钙钛矿太阳能电池用Ag/ZrO2/C柔性纳米纤维膜电极
O649; 钙钛矿太阳能电池(perovskite solar cells,PSCs)因其制备简单、光电转化效率较高等优点而备受关注.静电纺碳纳米纤维膜(carbon nanofiber films,CNFs)具有高比表面积、良好的电学性能和化学稳定性,但其脆性限制了它的应用.利用静电纺丝法结合水热法制备柔性导电Ag/ZrO2/C复合纳米纤维膜,然后将其应用于PSCs的对电极,研究不同Ag纳米颗粒添加量对柔性复合纳米纤维膜和电池的性能影响.结果表明:当银前驱体溶液质量浓度从0 g/mL增加至0.030 g/mL时,Ag/ZrO2/C复合纳米纤维表面的Ag纳米颗粒的包覆越来越好,薄膜显示良好的柔...
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| Published in: | 材料工程 Vol. 49; no. 9; pp. 79 - 86 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | Chinese |
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浙江理工大学 纺织科学与工程学院,杭州 310018
20-09-2021
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| Abstract | O649; 钙钛矿太阳能电池(perovskite solar cells,PSCs)因其制备简单、光电转化效率较高等优点而备受关注.静电纺碳纳米纤维膜(carbon nanofiber films,CNFs)具有高比表面积、良好的电学性能和化学稳定性,但其脆性限制了它的应用.利用静电纺丝法结合水热法制备柔性导电Ag/ZrO2/C复合纳米纤维膜,然后将其应用于PSCs的对电极,研究不同Ag纳米颗粒添加量对柔性复合纳米纤维膜和电池的性能影响.结果表明:当银前驱体溶液质量浓度从0 g/mL增加至0.030 g/mL时,Ag/ZrO2/C复合纳米纤维表面的Ag纳米颗粒的包覆越来越好,薄膜显示良好的柔韧性,其抗弯弹性模量为0.479 MPa,电导率从866 S/m增加到4862 S/m,提高了薄膜的空穴电子传输能力,进而增强PSCs的性能.当溶液质量浓度为0.030 g/mL时,器件具备最优的光电转换效率(6.05％)和最大电流(18.44 mA/cm2). |
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| AbstractList | O649; 钙钛矿太阳能电池(perovskite solar cells,PSCs)因其制备简单、光电转化效率较高等优点而备受关注.静电纺碳纳米纤维膜(carbon nanofiber films,CNFs)具有高比表面积、良好的电学性能和化学稳定性,但其脆性限制了它的应用.利用静电纺丝法结合水热法制备柔性导电Ag/ZrO2/C复合纳米纤维膜,然后将其应用于PSCs的对电极,研究不同Ag纳米颗粒添加量对柔性复合纳米纤维膜和电池的性能影响.结果表明:当银前驱体溶液质量浓度从0 g/mL增加至0.030 g/mL时,Ag/ZrO2/C复合纳米纤维表面的Ag纳米颗粒的包覆越来越好,薄膜显示良好的柔韧性,其抗弯弹性模量为0.479 MPa,电导率从866 S/m增加到4862 S/m,提高了薄膜的空穴电子传输能力,进而增强PSCs的性能.当溶液质量浓度为0.030 g/mL时,器件具备最优的光电转换效率(6.05％)和最大电流(18.44 mA/cm2). |
| Author | 吕芳洁 熊杰 宁磊 宋立新 荆婉如 辜宁霞 |
| AuthorAffiliation | 浙江理工大学 纺织科学与工程学院,杭州 310018 |
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| Author_FL | NING Lei LYU Fang-jie SONG Li-xin JING Wan-ru GU Ning-xia XIONG Jie |
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| DocumentTitle_FL | Ag/ZrO2/C flexible nanofiber films-based counter electrode for perovskite solar cells |
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| Keywords | 柔性复合纳米纤维膜电极 碳 钙钛矿太阳能电池 银 二氧化锆 |
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| Title | 钙钛矿太阳能电池用Ag/ZrO2/C柔性纳米纤维膜电极 |
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