31P-NMR Study of Phase Transition in Betaine Phosphate (CH3)3NCH2COO·H3PO4 at 365 K

The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both...

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Published in:Journal of the Physical Society of Japan Vol. 73; no. 6; p. 1423
Main Authors: Murashima, Ryota, Sanjo, Yohtarou, Machida, Mitsuo
Format: Journal Article
Language:English
Published: Tokyo The Physical Society of Japan 01-06-2004
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Abstract The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both the intrachain and interchain directions. The interaction parameters for intrachain J|| and interchain J[perpendicular] are determined to be 693(3) and 4.1(1) K, respectively.
AbstractList The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both the intrachain and interchain directions. The interaction parameters for intrachain J|| and interchain J[perpendicular] are determined to be 693(3) and 4.1(1) K, respectively.
Author Murashima, Ryota
Sanjo, Yohtarou
Machida, Mitsuo
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  givenname: Mitsuo
  surname: Machida
  fullname: Machida, Mitsuo
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Snippet The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical...
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