Optical properties of MgH2 measured in situ by ellipsometry and spectrophotometry

The dielectric properties of alpha-MgH2 are investigated in the photon energy range between 1 and 6.5 eV. For this purpose, a sample configuration and experimental setup are developed that allow both optical transmission and ellipsometric measurements of a transparent thin film in equilibrium with h...

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Bibliographic Details
Published in:Physical review. B, Condensed matter and materials physics Vol. 68; no. 11
Main Authors: Isidorsson, J, Giebels, IAME, Arwin, Hans, Griessen, R
Format: Journal Article
Language:English
Published: 2003
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Summary:The dielectric properties of alpha-MgH2 are investigated in the photon energy range between 1 and 6.5 eV. For this purpose, a sample configuration and experimental setup are developed that allow both optical transmission and ellipsometric measurements of a transparent thin film in equilibrium with hydrogen. We show that alpha-MgH2 is a transparent, color neutral insulator with a band gap of 5.6+/-0.1 eV. It has an intrinsic transparency of about 80% over the whole visible spectrum. The dielectric function found in this work confirms very recent band-structure calculations using the GW approximation by Alford and Chou (unpublished). As Pd is used as a cap layer we report also the optical properties of PdHx thin films.
ISSN:1550-235X
1098-0121
DOI:10.1103/PhysRevB.68.115112