Complete elastic tensor through the first-order transformation in U2Rh3Si5

• Published in: Physical review letters Vol. 95; no. 7; pp. 075506.1 - 075506.4
• Main Authors: LEISURE, R. G, KERN, S, DRYMIOTIS, F. R, LEDBETTER, H, MIGLIORI, A, MYDOSH, J. A
• Format: Journal Article
• Language: English
• Published: Ridge, NY American Physical Society 12-08-2005
• Subjects: Condensed matter: structure, mechanical and thermal properties; Elasticity, elastic constants; Equations of state, phase equilibria, and phase transitions; Exact sciences and technology; Mechanical and acoustical properties of condensed matter; Mechanical properties of solids; Physics; Solid-solid transitions; Specific phase transitions; Elastic modulus; Silicon alloys; Phase transformations; First order; Antiferromagnetic materials; Ultrasonic waves; Rhodium alloys; Uranium alloys; Bootstrap; Actinide alloys; Crystal field; Spin-phonon interactions
• ISSN: 0031-9007; 1079-7114
• DOI: 10.1103/PhysRevLett.95.075506

The complete elastic tensor of U(2)Rh(3)Si(5) has been determined over the temperature range of 5-300 K, including the dramatic first-order transition to an antiferromagnetic state at 25.5 K. Sharp upward steps in the elastic moduli as the temperature is decreased through the transition reveal the first-order nature of the phase change. In the antiferromagnetic state the temperature dependence of the elastic moduli scales with the square of the ordered moment on the uranium ion, demonstrating strong spin-lattice coupling. The temperature dependence of the moduli well above the transition indicates coupling of the ultrasonic waves to the crystal electric field levels of the uranium ion where the lowest state is a singlet. The elastic constant data suggest that the first-order phase change is magnetically driven by a bootstrap mechanism involving the ground state singlet and a magnetically active crystal electric field level.