Improved Efficiency and Lifetime of Deep‐Blue Hyperfluorescent Organic Light‐Emitting Diode using Pt(II) Complex as Phosphorescent Sensitizer
Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer an...
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| Published in: | Advanced science Vol. 8; no. 16; pp. e2100586 - n/a |
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| Main Authors: | , , , , , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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Weinheim
John Wiley & Sons, Inc
01-08-2021
John Wiley and Sons Inc Wiley |
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| Abstract | Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and ν‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore (ν‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A−1, and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m−2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance.
A novel technology of deep‐blue hyperfluorescent organic light‐emitting diode using Pt(II) complex as phosphorescent sensitizer and multiple resonance‐based fluorophore can pave the way of commercialization. |
|---|---|
| AbstractList | Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and
ν
‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore (
ν
‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate
y
below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A
−1
, and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m
−2
compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance.
A novel technology of deep‐blue hyperfluorescent organic light‐emitting diode using Pt(II) complex as phosphorescent sensitizer and multiple resonance‐based fluorophore can pave the way of commercialization. Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and ν ‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore ( ν ‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A −1 , and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m −2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance. Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and ν‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore (ν‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A−1, and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m−2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance. Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and ν‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore (ν‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A−1, and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m−2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance. A novel technology of deep‐blue hyperfluorescent organic light‐emitting diode using Pt(II) complex as phosphorescent sensitizer and multiple resonance‐based fluorophore can pave the way of commercialization. Although the organic light-emitting diode (OLED) has been successfully commercialized, the development of deep-blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7-dtb) as a phosphorescent sensitizer and a hydrocarbon-based and multiple resonance-based fluorophore as an emitter (TBPDP and ν-DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep-blue hyperfluorescent OLED using a multiple resonance-based fluorophore (ν-DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A-1 , and 19-fold improved half-lifetime of 253.8 h at 1000 cd m-2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance. Abstract Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long lifetime remains a challenge. Here, a novel hyperfluorescent OLED that incorporates the Pt(II) complex (PtON7‐dtb) as a phosphorescent sensitizer and a hydrocarbon‐based and multiple resonance‐based fluorophore as an emitter (TBPDP and ν‐DABNA) in the device emissive layer (EML), is proposed. Such an EML system can promote efficient energy transfer from the triplet excited states of the sensitizer to the singlet excited states of the fluorophore, thus significantly improving the efficiency and lifetime of the device. As a result, a deep‐blue hyperfluorescent OLED using a multiple resonance‐based fluorophore (ν‐DABNA) with Commission Internationale de L'Eclairage chromaticity coordinate y below 0.1 is demonstrated, which attains a narrow full width at half maximum of ≈17 nm, fourfold increased maximum current efficiency of 48.9 cd A−1, and 19‐fold improved half‐lifetime of 253.8 h at 1000 cd m−2 compared to a conventional phosphorescent OLED. The findings can lead to better understanding of the hyperfluorescent OLEDs with high performance. |
| Author | Kim, Ji Whan Kim, Joonghyuk Jeong, Hyein Ihn, Soo‐Ghang Choi, Hyeonho Maruyama, Yusuke Makida Son, Won‐Joon Nam, Sungho Lee, Jaesang Bae, Hye Jin Jeong, Daun Kim, Jong Soo |
| AuthorAffiliation | 3 Display Research Center Samsung Display Co. 1 Samsung‐ro Yongin‐si Gyeonggi‐do 17113 Republic of Korea 1 Samsung Advanced Institute of Technology Samsung Electronics Co., Ltd. 130 Samsung‐ro Suwon‐si Gyeonggi‐do 16678 Republic of Korea 2 Data and Information Technology Center Samsung Electronics Co., Ltd. 1 Samsungjeonja‐ro Hwaseong‐si Gyeonggi‐do 18448 Republic of Korea 4 Department of Electrical and Computer Engineering Inter‐University Semiconductor Research Center Seoul National University Seoul 08826 Republic of Korea |
| AuthorAffiliation_xml | – name: 4 Department of Electrical and Computer Engineering Inter‐University Semiconductor Research Center Seoul National University Seoul 08826 Republic of Korea – name: 3 Display Research Center Samsung Display Co. 1 Samsung‐ro Yongin‐si Gyeonggi‐do 17113 Republic of Korea – name: 1 Samsung Advanced Institute of Technology Samsung Electronics Co., Ltd. 130 Samsung‐ro Suwon‐si Gyeonggi‐do 16678 Republic of Korea – name: 2 Data and Information Technology Center Samsung Electronics Co., Ltd. 1 Samsungjeonja‐ro Hwaseong‐si Gyeonggi‐do 18448 Republic of Korea |
| Author_xml | – sequence: 1 givenname: Sungho surname: Nam fullname: Nam, Sungho organization: Samsung Electronics Co., Ltd – sequence: 2 givenname: Ji Whan surname: Kim fullname: Kim, Ji Whan organization: Samsung Electronics Co., Ltd – sequence: 3 givenname: Hye Jin surname: Bae fullname: Bae, Hye Jin organization: Samsung Electronics Co., Ltd – sequence: 4 givenname: Yusuke Makida surname: Maruyama fullname: Maruyama, Yusuke Makida organization: Samsung Electronics Co., Ltd – sequence: 5 givenname: Daun surname: Jeong fullname: Jeong, Daun organization: Samsung Electronics Co., Ltd – sequence: 6 givenname: Joonghyuk surname: Kim fullname: Kim, Joonghyuk organization: Samsung Electronics Co., Ltd – sequence: 7 givenname: Jong Soo surname: Kim fullname: Kim, Jong Soo organization: Samsung Electronics Co., Ltd – sequence: 8 givenname: Won‐Joon surname: Son fullname: Son, Won‐Joon organization: Samsung Electronics Co., Ltd – sequence: 9 givenname: Hyein surname: Jeong fullname: Jeong, Hyein organization: Samsung Display Co – sequence: 10 givenname: Jaesang surname: Lee fullname: Lee, Jaesang organization: Seoul National University – sequence: 11 givenname: Soo‐Ghang surname: Ihn fullname: Ihn, Soo‐Ghang email: sg.ihn@samsung.com organization: Samsung Electronics Co., Ltd – sequence: 12 givenname: Hyeonho orcidid: 0000-0002-6884-8193 surname: Choi fullname: Choi, Hyeonho email: hono.choi@samsung.com organization: Samsung Electronics Co., Ltd |
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| Snippet | Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and long... Although the organic light-emitting diode (OLED) has been successfully commercialized, the development of deep-blue OLEDs with high efficiency and long... Abstract Although the organic light‐emitting diode (OLED) has been successfully commercialized, the development of deep‐blue OLEDs with high efficiency and... |
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| Title | Improved Efficiency and Lifetime of Deep‐Blue Hyperfluorescent Organic Light‐Emitting Diode using Pt(II) Complex as Phosphorescent Sensitizer |
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