Crystal and Electronic Structure of the Lithium-Rich Silver Silicide Li12Ag1−xSi4 (x=0.15)

Zintl phases: The new lithium‐rich Zintl phase Li12Ag1−xSi4 (x=0.15) contains the highly charged 16‐electron anion [AgSi2]7−. Chemical bonding is discussed based on electronic band structure analysis (see figure).

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 19; no. 49; pp. 16528 - 16531
Main Authors:	Slabon, Adam, Budnyk, Serhiy, Cuervo-Reyes, Eduardo, Wörle, Michael, Verel, René, Nesper, Reinhard
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 02-12-2013 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Chemistry density functional calculations lithium NMR spectroscopy silicides Zintl phases
Online Access:	Get full text
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Description
Summary:	Zintl phases: The new lithium‐rich Zintl phase Li12Ag1−xSi4 (x=0.15) contains the highly charged 16‐electron anion [AgSi2]7−. Chemical bonding is discussed based on electronic band structure analysis (see figure).
Bibliography:	ark:/67375/WNG-22PQZZPX-T istex:CD5CDB93DB204610A31D26677D34B4B345E29B2D ArticleID:CHEM201302574
ISSN:	0947-6539 1521-3765
DOI:	10.1002/chem.201302574