Short synthesis of the C16-C28 polyketide fragment of apoptolidin A aglycone

Starting from (E,E)-1-[(1R)-(phenylethyl)oxy]-2-methylpenta-1,3-diene and triethylsilyl enol ether of butanone rapid access to Koert's advanced C10-C28 polyketide fragment of apoptolidin A is now possible.

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) no. 23; p. 2411
Main Authors:	Craita, Cotinica, Didier, Charles, Vogel, Pierre
Format:	Journal Article
Language:	English
Published:	England 21-06-2007
Subjects:	Macrolides - chemical synthesis Pyrones - chemical synthesis
Online Access:	Get more information
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Description
Summary:	Starting from (E,E)-1-[(1R)-(phenylethyl)oxy]-2-methylpenta-1,3-diene and triethylsilyl enol ether of butanone rapid access to Koert's advanced C10-C28 polyketide fragment of apoptolidin A is now possible.
ISSN:	1359-7345
DOI:	10.1039/b701293d