XPS Investigation of Co-Ni Oxidized Compounds Surface Using Peak-On-Satellite Ratio. Application to Co 20 Ni 80 Passive Layer Structure and Composition

• Published in: ACS omega Vol. 9; no. 39; pp. 40707 - 40722
• Main Authors: Laïk, Barbara, Richet, Morgane, Emery, Nicolas, Bach, Stephane, Perrière, Loïc, Cotrebil, Yvan, Russier, Vincent, Guillot, Ivan, Dubot, Pierre
• Format: Journal Article
• Language: English
• Published: United States ACS Publications 01-10-2024
• Subjects: Chemical Sciences
• ISSN: 2470-1343; 2470-1343
• DOI: 10.1021/acsomega.4c05082

XPS data processing for cobalt and nickel core-level peaks can be complicated. This is especially true when analyzing a mixture of oxide/oxyhydroxide/hydroxide compounds of these metals. The objective of this study is to develop a method for decomposing XPS spectra of 2p core levels for nickel and cobalt-oxidized compounds. This methodology was then employed to study the passivation layer of the Co
Ni
alloy. The analysis of Ni
and Co
photo peaks using a homemade code based on core-level peak structure and satellites enables us to determine the chemical composition of the surface layer, knowledge of which is particularly important because it is directly linked to the anticorrosive properties it confers on the surface of the oxidized alloy. The XPS analysis, coupled with sequential ion sputtering, revealed that the passive layer of the Co
Ni
alloy is heterogeneously covered with either oxidized cobalt compounds or oxidized nickel compounds. The method used also demonstrates that the chemical heterogeneity is associated with the thickness heterogeneity of the passive layer.