Synthesis and acylation of 2-nitro-11H-dibenzo[b,e][1,4]dioxepin

A one‐pot synthesis of the 11H‐dibenzo[b,e]1,4]dioxepin ring system from catechol and an o‐chlorobenzyl chloride is described. Friedel‐Crafts acylation occurs at the 7‐position as shown by X‐ray analysis.

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Bibliographic Details
Published in:	Journal of heterocyclic chemistry Vol. 23; no. 3; pp. 673 - 677
Main Authors:	Hagmann, William K., O'Grady, Laura A., Dorn, Conrad P., Springer, James P.
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley-Blackwell 01-05-1986 Wiley‐Blackwell HeteroCorporation
Subjects:	Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with o, s, se, te hetero atom and condensed derivatives Organic chemistry Organic compounds Physics Preparations and properties Structure of solids and liquids; crystallography Structure of specific crystalline solids Molecular structure Aromatic compound Tricyclic compound Experimental study Oxygen heterocycle X ray diffraction Acylation Organic compounds Crystalline structure
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