Photochemistry of fluorochloroamines in low-temperature argon matrices

• Published in: Journal of physical chemistry (1952) Vol. 94; no. 7; pp. 3027 - 3031
• Main Authors: CONKLIN, R. A, GILBERT, J. V
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 05-04-1990
• Subjects: AMINES; CHEMICAL REACTIONS; CHEMISTRY; DATA; DATA ANALYSIS; DECOMPOSITION; ELEMENTS; Exact sciences and technology; EXPERIMENTAL DATA; General and physical chemistry; HALOGENS; INFORMATION; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MEASURING INSTRUMENTS; MEASURING METHODS; NONMETALS; NUMERICAL DATA; ORGANIC COMPOUNDS; PHOTOCHEMICAL REACTIONS 400201 > Chemical & Physicochemical Properties; PHOTOCHEMISTRY; PHOTOLYSIS; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Tertiary amine; Reaction mechanism; Infrared spectrum; Experimental study; Chemical reactivity; Photochemistry
• ISSN: 0022-3654; 1541-5740
• DOI: 10.1021/j100370a054

Broad-band and single-wavelength photolysis studies of NFCl{sub 2} and NF{sub 2}Cl in low-temperature argon matrices have been carried out and the photolysis products identified via the IR spectra of the matrices. Broad-band photolysis and photolysis at 250, 270, and 300 nm of the NFCl{sub 2} matrix produced NF, as identified by the appearance of a peak at 1,113 cm{sup {minus}1} in the IR spectrum. Photolysis of the NFCl{sub 2}/Ar matrix at 210 and at 330 nm and of the NF{sub 2}Cl/Ar matrix at 210, 245, and 330 nm produced no changes in the IR spectrum. Mechanisms are presented to explain these results.