"Crowned" Univalent Indium Complexes as Donors? Experimental and Computational Insights on the Valence Isomers of EE′X4 Species

The use of the univalent indium reagent [In([18]crown‐6)][OTf] as a donor is investigated by its reactions with acceptors including InX3 (X=Cl, Br, I). The donor–acceptor complexes of the form [X([18]crown‐6)InInX3] obtained in this manner represent the first new isomeric form of indium(II) halides...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 17; no. 22; pp. 6148 - 6161
Main Authors:	Cooper, Benjamin F. T., Hamaed, Hiyam, Friedl, Warren W., Stinchcombe, Michael R., Schurko, Robert W., Macdonald, Charles L. B.
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 23-05-2011 WILEY‐VCH Verlag
Subjects:	computational chemistry crown ethers donor-acceptor systems indium valence isomers
Online Access:	Get full text
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