Improved Electrical Properties of Solution-Processed ZrO2 Gate Dielectric for Large-Area Flexible Electronics

Zirconium oxide (ZrO 2 ), which has high dielectric constant, was investigated for application in flexible electronics. When the spun-cast film was annealed at a low temperature, the electrical properties were not encouraging because residual organic particles remained at the dielectric. To address...

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Published in:Jpn J Appl Phys Vol. 52; no. 10; pp. 100206 - 100206-3
Main Authors: Hasan, Musarrat, Jang, Mi, Kim, Dong-Hyoub, Nguyen, Manh Cuong, Yang, Hoichang, Jeong, Jae Kyeong, Choi, Rino
Format: Journal Article
Language:English
Published: The Japan Society of Applied Physics 01-10-2013
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Abstract Zirconium oxide (ZrO 2 ), which has high dielectric constant, was investigated for application in flexible electronics. When the spun-cast film was annealed at a low temperature, the electrical properties were not encouraging because residual organic particles remained at the dielectric. To address this problem we used plasma annealing at a reasonably low temperature and achieved improved dielectric properties such as lower leakage current, higher dielectric constant, and better reliability. Auger depth profile spectroscopy results suggested reduction of carbon percentage at the dielectric. We demonstrated device application by fabricating transistor device with an organic channel layer. The transistor electrical properties were encouraging, exhibiting an electron mobility of 0.3 cm 2 /(V$\cdot$s). The results were very promising and suggest that ZrO 2 could be applied to all-printed electronic devices in the near future.
AbstractList Zirconium oxide (ZrO 2 ), which has high dielectric constant, was investigated for application in flexible electronics. When the spun-cast film was annealed at a low temperature, the electrical properties were not encouraging because residual organic particles remained at the dielectric. To address this problem we used plasma annealing at a reasonably low temperature and achieved improved dielectric properties such as lower leakage current, higher dielectric constant, and better reliability. Auger depth profile spectroscopy results suggested reduction of carbon percentage at the dielectric. We demonstrated device application by fabricating transistor device with an organic channel layer. The transistor electrical properties were encouraging, exhibiting an electron mobility of 0.3 cm 2 /(V$\cdot$s). The results were very promising and suggest that ZrO 2 could be applied to all-printed electronic devices in the near future.
Author Jeong, Jae Kyeong
Kim, Dong-Hyoub
Yang, Hoichang
Jang, Mi
Nguyen, Manh Cuong
Hasan, Musarrat
Choi, Rino
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  givenname: Mi
  surname: Jang
  fullname: Jang, Mi
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  givenname: Rino
  surname: Choi
  fullname: Choi, Rino
  organization: Department of Materials Science and Engineering, Inha University, Incheon 402-751, Republic of Korea
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Notes (Color online) (a) Auger electron depth profiles for ZrO 2 films plasma annealed under various conditions. Plasma annealing was performed for 1 h. (b) Leakage current density of capacitors annealed at 250 °C in O 2 plasma for various lengths of time. (Color online) (a) Capacitance densities for ZrO 2 films annealed at 250 °C in O 2 plasma for various length of time and compared them with device annealed at 250 °C for 60 min in O 2 atmosphere. (b) Current densities and EOTs for various films annealed at 250 °C for various lengths of time. (Color online) (a) Changes in interface trap density of ZrO 2 capacitor and in hysteresis with various lengths of plasma annealing time. (b) Change in flat-band voltage with application of prolonged negative bias stress. (Color online) (a) Transfer and (b) output characteristics of solution-processed TES-ADT TFT with plasma-annealed ZrO 2 as gate dielectric.
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