31P-NMR Study of Phase Transition in Betaine Phosphate (CH3)3NCH2COO·H3PO4 at 365 K
The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both...
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Published in: | Journal of the Physical Society of Japan Vol. 73; no. 6; p. 1423 |
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Main Authors: | , , |
Format: | Journal Article |
Language: | English |
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Tokyo
The Physical Society of Japan
01-06-2004
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Abstract | The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both the intrachain and interchain directions. The interaction parameters for intrachain J|| and interchain J[perpendicular] are determined to be 693(3) and 4.1(1) K, respectively. |
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AbstractList | The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical slowing down. The critical relaxation rate is reproduced by the quasi-one-dimensional Ising model with antiferroelectric interactions along both the intrachain and interchain directions. The interaction parameters for intrachain J|| and interchain J[perpendicular] are determined to be 693(3) and 4.1(1) K, respectively. |
Author | Murashima, Ryota Sanjo, Yohtarou Machida, Mitsuo |
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ContentType | Journal Article |
Copyright | Copyright Japan Science and Technology Agency 2004 |
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Snippet | The phase transition in (CH3)3NCH2COO·H3PO4 at TC1=365 K was studied by 31P-NMR. Spin-lattice relaxation time shows a sharp dip at TC1 due to the critical... |
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Title | 31P-NMR Study of Phase Transition in Betaine Phosphate (CH3)3NCH2COO·H3PO4 at 365 K |
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