Synthesis and Crystal Structure of a New Silver(I) Complex

The reaction of 4‐amino‐6‐methyl‐1,2,4‐triazine‐3(2 H)‐thione‐5‐one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO)2]NO3 (1). 1 was characterized by IR and 13C NMR spectroscopy and by an X‐ray structure analysis [space group C2/c, Z = 4, lattice dimensions at –80 °C: a = 1306...

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Bibliographic Details
Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 625; no. 9; pp. 1411 - 1412
Main Authors:	Adhami, Forough, Ghassemzadeh, Mitra, Heravi, Majid M., Taeb, Abas, Neumüller, Bernhard
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag GmbH 01-09-1999 WILEY‐VCH Verlag GmbH
Subjects:	crystal structure Silver(I) complex triazine ligand
Online Access:	Get full text
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Summary:	The reaction of 4‐amino‐6‐methyl‐1,2,4‐triazine‐3(2 H)‐thione‐5‐one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO)2]NO3 (1). 1 was characterized by IR and 13C NMR spectroscopy and by an X‐ray structure analysis [space group C2/c, Z = 4, lattice dimensions at –80 °C: a = 1306.7(2), b = 1139.0(2), c = 1089.2(1) pm, β = 94.54(1)°, R1 = 0.0294]. The cation possesses a highly distorted linear coordination sphere in the solid state.
Bibliography:	ArticleID:ZAAC1411 istex:EEB1B909E4CD1E5C15AB4A93AE80D473B32EFD7D ark:/67375/WNG-R56WNWT6-2
ISSN:	0044-2313 1521-3749
DOI:	10.1002/(SICI)1521-3749(199909)625:9<1411::AID-ZAAC1411>3.0.CO;2-R