Adsorptive removal of heavy metals from wastewater using Cobalt-diphenylamine (Co-DPA) complex

• Published in: BMC chemistry Vol. 18; no. 1; pp. 23 - 15
• Main Authors: Yimer, Mesfin, Ansari, Shagufi Naz, Berehe, Biniyam Abdu, Gudimella, Krishna Kanthi, Gedda, Gangaraju, Girma, Wubshet Mekonnen, Hasan, Nazim, Tasneem, Shadma
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 29-01-2024; BioMed Central Ltd; Springer Nature B.V; BMC
• Subjects: Adsorbents; Adsorption; Adsorptivity; Cadmium; Chemistry; Chemistry and Materials Science; Chemistry/Food Science; Cobalt; Cobalt compounds; Cu-DPA; Economic development; Freundlich isotherm; Heavy metals; Industrial development; Lead; Metal industry; Purification; Real estate development; Real sample; Sewage; Trivalent chromium; Wastewater; Wastewater treatment; Cu-DPA; Real sample; Adsorption; Wastewater; Freundlich isotherm
• ISSN: 2661-801X; 2661-801X
• DOI: 10.1186/s13065-024-01128-z

Heavy metals like Cadmium, Lead, and Chromium are the pollutants emitted into the environment through industrial development. In this work, a new diphenylamine coordinated cobalt complex (Co-DPA) has been synthesized and tested for its efficiency in removing heavy metals from wastewater, and its adsorption capacity was investigated. The effectiveness of heavy metals removal by Co-DPA was evaluated by adjusting the adsorption parameters, such as adsorbent dose, pH, initial metals concentration, and adsorption period. Heavy metal concentrations in real sample were 0.267, 0.075, and 0.125 mg/L for Cd
2+
, Pb
2+
, and Cr
3+
before using as-synthesized Co-DPA to treat wastewater. After being treated with synthesized Co-DPA the concentration of heavy metals was reduced to 0.0129, 0.00028, 0.00054 mg/L for Cd
2+
, Pb
2+
, and Cr
3+
, respectively, in 80 min. The removal efficiency was 95.6%, 99.5%, and 99.5% for the respective metals. The adsorption process fitted satisfactorily with Freundlich isotherm with R
2
(0.999, 0.997, 0.995) for Cd
2+
, Pb
2+
, and Cr
3+
, respectively. The kinetic data obeyed the pseudo-second order for Cd
2+
and Cr
2+
and the pseudo-first order for Pb
2+
. Based on the results obtained within the framework of this study, it is concluded that the as-synthesized Co-DPA is a good adsorbent to eliminate heavy metal ions like Cd
2+
, Pb
2+
, and Cr
3+
from wastewater solution. In general, Co-DPA is a promising new material for the removal of heavy metal ions from water.
Graphical Abstract