CO2/N2 gas separation using Fe(BTC)-based mixed matrix membranes: A view on the adsorptive and filler properties of metal-organic frameworks
[Display omitted] •Metal-Organic Framework (MOF) Fe(BTC) evaluated as an adsorbent for CO2/N2 adsorption.•Fe(BTC)-based mixed matrix membranes (MMMs) were prepared and characterized.•MMMs showed higher separation performance at high temperature.•At 353 K, Fe(BTC)-based MMMs surpass the Robeson upper...
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| Published in: | Separation and purification technology Vol. 202; pp. 174 - 184 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
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Elsevier B.V
31-08-2018
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| Abstract | [Display omitted]
•Metal-Organic Framework (MOF) Fe(BTC) evaluated as an adsorbent for CO2/N2 adsorption.•Fe(BTC)-based mixed matrix membranes (MMMs) were prepared and characterized.•MMMs showed higher separation performance at high temperature.•At 353 K, Fe(BTC)-based MMMs surpass the Robeson upper-bound correlation.
The incorporation of a Metal-Organic Framework (MOF), Fe(BTC), into a polymeric membrane was assessed for CO2/N2 gas separation. The adsorptive and filler properties of the MOF in the Mixed Matrix Membranes (MMMs) produced were investigated as a strategy to separate CO2 from N2 and contribute to reduce CO2 emissions. Therefore, Fe(BTC) was firstly characterized by single-component adsorption equilibria measurements of CO2 and N2, to evaluate the MOF performance as an adsorbent for CO2/N2 separation and its adsorption role in the MMMs performance. Fe(BTC) was then incorporated in Matrimid®5218 at different loading percentages, and the MMMs produced were characterized by distinct techniques (SEM, TGA, puncture tests and contact angle essays). Finally, pure gas permeation experiments were carried out for CO2 and N2 at 303 K, 323 K and 353 K, to evaluate the temperature impact on both gas permeability and CO2/N2 ideal selectivity. The results show that an increase in CO2 permeability and CO2/N2 ideal selectivity can be advantageously achieved, especially at the higher operating temperature of 353 K. At these conditions, the Robeson upper-bound is surpassed, which is a clear indication of the high potential of using Matrimid®5218/Fe(BTC) MMMs in post-combustion streams at high-temperatures. |
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| AbstractList | [Display omitted]
•Metal-Organic Framework (MOF) Fe(BTC) evaluated as an adsorbent for CO2/N2 adsorption.•Fe(BTC)-based mixed matrix membranes (MMMs) were prepared and characterized.•MMMs showed higher separation performance at high temperature.•At 353 K, Fe(BTC)-based MMMs surpass the Robeson upper-bound correlation.
The incorporation of a Metal-Organic Framework (MOF), Fe(BTC), into a polymeric membrane was assessed for CO2/N2 gas separation. The adsorptive and filler properties of the MOF in the Mixed Matrix Membranes (MMMs) produced were investigated as a strategy to separate CO2 from N2 and contribute to reduce CO2 emissions. Therefore, Fe(BTC) was firstly characterized by single-component adsorption equilibria measurements of CO2 and N2, to evaluate the MOF performance as an adsorbent for CO2/N2 separation and its adsorption role in the MMMs performance. Fe(BTC) was then incorporated in Matrimid®5218 at different loading percentages, and the MMMs produced were characterized by distinct techniques (SEM, TGA, puncture tests and contact angle essays). Finally, pure gas permeation experiments were carried out for CO2 and N2 at 303 K, 323 K and 353 K, to evaluate the temperature impact on both gas permeability and CO2/N2 ideal selectivity. The results show that an increase in CO2 permeability and CO2/N2 ideal selectivity can be advantageously achieved, especially at the higher operating temperature of 353 K. At these conditions, the Robeson upper-bound is surpassed, which is a clear indication of the high potential of using Matrimid®5218/Fe(BTC) MMMs in post-combustion streams at high-temperatures. |
| Author | Nabais, Ana Rita Mota, José P.B. Neves, Luísa A. Esteves, Isabel A.A.C. Ribeiro, Rui P.P.L. Alves, Vítor D. |
| Author_xml | – sequence: 1 givenname: Ana Rita surname: Nabais fullname: Nabais, Ana Rita organization: LAQV – REQUIMTE, Departamento de Qúímica, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, Caparica 2829-516, Portugal – sequence: 2 givenname: Rui P.P.L. surname: Ribeiro fullname: Ribeiro, Rui P.P.L. organization: LAQV – REQUIMTE, Departamento de Qúímica, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, Caparica 2829-516, Portugal – sequence: 3 givenname: José P.B. surname: Mota fullname: Mota, José P.B. organization: LAQV – REQUIMTE, Departamento de Qúímica, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, Caparica 2829-516, Portugal – sequence: 4 givenname: Vítor D. surname: Alves fullname: Alves, Vítor D. organization: LEAF, Linking Landscape, Environment, Agriculture and Food, Instituto Superior de Agronomia, Universidade de Lisboa, Tapada da Ajuda, Lisboa 1349-017, Portugal – sequence: 5 givenname: Isabel A.A.C. surname: Esteves fullname: Esteves, Isabel A.A.C. email: iaesteves@fct.unl.pt organization: LAQV – REQUIMTE, Departamento de Qúímica, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, Caparica 2829-516, Portugal – sequence: 6 givenname: Luísa A. surname: Neves fullname: Neves, Luísa A. email: lan11892@fct.unl.pt organization: LAQV – REQUIMTE, Departamento de Qúímica, Faculdade de Ciências e Tecnologia, Universidade NOVA de Lisboa, Caparica 2829-516, Portugal |
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| Copyright | 2018 Elsevier B.V. |
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| References | Deniz, Karadas, Patel, Aparicio, Yavuz, Atilhan (b0190) 2013; 175 M.M. Dubinin, Progress in surface and membrane science, in: Progress in Surface and Membrane Science, first ed., Academic Press, New York, 1975. Lee, Tang, Huo (b0045) 2014; 4 Meek, Greathouse, Allendorf (b0105) 2011; 23 Sing (b0290) 1985; 57 Zornoza, Tellez, Coronas, Gascon, Kapteijn (b0025) 2013; 166 Jin (b0040) 2016; 305 Soubeyrand-Lenoir (b0195) 2012; 134 Rouqerol, Rouquerol, Sing (b0230) 1999 Joly, Le Cerf, Chappey, Langevin, Muller (b0350) 1999; 16 Du, Li, Li, Si (b0315) 2016; 6 Mollmer (b0325) 2012; 12 Walton, Snurr (b0200) 2007; 129 Dubinin (b0220) 1960; 60 Chung, Fen, Liu (b0330) 2006; 271 Brunetti, Scura, Barbieri, Drioli (b0010) 2010; 359 Llewellyn (b0160) 2008; 24 Rezakazemi, Amooghin, Montazer-Rahmati, Ismail, Matsuura (b0060) 2014; 39 Pechar (b0070) 2006; 277 Perez, Jr, Ferraris, Musselman (b0125) 2009; 328 Bae, Long (b0120) 2013; 6 Wang, Liu, Demir, Paul, Li (b0050) 2016; 45 Mosleh, Mozdianfard, Hemmati, Khanbabaei (b0355) 2017; 38 Robeson (b0055) 2008; 320 Gascón, Jiménez, Blanco, Sanchez-sanchez (b0175) 2017 Freeman (b0035) 1999; 32 Camacho, Ribeiro, Esteves, Mota (b0205) 2015; 141 Tomé, Marrucho (b0375) 2016; 45 Agarwal, Schwarz (b0255) 1988; 26 Li (b0015) 2011; 255 Pilloni (b0305) 2015; 213 Wood (b0240) 2001; 39 Gascon, Aktay, Hernandez-Alonso, van Klink, Kapteijn (b0110) 2009; 261 Ulbricht (b0020) 2006; 47 Vu, Koros, Miller (b0090) 2003; 211 Basu, Cano-odena, Vankelecom (b0115) 2011; 81 Dhakshinamoorthy, Alvaro, Garcia (b0165) 2011; 17 Pechar (b0065) 2006; 277 Krishna, Van Baten (b0150) 2012; 87 Neves, Crespo, Coelhoso (b0270) 2010; 357 Dhakshinamoorthy, Alvaro, Garcia (b0180) 2012; 48 Vu, Koros, Miller (b0095) 2003; 221 Do (b0215) 1998 Babu (b0335) 2010; 12 Josephine, Ordo, Jr, Ferraris, Musselman (b0365) 2010; 361 Tien (b0235) 1994 Calvin, Danner (b0245) 1972; 17 Dhakshinamoorthy (b0300) 2012; 2 Guesh (b0185) 2017; 17 Abdelrahim, Martins, Neves, Capasso (b0275) 2017; 528 Cussler (b0280) 1997 Opanasenko, Dhakshinamoorthy, Shamzhy, Nachtigall, Hora (b0295) 2013; 3 Opanasenko, Nachtigall, Jagiello (b0310) 2015; 243 Reid, Prausnitz, Sherwood (b0250) 1988 Ploegmakers, Japip, Nijmeijer (b0320) 2013; 428 Kim, Pechar, Marand (b0085) 2006; 192 Monteiro (b0340) 2017; 5 Millward, Yaghi (b0145) 2005; 127 Zhang, Musselman, Ferraris, Jr (b0345) 2008; 313 Esteves, Lopes, Nunes, Mota (b0265) 2008; 62 Rowe, Robeson, Freeman, Paul (b0370) 2010; 360 Shahid, Nijmeijer (b0130) 2014; 459 Sánchez-sanchez, Asua, Ruano (b0170) 2015; 15 Ramdin, De Loos, Vlugt (b0005) 2012; 51 Koros, Fleming (b0030) 1993; 83 Sabetghadam (b0100) 2016; 26 Horcajada (b0155) 2007; 100 Sentaro, Kusumi, Yoshisada (b0260) 1976; 56 Golemme, Bruno, Manes, Muoio (b0075) 2006; 200 Gumma, Talu (b0210) 2010; 26 Chung, Chan, Wang, Lu, He (b0080) 2003; 211 Dorosti, Alizadehdakhel (b0135) 2018 Ilyas, Muhammad, Amjad, Ayub, Vankelecom, Khan (b0360) 2017; 543 Thommes (b0285) 2015; 87 Farrusseng (b0140) 2011 |
| References_xml | – volume: 277 start-page: 195 year: 2006 end-page: 202 ident: b0070 article-title: Fabrication and characterization of polyimide-zeolite L mixed matrix membranes for gas separations publication-title: J. Memb. Sci. contributor: fullname: Pechar – volume: 15 start-page: 4498 year: 2015 end-page: 4505 ident: b0170 article-title: Direct synthesis, structural features and enhanced catalytic activity of the Basolite F300-like semi-amorphous Fe-BTC framework publication-title: Cryst. Growth Des. contributor: fullname: Ruano – volume: 255 start-page: 1791 year: 2011 end-page: 1823 ident: b0015 article-title: Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks publication-title: Coord. Chem. Rev. contributor: fullname: Li – volume: 26 start-page: 17013 year: 2010 end-page: 17023 ident: b0210 article-title: Net adsorption: a thermodynamic framework for supercritical gas adsorption and storage in porous solids publication-title: Langmuir contributor: fullname: Talu – volume: 543 start-page: 301 year: 2017 end-page: 309 ident: b0360 article-title: Supported protic ionic liquid membrane based on 3-(trimethoxysilyl) propan-1-aminium acetate for the highly selective separation of CO2 publication-title: J. Memb. Sci. contributor: fullname: Khan – volume: 87 start-page: 1051 year: 2015 end-page: 1069 ident: b0285 article-title: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) publication-title: Pure Appl. Chem. contributor: fullname: Thommes – year: 1997 ident: b0280 article-title: Diffusion Mass Transfer in Fluid Systems contributor: fullname: Cussler – volume: 48 start-page: 11275 year: 2012 end-page: 11288 ident: b0180 article-title: Commercial metal – organic frameworks as heterogeneous catalysts publication-title: Chem. Commun. contributor: fullname: Garcia – year: 1994 ident: b0235 article-title: Adsorption Calculations and Modeling contributor: fullname: Tien – volume: 129 start-page: 8552 year: 2007 end-page: 8556 ident: b0200 article-title: Applicability of the BET method for determining surface areas of microporous metal-organic frameworks publication-title: J. Am. Chem. Soc. contributor: fullname: Snurr – volume: 81 start-page: 31 year: 2011 end-page: 40 ident: b0115 article-title: MOF-containing mixed-matrix membranes for CO2/CH4 and CO2/N2 binary gas mixture separations publication-title: Sep. Purif. Technol. contributor: fullname: Vankelecom – volume: 39 start-page: 343 year: 2001 end-page: 356 ident: b0240 article-title: Affinity coefficients of the Polanyi/Dubinin adsorption isotherm equations: a review with compilations and correlations publication-title: Carbon N. Y. contributor: fullname: Wood – volume: 39 start-page: 817 year: 2014 end-page: 861 ident: b0060 article-title: State-of-the-art membrane based CO2 separation using mixed matrix membranes (MMMs): an overview on current status and future directions publication-title: Prog. Polym. Sci. contributor: fullname: Matsuura – volume: 221 start-page: 233 year: 2003 end-page: 239 ident: b0095 article-title: Effect of condensable impurity in CO2/CH4 gas feeds on performance of mixed matrix membranes using carbon molecular sieves publication-title: J. Memb. Sci. contributor: fullname: Miller – volume: 12 start-page: 632 year: 2010 end-page: 635 ident: b0335 article-title: Electrocatalytic activity of Basolite TM F300 metal-organic-framework structures publication-title: Electrochem. commun. contributor: fullname: Babu – volume: 5 start-page: 1 year: 2017 end-page: 4 ident: b0340 article-title: Membranes with a low loading of metal – organic framework-supported ionic liquids for CO2/N2 separation in CO2 capture publication-title: Energy Technol. contributor: fullname: Monteiro – volume: 192 start-page: 330 year: 2006 end-page: 339 ident: b0085 article-title: Poly(imide siloxane) and carbon nanotube mixed matrix membranes for gas separation publication-title: Desalination contributor: fullname: Marand – volume: 47 start-page: 2217 year: 2006 end-page: 2262 ident: b0020 article-title: Advanced functional polymer membranes publication-title: Polymer (Guildf) contributor: fullname: Ulbricht – volume: 360 start-page: 58 year: 2010 end-page: 69 ident: b0370 article-title: Influence of temperature on the upper bound: theoretical considerations and comparison with experimental results publication-title: J. Memb. Sci. contributor: fullname: Paul – volume: 141 start-page: 150 year: 2015 end-page: 159 ident: b0205 article-title: Adsorption equilibrium of carbon dioxide and nitrogen on the MIL-53(Al) metal organic framework publication-title: Sep. Purif. Technol. contributor: fullname: Mota – volume: 16 start-page: 47 year: 1999 end-page: 54 ident: b0350 article-title: Residual solvent effect on the permeation properties of fluorinated polyimide films publication-title: Sep. Purif. Technol. contributor: fullname: Muller – volume: 328 start-page: 165 year: 2009 end-page: 173 ident: b0125 article-title: Mixed-matrix membranes containing MOF-5 for gas separations publication-title: J. Memb. Sci. contributor: fullname: Musselman – volume: 83 start-page: 317 year: 1993 end-page: 330 ident: b0030 article-title: Membrane-based gas separation publication-title: J. Memb. Sci. contributor: fullname: Fleming – volume: 528 start-page: 225 year: 2017 end-page: 230 ident: b0275 article-title: Supported ionic liquid membranes immobilized with carbonic anhydrases for CO2 transport at high temperatures publication-title: J. Memb. Sci. contributor: fullname: Capasso – volume: 17 start-page: 236 year: 1972 end-page: 241 ident: b0245 article-title: Improved equation for prediction of saturated liquid density publication-title: J. Chem. Eng. Data contributor: fullname: Danner – year: 2011 ident: b0140 article-title: Metal Organic Frameworks: Applications from Catalysis to Gas Storage publication-title: Metal Organic Frameworks: Applications from Catalysis to Gas Storage contributor: fullname: Farrusseng – volume: 62 start-page: 281 year: 2008 end-page: 296 ident: b0265 article-title: Adsorption of natural gas and biogas components on activated carbon publication-title: Sep. Purif. Technol. contributor: fullname: Mota – volume: 261 start-page: 75 year: 2009 end-page: 87 ident: b0110 article-title: Amino-based metal-organic frameworks as stable, highly active basic catalysts publication-title: J. Catal. contributor: fullname: Kapteijn – volume: 127 start-page: 17998 year: 2005 end-page: 17999 ident: b0145 article-title: Metal organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature publication-title: J. Am. Chem. Soc. contributor: fullname: Yaghi – volume: 357 start-page: 160 year: 2010 end-page: 170 ident: b0270 article-title: Gas permeation studies in supported ionic liquid membranes publication-title: J. Memb. Sci. contributor: fullname: Coelhoso – volume: 32 start-page: 375 year: 1999 end-page: 380 ident: b0035 article-title: Basis of permeability/selectivity tradeoff relations in polymeric gas separation membranes publication-title: Macromolecules contributor: fullname: Freeman – volume: 6 start-page: 62705 year: 2016 end-page: 62716 ident: b0315 article-title: Adsorption mechanism on metal organic frameworks of Cu-BTC, Fe-BTC and ZIF-8 for CO2 capture investigated by X-ray absorption fine structure publication-title: RSC Adv. contributor: fullname: Si – volume: 24 start-page: 7245 year: 2008 end-page: 7250 ident: b0160 article-title: High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101 publication-title: Langmuir contributor: fullname: Llewellyn – volume: 23 start-page: 249 year: 2011 end-page: 267 ident: b0105 article-title: Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials publication-title: Adv. Mater. contributor: fullname: Allendorf – volume: 12 start-page: 10274 year: 2012 end-page: 10286 ident: b0325 article-title: Pure and mixed gas adsorption of CH4 and N2 on the metal–organic framework Basolite A100 and a novel copper-based 1,2,4-triazolylisophtalate MOF publication-title: J. Mater. Chem. contributor: fullname: Mollmer – volume: 200 start-page: 440 year: 2006 end-page: 442 ident: b0075 article-title: Preparation and properties of superglassy polymers - zeolite mixed matrix membranes publication-title: Desalination contributor: fullname: Muoio – start-page: 1 year: 2017 end-page: 8 ident: b0175 article-title: Semi-crystalline Fe-BTC MOF material as an efficient support for enzyme immobilization publication-title: Catal. Today contributor: fullname: Sanchez-sanchez – volume: 320 start-page: 390 year: 2008 end-page: 400 ident: b0055 article-title: The upper bound revisited publication-title: J. Memb. Sci. contributor: fullname: Robeson – volume: 56 start-page: 83 year: 1976 end-page: 91 ident: b0260 article-title: Physical adsorption of gases at high pressure. IV. An improvement of the Dubinin—Astakhov adsorption equation publication-title: J. Colloid Interface Sci. contributor: fullname: Yoshisada – year: 1999 ident: b0230 article-title: Adsorption by Powders and Porous Solids: Principles, Methodology and Applications contributor: fullname: Sing – volume: 361 start-page: 28 year: 2010 end-page: 37 ident: b0365 article-title: Molecular sieving realized with ZIF-8/Matrimid ® mixed-matrix membranes publication-title: J. Memb. Sci. contributor: fullname: Musselman – volume: 277 start-page: 210 year: 2006 end-page: 218 ident: b0065 article-title: Preparation and characterization of a poly(imide siloxane) and zeolite L mixed matrix membrane publication-title: J. Memb. Sci. contributor: fullname: Pechar – volume: 45 start-page: 2785 year: 2016 end-page: 2824 ident: b0375 article-title: Ionic liquid-based materials: a platform to design engineered CO2 separation membranes publication-title: Chem. Soc. Rev. contributor: fullname: Marrucho – volume: 17 start-page: 6256 year: 2011 end-page: 6262 ident: b0165 article-title: Atmospheric-pressure, liquid-phase, selective aerobic oxidation of alkanes catalysed by metal–organic frameworks publication-title: Chem. Eur. J. contributor: fullname: Garcia – volume: 45 start-page: 5107 year: 2016 end-page: 5134 ident: b0050 article-title: Applications of water stable metal – organic frameworks publication-title: Chem. Soc. Rev. contributor: fullname: Li – volume: 459 start-page: 33 year: 2014 end-page: 44 ident: b0130 article-title: High pressure gas separation performance of mixed-matrix polymer membranes containing mesoporous Fe(BTC) publication-title: J. Memb. Sci. contributor: fullname: Nijmeijer – volume: 271 start-page: 221 year: 2006 end-page: 231 ident: b0330 article-title: Enhanced Matrimid membranes for pervaporation by homogenous blends with polybenzimidazole (PBI) publication-title: J. Memb. Sci. contributor: fullname: Liu – volume: 166 start-page: 67 year: 2013 end-page: 78 ident: b0025 article-title: Metal organic framework based mixed matrix membranes: an increasingly important field of research with a large application potential publication-title: Microporous Mesoporous Mater. contributor: fullname: Kapteijn – volume: 26 start-page: 873 year: 1988 end-page: 887 ident: b0255 article-title: Analysis of high pressure adsorption of gases on activated carbon potential theory publication-title: Carbon N. Y. contributor: fullname: Schwarz – volume: 87 start-page: 120 year: 2012 end-page: 126 ident: b0150 article-title: A comparison of the CO2 capture characteristics of zeolites and metal-organic frameworks publication-title: Sep. Purif. Technol. contributor: fullname: Van Baten – volume: 60 start-page: 235 year: 1960 end-page: 241 ident: b0220 article-title: The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces publication-title: Chem. Rev. contributor: fullname: Dubinin – volume: 17 start-page: 1806 year: 2017 end-page: 1813 ident: b0185 article-title: Sustainable preparation of MIL-100(Fe) and its photocatalytic behavior in the degradation of methyl orange in water publication-title: Cryst. Growth Des. contributor: fullname: Guesh – year: 1998 ident: b0215 article-title: Adsorption Analysis: Equilibria and Kinetics, Series in Chem. Eng. contributor: fullname: Do – volume: 3 start-page: 500 year: 2013 end-page: 507 ident: b0295 article-title: Catalysis science & technology zeolites in Knoevenagel condensation † publication-title: Catal. Sci. Technol. contributor: fullname: Hora – volume: 211 start-page: 311 year: 2003 end-page: 334 ident: b0090 article-title: Mixed matrix membranes using carbon molecular sieves publication-title: J. Memb. Sci. contributor: fullname: Miller – year: 2018 ident: b0135 article-title: Fabrication and investigation of PEBAX/Fe-BTC, a high permeable and CO2 selective mixed matrix membrane publication-title: Chem. Eng. Res. Des. contributor: fullname: Alizadehdakhel – volume: 4 start-page: 3740 year: 2014 ident: b0045 article-title: Fabrication of porous matrix membrane as green template for water treatment publication-title: Sci. Rep. contributor: fullname: Huo – volume: 6 start-page: 3565 year: 2013 end-page: 3569 ident: b0120 article-title: CO2/N2 separations with mixed-matrix membranes containing Mg2(dobdc) nanocrystals publication-title: Energy Environ. Sci. contributor: fullname: Long – volume: 211 start-page: 91 year: 2003 end-page: 99 ident: b0080 article-title: Characterization of permeability and sorption in Matrimid/C60 mixed matrix membranes publication-title: J. Memb. Sci. contributor: fullname: He – volume: 38 start-page: 1363 year: 2017 end-page: 1370 ident: b0355 article-title: Mixed matrix membranes of Pebax1657 loaded with iron benzene-1,3,5-tricarboxylate for gas separation publication-title: Polym. Compos. contributor: fullname: Khanbabaei – volume: 305 start-page: 12 year: 2016 end-page: 18 ident: b0040 article-title: Conversion of xylose into furfural in a MOF-based mixed matrix membrane reactor publication-title: Chem. Eng. J. contributor: fullname: Jin – volume: 26 start-page: 3154 year: 2016 end-page: 3163 ident: b0100 article-title: Metal organic framework crystals in mixed-matrix membranes: impact of the filler morphology on the gas separation performance publication-title: Adv. Funct. Mater. contributor: fullname: Sabetghadam – volume: 57 start-page: 603 year: 1985 end-page: 619 ident: b0290 article-title: International union of pure commision on colloid and surface chemistry including catalysis - reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity publication-title: Pure Appl. Chem. contributor: fullname: Sing – volume: 313 start-page: 170 year: 2008 end-page: 181 ident: b0345 article-title: Gas permeability properties of Matrimid® membranes containing the metal-organic framework Cu-BPY-HFS publication-title: J. Mater. Chem. A contributor: fullname: Jr – volume: 175 start-page: 34 year: 2013 end-page: 42 ident: b0190 article-title: A combined computational and experimental study of high pressure and supercritical CO2 adsorption on basolite MOFs publication-title: Microporous Mesoporous Mater. contributor: fullname: Atilhan – volume: 100 start-page: 2820 year: 2007 end-page: 2822 ident: b0155 article-title: Synthesis and catalytic properties of MIL-100(Fe), an iron(iii) carboxylate with large pores publication-title: Chem. Commun. contributor: fullname: Horcajada – volume: 134 start-page: 10174 year: 2012 end-page: 10181 ident: b0195 article-title: How water fosters a remarkable 5-fold increase in low-pressure CO2 uptake within mesoporous MIL-100(Fe) publication-title: J. Am. Chem. Soc. contributor: fullname: Soubeyrand-Lenoir – volume: 51 start-page: 8149 year: 2012 end-page: 8177 ident: b0005 article-title: State-of-the-art of CO2 capture with ionic liquids publication-title: Ind. Eng. Chem. Res. contributor: fullname: Vlugt – volume: 359 start-page: 115 year: 2010 end-page: 125 ident: b0010 article-title: Membrane technologies for CO2 separation publication-title: J. Memb. Sci. contributor: fullname: Drioli – year: 1988 ident: b0250 article-title: The Properties of Gases and Liquids contributor: fullname: Sherwood – volume: 2 start-page: 2060 year: 2012 end-page: 2065 ident: b0300 article-title: Comparison of porous iron trimesates basolite F300 and MIL-100(Fe) as heterogeneous catalysts for lewis acid and oxidation reactions: roles of structural defects and stability publication-title: ACS Catal. contributor: fullname: Dhakshinamoorthy – volume: 243 start-page: 69 year: 2015 end-page: 75 ident: b0310 article-title: Adsorption of pentane isomers on metal-organic frameworks Cu-BTC and Fe-BTC publication-title: Catal. Today contributor: fullname: Jagiello – volume: 213 start-page: 14 year: 2015 end-page: 21 ident: b0305 article-title: Microporous and mesoporous materials liquid-assisted mechanochemical synthesis of an iron carboxylate metal organic framework and its evaluation in diesel fuel desulfurization publication-title: Microporous Mesoporous Mater. contributor: fullname: Pilloni – volume: 428 start-page: 445 year: 2013 end-page: 453 ident: b0320 article-title: Mixed matrix membranes containing MOFs for ethylene/ethane separation Part A: membrane preparation and characterization publication-title: J. Memb. Sci. contributor: fullname: Nijmeijer |
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•Metal-Organic Framework (MOF) Fe(BTC) evaluated as an adsorbent for CO2/N2 adsorption.•Fe(BTC)-based mixed matrix membranes (MMMs) were... |
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| Title | CO2/N2 gas separation using Fe(BTC)-based mixed matrix membranes: A view on the adsorptive and filler properties of metal-organic frameworks |
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