Synthesis of the Long Sought After Compound Pentafluoronitrosulfane, SF5NO2

Call off the search: Photolysis of a mixture of SF5Br and NO2 results in the synthesis of gram quantities of pentafluoronitrosulfane, SF5NO2 (see picture), whose preliminary structure was obtained by gas‐phase electron diffraction studies and reveals the longest SVIN bond reported (1.903(7) Å)....

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 45; no. 6; pp. 938 - 940
Main Authors:	Lu, Norman, Kumar, H. P. Sampath, Fye, James L., Sun Blanks, Jian, Thrasher, Joseph S., Willner, Helge, Oberhammer, Heinz
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 30-01-2006 WILEY‐VCH Verlag
Subjects:	atmospheric chemistry fluorine nitro compounds photolysis sulfur
Online Access:	Get full text
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Summary:	Call off the search: Photolysis of a mixture of SF5Br and NO2 results in the synthesis of gram quantities of pentafluoronitrosulfane, SF5NO2 (see picture), whose preliminary structure was obtained by gas‐phase electron diffraction studies and reveals the longest SVIN bond reported (1.903(7) Å).
Bibliography:	ark:/67375/WNG-2PW8KKL8-S istex:43D08ECC866F58D43734C47B7DA5E5C9DCA8CC39 The authors gratefully acknowledge the support of The University of Alabama. N.L. thanks Dr. J. C. Jiang (Institute of Atomic and Molecular Sciences, Academia Sinica, Taiwan) for MP2 calculations. ArticleID:ANIE200503320 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200503320