Abstract Journal of Molecular Spectroscopy Volume 355, January 2019, Pages 40-45 The 1+1 REMPI spectrum of SiO in the 210-220 nm range is recorded. Observed bands are assigned to the $A-X$ vibrational bands $(v``=0-3, v`=5-10)$ and a tentative assignment is given to the 2-photon transition from $X$ to the n=12-13 $[X^{2}{\Sigma}^{+},v^{+}=1]$ Rydberg states at 216-217 nm. We estimate the IP of SiO to be 11.59(1) eV. The SiO$^{+}$ cation has previously been identified as a molecular candidate amenable to laser control. Our work allows us to identify an efficient method for loading cold SiO$^{+}$ from an ablated sample of SiO into an ion trap via the $(5,0)$ $A-X$ band at 213.977 nm.
AbstractList Journal of Molecular Spectroscopy Volume 355, January 2019, Pages 40-45 The 1+1 REMPI spectrum of SiO in the 210-220 nm range is recorded. Observed bands are assigned to the $A-X$ vibrational bands $(v``=0-3, v`=5-10)$ and a tentative assignment is given to the 2-photon transition from $X$ to the n=12-13 $[X^{2}{\Sigma}^{+},v^{+}=1]$ Rydberg states at 216-217 nm. We estimate the IP of SiO to be 11.59(1) eV. The SiO$^{+}$ cation has previously been identified as a molecular candidate amenable to laser control. Our work allows us to identify an efficient method for loading cold SiO$^{+}$ from an ablated sample of SiO into an ion trap via the $(5,0)$ $A-X$ band at 213.977 nm.
Author Stollenwerk, Patrick R
Antonov, Ivan O
Odom, Brian C
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  givenname: Brian C
  surname: Odom
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BackLink https://doi.org/10.1016/j.jms.2018.11.008$$DView published paper (Access to full text may be restricted)
https://doi.org/10.48550/arXiv.1710.08905$$DView paper in arXiv
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Snippet Journal of Molecular Spectroscopy Volume 355, January 2019, Pages 40-45 The 1+1 REMPI spectrum of SiO in the 210-220 nm range is recorded. Observed bands are...
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Title IP determination and 1+1 REMPI spectrum of SiO at 210-220 nm with implications for SiO$^{+}$ ion trap loading
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