Site-selective functionalization of Si 6 R 6 siliconoids
The recent progress in the synthesis of partially substituted neutral silicon clusters (siliconoids) revealed unique structures and electronic anisotropies that are reminiscent of bulk and nano surfaces of silicon. Here, we report the selective 2-lithiation of the global minimum Si R siliconoid at a...
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| Published in: | Chemical science (Cambridge) Vol. 10; no. 16; pp. 4523 - 4530 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
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28-04-2019
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| Abstract | The recent progress in the synthesis of partially substituted neutral silicon clusters (siliconoids) revealed unique structures and electronic anisotropies that are reminiscent of bulk and nano surfaces of silicon. Here, we report the selective 2-lithiation of the global minimum Si
R
siliconoid at a different vertex than in the previously reported isomeric 4-lithiated derivative (R = 2,4,6-
Pr
C
H
). In order to enable an intuitive distinction of the vertices of the global minimum Si
R
scaffold (which can be considered the silicon analogue of benzene in terms of thermodynamic stability), we introduce a novel nomenclature in analogy to the
-
-
nomenclature of disubstituted benzenes. By treatment of the 2-lithiated Si
cluster with Me
SiCl, SiCl
H
B·SMe
, (Me
N)
PCl as well as with carboxylic acid chlorides RCOCl (R =
Bu, Ph) various 2-functionalized Si
clusters were obtained and characterized in solution and - in most cases - the solid state. The structural and spectroscopic effect of the position of the newly introduced functional group is discussed by comparison to the corresponding 4-functionalized derivatives. |
|---|---|
| AbstractList | The recent progress in the synthesis of partially substituted neutral silicon clusters (siliconoids) revealed unique structures and electronic anisotropies that are reminiscent of bulk and nano surfaces of silicon. Here, we report the selective 2-lithiation of the global minimum Si
6
R
6
siliconoid at a different vertex than in the previously reported isomeric 4-lithiated derivative (R = 2,4,6-
i
Pr
3
C
6
H
2
). In order to enable an intuitive distinction of the vertices of the global minimum Si
6
R
6
scaffold (which can be considered the silicon analogue of benzene in terms of thermodynamic stability), we introduce a novel nomenclature in analogy to the
ortho
–
meta
–
para
nomenclature of disubstituted benzenes. By treatment of the 2-lithiated Si
6
cluster with Me
3
SiCl, SiCl
4
H
3
B·SMe
2
, (Me
2
N)
2
PCl as well as with carboxylic acid chlorides RCOCl (R =
t
Bu, Ph) various 2-functionalized Si
6
clusters were obtained and characterized in solution and – in most cases – the solid state. The structural and spectroscopic effect of the position of the newly introduced functional group is discussed by comparison to the corresponding 4-functionalized derivatives. The recent progress in the synthesis of partially substituted neutral silicon clusters (siliconoids) revealed unique structures and electronic anisotropies that are reminiscent of bulk and nano surfaces of silicon. Here, we report the selective 2-lithiation of the global minimum Si R siliconoid at a different vertex than in the previously reported isomeric 4-lithiated derivative (R = 2,4,6- Pr C H ). In order to enable an intuitive distinction of the vertices of the global minimum Si R scaffold (which can be considered the silicon analogue of benzene in terms of thermodynamic stability), we introduce a novel nomenclature in analogy to the - - nomenclature of disubstituted benzenes. By treatment of the 2-lithiated Si cluster with Me SiCl, SiCl H B·SMe , (Me N) PCl as well as with carboxylic acid chlorides RCOCl (R = Bu, Ph) various 2-functionalized Si clusters were obtained and characterized in solution and - in most cases - the solid state. The structural and spectroscopic effect of the position of the newly introduced functional group is discussed by comparison to the corresponding 4-functionalized derivatives. |
| Author | Huch, Volker Scheschkewitz, David Leszczyńska, Kinga I Willmes, Philipp Poitiers, Nadine E Heider, Yannic |
| Author_xml | – sequence: 1 givenname: Yannic surname: Heider fullname: Heider, Yannic email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de – sequence: 2 givenname: Nadine E orcidid: 0000-0001-5393-741X surname: Poitiers fullname: Poitiers, Nadine E email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de – sequence: 3 givenname: Philipp surname: Willmes fullname: Willmes, Philipp email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de – sequence: 4 givenname: Kinga I surname: Leszczyńska fullname: Leszczyńska, Kinga I email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de – sequence: 5 givenname: Volker surname: Huch fullname: Huch, Volker email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de – sequence: 6 givenname: David orcidid: 0000-0001-5600-8034 surname: Scheschkewitz fullname: Scheschkewitz, David email: scheschkewitz@mx.uni-saarland.de organization: Krupp-Chair of General and Inorganic Chemistry , Saarland University , 66123 Saarbrücken , Germany . Email: scheschkewitz@mx.uni-saarland.de |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/31057782$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/ja01506a003 10.1063/1.120452 10.1002/qua.10630 10.1515/zpch-1931-15403 10.1002/anie.201811331 10.1002/anie.201807080 10.1038/122810c0 10.1002/anie.201310475 10.1002/anie.200462730 10.1039/C5CC09878E 10.1103/RevModPhys.30.159 10.1002/anie.201102623 10.1063/1.121367 10.1515/MGMC.2002.25.1-2.93 10.1002/anie.200501289 10.1021/jp004223n 10.1002/ange.200805289 10.1021/ja307344f 10.1021/ja00758a016 10.1126/science.1181771 10.1002/anie.201603951 10.1021/cr60165a003 10.1002/chem.201805442 10.1021/ja0488075 10.1002/anie.200804965 10.1016/j.ccr.2006.09.007 10.1002/anie.201001630 10.1039/C4SC00365A 10.1021/ja00046a035 10.1021/ja104810u 10.1021/ja409074m 10.1002/anie.201209906 10.1002/anie.200353406 10.1016/j.ccr.2004.08.020 10.1038/ncomms6353 10.1021/ja00198a085 10.1246/cl.130856 10.1021/jp0467696 10.1021/ja00076a061 10.1039/C8DT01009A 10.1021/cr00002a004 10.1002/anie.201511037 10.1126/science.252.5009.1085 10.1002/1521-3773(20021104)41:21<4006::AID-ANIE4006>3.0.CO;2-I 10.1063/1.114338 10.1021/om049921z 10.1002/anie.201208506 10.1103/PhysRevB.64.125413 10.1021/om0497137 10.1002/zaac.201800227 10.1039/c0cs00210k 10.1103/PhysRevLett.55.2853 10.1021/ja00013a058 10.1021/ic302802h 10.1246/cl.2007.368 10.1039/tf9383400156 10.1002/anie.201003988 10.1002/ange.200701203 10.1002/anie.198700013 10.1021/om800881y 10.1016/S0022-328X(00)91569-9 10.1007/430_2010_33 10.1021/ja00044a011 10.1063/1.1731993 10.1021/cr020406p 10.1021/cr00037a600 10.1021/ja00180a027 |
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| References | Fischer (C8SC05591B-(cit15)/*[position()=1]) 2005; 44 Dinadayalane (C8SC05591B-(cit37)/*[position()=1]) 2004; 108 Newton (C8SC05591B-(cit38)/*[position()=1]) 1972; 93 Ge (C8SC05591B-(cit10)/*[position()=1]) 2003; 95 Rechtsteiner (C8SC05591B-(cit6)/*[position()=1]) 2001; 105 International Union of Pure and Applied Chemistry (C8SC05591B-(cit48)/*[position()=1]) 1979 Hammett (C8SC05591B-(cit70)/*[position()=1]) 1938; 34 Kessels (C8SC05591B-(cit8)/*[position()=1]) 1998; 72 Goicoechea (C8SC05591B-(cit28)/*[position()=1]) 2004; 126 Heider (C8SC05591B-(cit4)/*[position()=1]) 2018; 47 Zintl (C8SC05591B-(cit25)/*[position()=1]) 1931; 154 Sita (C8SC05591B-(cit60)/*[position()=1]) 1991; 113 Jana (C8SC05591B-(cit49)/*[position()=1]) 2014; 53 Iwamoto (C8SC05591B-(cit2)/*[position()=1]) 2014; 43 Nied (C8SC05591B-(cit16)/*[position()=1]) 2010; 132 Abersfelder (C8SC05591B-(cit22)/*[position()=1]) 2010; 327 Abersfelder (C8SC05591B-(cit23)/*[position()=1]) 2011; 50 Grützmacher (C8SC05591B-(cit42)/*[position()=1]) 2002; 41 Nied (C8SC05591B-(cit43)/*[position()=1]) 2011; 40 Davidson (C8SC05591B-(cit5)/*[position()=1]) 1970; 24 Waibel (C8SC05591B-(cit29)/*[position()=1]) 2013; 52 Jaffe (C8SC05591B-(cit72)/*[position()=1]) 1953; 53 Neergaard Waltenburg (C8SC05591B-(cit13)/*[position()=1]) 1995; 95 Hammett (C8SC05591B-(cit73)/*[position()=1]) 1970 Kratzert (C8SC05591B-(cit46)/*[position()=1]) 2013; 52 Scheschkewitz (C8SC05591B-(cit14)/*[position()=1]) 2005; 44 Iwamoto (C8SC05591B-(cit54)/*[position()=1]) 2007; 36 Leszczyńska (C8SC05591B-(cit33)/*[position()=1]) 2019 IUPAC Nomenclature of Organic Chemistry 1957 (C8SC05591B-(cit47)/*[position()=1]) 1960; 82 Scharfe (C8SC05591B-(cit27)/*[position()=1]) 2011; 50 Iwamoto (C8SC05591B-(cit19)/*[position()=1]) 2014; 5 Tsurusaki (C8SC05591B-(cit17)/*[position()=1]) 2013; 135 Hadjisavvas (C8SC05591B-(cit11)/*[position()=1]) 2001; 64 Juselius (C8SC05591B-(cit65)/*[position()=1]) 2004; 121 Lerner (C8SC05591B-(cit69)/*[position()=1]) 2005; 249 Breher (C8SC05591B-(cit1)/*[position()=1]) 2007; 251 Kyushin (C8SC05591B-(cit3)/*[position()=1]) 2017; vol. 1 Dilmac (C8SC05591B-(cit39)/*[position()=1]) 2017; 56 Watanabe (C8SC05591B-(cit9)/*[position()=1]) 1997; 71 Raghavachari (C8SC05591B-(cit55)/*[position()=1]) 1985; 55 Shaik (C8SC05591B-(cit44)/*[position()=1]) 1992; 114 Ishida (C8SC05591B-(cit18)/*[position()=1]) 2013; 52 Power (C8SC05591B-(cit41)/*[position()=1]) 2003; 103 Richards (C8SC05591B-(cit62)/*[position()=1]) 2004; 23 Jarrold (C8SC05591B-(cit12)/*[position()=1]) 1991; 252 Cox (C8SC05591B-(cit36)/*[position()=1]) 1958; 30 Sindlinger (C8SC05591B-(cit50)/*[position()=1]) 2014; 5 Xiong (C8SC05591B-(cit52)/*[position()=1]) 2017; 119 Lorenz (C8SC05591B-(cit31)/*[position()=1]) 2018; 57 Henneberger (C8SC05591B-(cit30)/*[position()=1]) 2018; 644 Moteki (C8SC05591B-(cit24)/*[position()=1]) 2009; 28 Wu (C8SC05591B-(cit45)/*[position()=1]) 2009; 48 Nieder (C8SC05591B-(cit56)/*[position()=1]) 2016; 52 Schiegerl (C8SC05591B-(cit20)/*[position()=1]) 2018; 24 Murakami (C8SC05591B-(cit7)/*[position()=1]) 1995; 67 Peng (C8SC05591B-(cit53)/*[position()=1]) 2004; 43 Nied (C8SC05591B-(cit58)/*[position()=1]) 2009; 121 Hansch (C8SC05591B-(cit68)/*[position()=1]) 1991; 91 Fässler (C8SC05591B-(cit26)/*[position()=1]) 2011; 140 Breher (C8SC05591B-(cit40)/*[position()=1]) 2007; 251 Sita (C8SC05591B-(cit61)/*[position()=1]) 1992; 114 Sita (C8SC05591B-(cit57)/*[position()=1]) 1989; 11 Drost (C8SC05591B-(cit64)/*[position()=1]) 2002; 25 Richards (C8SC05591B-(cit63)/*[position()=1]) 2004; 23 Willmes (C8SC05591B-(cit32)/*[position()=1]) 2016; 55 Sita (C8SC05591B-(cit59)/*[position()=1]) 1990; 112 Spiesecke (C8SC05591B-(cit74)/*[position()=1]) 1961; 35 Veith (C8SC05591B-(cit51)/*[position()=1]) 1987; 26 Glending (C8SC05591B-(cit35)/*[position()=1]) 1993; 115 Abersfelder (C8SC05591B-(cit21)/*[position()=1]) 2012; 134 Hammett (C8SC05591B-(cit71)/*[position()=1]) 1940 Berger (C8SC05591B-(cit66)/*[position()=1]) 2010; 49 Lonsdale (C8SC05591B-(cit34)/*[position()=1]) 1928; 122 |
| References_xml | – volume: 82 start-page: 5545 year: 1960 ident: C8SC05591B-(cit47)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01506a003 contributor: fullname: IUPAC Nomenclature of Organic Chemistry 1957 – volume: 71 start-page: 1207 year: 1997 ident: C8SC05591B-(cit9)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.120452 contributor: fullname: Watanabe – volume: 95 start-page: 617 year: 2003 ident: C8SC05591B-(cit10)/*[position()=1] publication-title: Int. J. Quantum Chem. doi: 10.1002/qua.10630 contributor: fullname: Ge – volume: 154 start-page: 47 year: 1931 ident: C8SC05591B-(cit25)/*[position()=1] publication-title: Z. Phys. Chem. Abt. A doi: 10.1515/zpch-1931-15403 contributor: fullname: Zintl – year: 2019 ident: C8SC05591B-(cit33)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201811331 contributor: fullname: Leszczyńska – volume: 57 start-page: 12956 year: 2018 ident: C8SC05591B-(cit31)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201807080 contributor: fullname: Lorenz – volume: 122 start-page: 810 year: 1928 ident: C8SC05591B-(cit34)/*[position()=1] publication-title: Nature doi: 10.1038/122810c0 contributor: fullname: Lonsdale – volume: 53 start-page: 3514 year: 2014 ident: C8SC05591B-(cit49)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201310475 contributor: fullname: Jana – volume: 44 start-page: 2954 year: 2005 ident: C8SC05591B-(cit14)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200462730 contributor: fullname: Scheschkewitz – volume: 52 start-page: 2799 year: 2016 ident: C8SC05591B-(cit56)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/C5CC09878E contributor: fullname: Nieder – volume: 30 start-page: 159 issue: 1 year: 1958 ident: C8SC05591B-(cit36)/*[position()=1] publication-title: Rev. Mod. Phys. doi: 10.1103/RevModPhys.30.159 contributor: fullname: Cox – start-page: 184 volume-title: Physical Organic Chemistry year: 1940 ident: C8SC05591B-(cit71)/*[position()=1] contributor: fullname: Hammett – volume: vol. 1 volume-title: Organosilicon Compounds: Theory and Experiment (Synthesis) year: 2017 ident: C8SC05591B-(cit3)/*[position()=1] contributor: fullname: Kyushin – volume: 50 start-page: 7936 year: 2011 ident: C8SC05591B-(cit23)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201102623 contributor: fullname: Abersfelder – volume: 72 start-page: 2397 year: 1998 ident: C8SC05591B-(cit8)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.121367 contributor: fullname: Kessels – volume: 25 start-page: 93 year: 2002 ident: C8SC05591B-(cit64)/*[position()=1] publication-title: Main Group Met. Chem. doi: 10.1515/MGMC.2002.25.1-2.93 contributor: fullname: Drost – volume: 44 start-page: 7884 year: 2005 ident: C8SC05591B-(cit15)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200501289 contributor: fullname: Fischer – volume-title: Physical Organic Chemistry year: 1970 ident: C8SC05591B-(cit73)/*[position()=1] contributor: fullname: Hammett – volume: 105 start-page: 4188 year: 2001 ident: C8SC05591B-(cit6)/*[position()=1] publication-title: J. Phys. Chem. B doi: 10.1021/jp004223n contributor: fullname: Rechtsteiner – volume: 121 start-page: 1439 year: 2009 ident: C8SC05591B-(cit58)/*[position()=1] publication-title: Angew. Chem. doi: 10.1002/ange.200805289 contributor: fullname: Nied – volume: 134 start-page: 16008 year: 2012 ident: C8SC05591B-(cit21)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja307344f contributor: fullname: Abersfelder – volume: 93 start-page: 773 year: 1972 ident: C8SC05591B-(cit38)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00758a016 contributor: fullname: Newton – volume: 327 start-page: 564 year: 2010 ident: C8SC05591B-(cit22)/*[position()=1] publication-title: Science doi: 10.1126/science.1181771 contributor: fullname: Abersfelder – volume: 56 start-page: 5684 year: 2017 ident: C8SC05591B-(cit39)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201603951 contributor: fullname: Dilmac – volume: 53 start-page: 191 year: 1953 ident: C8SC05591B-(cit72)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr60165a003 contributor: fullname: Jaffe – volume: 24 start-page: 19171 year: 2018 ident: C8SC05591B-(cit20)/*[position()=1] publication-title: Chem. Eur. J. doi: 10.1002/chem.201805442 contributor: fullname: Schiegerl – volume: 126 start-page: 6860 year: 2004 ident: C8SC05591B-(cit28)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja0488075 contributor: fullname: Goicoechea – volume: 48 start-page: 1407 year: 2009 ident: C8SC05591B-(cit45)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200804965 contributor: fullname: Wu – volume: 251 start-page: 1007 year: 2007 ident: C8SC05591B-(cit1)/*[position()=1] publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2006.09.007 contributor: fullname: Breher – volume: 50 start-page: 3630 year: 2011 ident: C8SC05591B-(cit27)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201001630 contributor: fullname: Scharfe – volume: 5 start-page: 2739 year: 2014 ident: C8SC05591B-(cit50)/*[position()=1] publication-title: Chem. Sci. doi: 10.1039/C4SC00365A contributor: fullname: Sindlinger – volume: 114 start-page: 7861 year: 1992 ident: C8SC05591B-(cit44)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00046a035 contributor: fullname: Shaik – volume: 132 start-page: 10264 year: 2010 ident: C8SC05591B-(cit16)/*[position()=1] publication-title: Am. Chem. Soc. doi: 10.1021/ja104810u contributor: fullname: Nied – volume: 135 start-page: 16340 year: 2013 ident: C8SC05591B-(cit17)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja409074m contributor: fullname: Tsurusaki – volume: 52 start-page: 4478 year: 2013 ident: C8SC05591B-(cit46)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201209906 contributor: fullname: Kratzert – volume: 43 start-page: 3443 year: 2004 ident: C8SC05591B-(cit53)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200353406 contributor: fullname: Peng – volume: 249 start-page: 781 year: 2005 ident: C8SC05591B-(cit69)/*[position()=1] publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2004.08.020 contributor: fullname: Lerner – volume: 5 start-page: 5353 year: 2014 ident: C8SC05591B-(cit19)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/ncomms6353 contributor: fullname: Iwamoto – volume: 11 start-page: 6454 year: 1989 ident: C8SC05591B-(cit57)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00198a085 contributor: fullname: Sita – volume: 43 start-page: 164 year: 2014 ident: C8SC05591B-(cit2)/*[position()=1] publication-title: Chem. Lett. doi: 10.1246/cl.130856 contributor: fullname: Iwamoto – volume: 108 start-page: 11433 year: 2004 ident: C8SC05591B-(cit37)/*[position()=1] publication-title: J. Phys. Chem. A doi: 10.1021/jp0467696 contributor: fullname: Dinadayalane – volume: 115 start-page: 10952 issue: 23 year: 1993 ident: C8SC05591B-(cit35)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00076a061 contributor: fullname: Glending – volume: 47 start-page: 7104 year: 2018 ident: C8SC05591B-(cit4)/*[position()=1] publication-title: Dalton Trans. doi: 10.1039/C8DT01009A contributor: fullname: Heider – volume: 91 start-page: 165 year: 1991 ident: C8SC05591B-(cit68)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr00002a004 contributor: fullname: Hansch – volume: 55 start-page: 2907 year: 2016 ident: C8SC05591B-(cit32)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201511037 contributor: fullname: Willmes – volume: 252 start-page: 1085 year: 1991 ident: C8SC05591B-(cit12)/*[position()=1] publication-title: Science doi: 10.1126/science.252.5009.1085 contributor: fullname: Jarrold – volume: 41 start-page: 4006 year: 2002 ident: C8SC05591B-(cit42)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/1521-3773(20021104)41:21<4006::AID-ANIE4006>3.0.CO;2-I contributor: fullname: Grützmacher – volume: 67 start-page: 2341 year: 1995 ident: C8SC05591B-(cit7)/*[position()=1] publication-title: Appl. Phys. Lett. doi: 10.1063/1.114338 contributor: fullname: Murakami – volume: 23 start-page: 2841 year: 2004 ident: C8SC05591B-(cit63)/*[position()=1] publication-title: Organometallics doi: 10.1021/om049921z contributor: fullname: Richards – volume: 52 start-page: 2507 year: 2013 ident: C8SC05591B-(cit18)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201208506 contributor: fullname: Ishida – volume: 64 start-page: 125413 year: 2001 ident: C8SC05591B-(cit11)/*[position()=1] publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.64.125413 contributor: fullname: Hadjisavvas – volume: 23 start-page: 4009 year: 2004 ident: C8SC05591B-(cit62)/*[position()=1] publication-title: Organometallics doi: 10.1021/om0497137 contributor: fullname: Richards – volume: 644 start-page: 1018 year: 2018 ident: C8SC05591B-(cit30)/*[position()=1] publication-title: Z. Anorg. Allg. Chem. doi: 10.1002/zaac.201800227 contributor: fullname: Henneberger – volume: 40 start-page: 3455 year: 2011 ident: C8SC05591B-(cit43)/*[position()=1] publication-title: Chem. Soc. Rev. doi: 10.1039/c0cs00210k contributor: fullname: Nied – volume: 55 start-page: 2853 year: 1985 ident: C8SC05591B-(cit55)/*[position()=1] publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.55.2853 contributor: fullname: Raghavachari – volume: 113 start-page: 5070 year: 1991 ident: C8SC05591B-(cit60)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00013a058 contributor: fullname: Sita – volume: 52 start-page: 5861 year: 2013 ident: C8SC05591B-(cit29)/*[position()=1] publication-title: Inorg. Chem. doi: 10.1021/ic302802h contributor: fullname: Waibel – volume: 36 start-page: 368 year: 2007 ident: C8SC05591B-(cit54)/*[position()=1] publication-title: Chem. Lett. doi: 10.1246/cl.2007.368 contributor: fullname: Iwamoto – volume: 121 start-page: 3952 year: 2004 ident: C8SC05591B-(cit65)/*[position()=1] publication-title: Chem. Phys. contributor: fullname: Juselius – volume: 34 start-page: 156 year: 1938 ident: C8SC05591B-(cit70)/*[position()=1] publication-title: Trans. Faraday Soc. doi: 10.1039/tf9383400156 contributor: fullname: Hammett – volume-title: Nomenclature of Organic Chemistry, sections A, B, C, D, E, F, H year: 1979 ident: C8SC05591B-(cit48)/*[position()=1] contributor: fullname: International Union of Pure and Applied Chemistry – volume: 49 start-page: 10006 year: 2010 ident: C8SC05591B-(cit66)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201003988 contributor: fullname: Berger – volume: 251 start-page: 1007 year: 2007 ident: C8SC05591B-(cit40)/*[position()=1] publication-title: Coord. Chem. Rev. doi: 10.1016/j.ccr.2006.09.007 contributor: fullname: Breher – volume: 119 start-page: 4595 year: 2017 ident: C8SC05591B-(cit52)/*[position()=1] publication-title: Angew. Chem. doi: 10.1002/ange.200701203 contributor: fullname: Xiong – volume: 26 start-page: 1 year: 1987 ident: C8SC05591B-(cit51)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.198700013 contributor: fullname: Veith – volume: 28 start-page: 2218 year: 2009 ident: C8SC05591B-(cit24)/*[position()=1] publication-title: Organometallics doi: 10.1021/om800881y contributor: fullname: Moteki – volume: 24 start-page: 97 year: 1970 ident: C8SC05591B-(cit5)/*[position()=1] publication-title: J. Organomet. Chem. doi: 10.1016/S0022-328X(00)91569-9 contributor: fullname: Davidson – volume: 140 start-page: 91 year: 2011 ident: C8SC05591B-(cit26)/*[position()=1] publication-title: Struct. Bond. doi: 10.1007/430_2010_33 contributor: fullname: Fässler – volume: 114 start-page: 7024 year: 1992 ident: C8SC05591B-(cit61)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00044a011 contributor: fullname: Sita – volume: 35 start-page: 731 year: 1961 ident: C8SC05591B-(cit74)/*[position()=1] publication-title: J. Chem. Phys. doi: 10.1063/1.1731993 contributor: fullname: Spiesecke – volume: 103 start-page: 789 year: 2003 ident: C8SC05591B-(cit41)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr020406p contributor: fullname: Power – volume: 95 start-page: 1589 year: 1995 ident: C8SC05591B-(cit13)/*[position()=1] publication-title: Chem. Rev. doi: 10.1021/cr00037a600 contributor: fullname: Neergaard Waltenburg – volume: 112 start-page: 8839 year: 1990 ident: C8SC05591B-(cit59)/*[position()=1] publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00180a027 contributor: fullname: Sita |
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