Reactions of bis(cyclopentadienyl)titanium(IV) and zirconium(IV) chlorides with 1,1'-diacetylferrocenyl bis(hydrazones). Formation of trimetallic derivatives

Reactions of bis(cyclopentadienyl)titanium(IV) and zirconium(IV) chlorides with 1,1'-diacetylferrocenyl bis(hydrazones). Formation of trimetallic derivatives

Bis(cyclopentadienyl)titanium(IV) and zirconium(IV) chlorides react with bis(hydrazones) derived from 1,1'-diacetylferrocene in anhydrous THF in the presence of base to give complexes of the type [(Cp^sub 2^MCl)^sub 2^L] [M = Ti or Zr; LH^sub 2^ = ferrocenyl bis(hydrazones)]. Tentative structur...

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Bibliographic Details
Published in:Transition metal chemistry (Weinheim) Vol. 25; no. 6; p. 613
Main Authors: Mala, Anchal, Srivastava, Akhilesh K, Pandey, Om P, Sengupta, Soumitra K
Format: Journal Article
Language:English
Published: Dordrecht Springer Nature B.V 01-12-2000
Online Access:Get full text
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Summary:Bis(cyclopentadienyl)titanium(IV) and zirconium(IV) chlorides react with bis(hydrazones) derived from 1,1'-diacetylferrocene in anhydrous THF in the presence of base to give complexes of the type [(Cp^sub 2^MCl)^sub 2^L] [M = Ti or Zr; LH^sub 2^ = ferrocenyl bis(hydrazones)]. Tentative structures are proposed for these complexes based upon elemental analyses, electrical conductance, magnetic moment and spectroscopic data.[PUBLICATION ABSTRACT]
ISSN:0340-4285
1572-901X
DOI:10.1023/A:1007036131648