Direct observation of the kinetic acidities of transient aromatic cation radicals: the mechanism of electrophilic side-chain nitration of the methylbenzenes

Direct observation of the kinetic acidities of transient aromatic cation radicals: the mechanism of electrophilic side-chain nitration of the methylbenzenes

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Bibliographic Details
Published in:Journal of the American Chemical Society Vol. 111; no. 6; pp. 2263 - 2276
Main Authors: MASNOVI, J. M, SANKARARAMAN, S, KOCHI, J. K
Format: Journal Article
Language:English
Published: Washington, DC American Chemical Society 15-03-1989
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Photochemistry
Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Reaction intermediate
Deexcitation
Nitration
Charge transfer compound
Kinetics
Electrophilic reaction
Quantum yield
Organic radical cation
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Description
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00188a048