Surface modification using heptafluorobutyric acid to produce highly stable Li metal anodes
The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique usi...
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Published in: | Nature communications Vol. 14; no. 1; p. 2883 |
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Abstract | The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm
−2
) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance.
Development of lithium metal anodes is limited due to the dendritic growth and high reactivity of metal lithium. Here authors propose a surface modification strategy using heptafluorobutyric acid to form a lithiophilic interface, which enables uniform Li deposition and improving battery performance. |
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AbstractList | Abstract The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm−2) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance. The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm −2 ) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance. Development of lithium metal anodes is limited due to the dendritic growth and high reactivity of metal lithium. Here authors propose a surface modification strategy using heptafluorobutyric acid to form a lithiophilic interface, which enables uniform Li deposition and improving battery performance. The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm −2 ) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance. The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm ) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance. The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic growth in carbonate-based electrolytes limit its application. To address these issues, we propose a novel surface modification technique using heptafluorobutyric acid. In-situ spontaneous reaction between Li and the organic acid generates a lithiophilic interface of lithium heptafluorobutyrate for dendrite-free uniform Li deposition, which significantly improves the cycle stability (Li/Li symmetric cells >1200 h at 1.0 mA cm−2) and Coulombic efficiency (>99.3%) in conventional carbonate-based electrolytes. This lithiophilic interface also enables full batteries to achieve 83.2% capacity retention over 300 cycles under realistic testing condition. Lithium heptafluorobutyrate interface acts as an electrical bridge for uniform lithium-ion flux between Li anode and plating Li, which minimizes the occurrence of tortuous lithium dendrites and lowers interface impedance.Development of lithium metal anodes is limited due to the dendritic growth and high reactivity of metal lithium. Here authors propose a surface modification strategy using heptafluorobutyric acid to form a lithiophilic interface, which enables uniform Li deposition and improving battery performance. |
ArticleNumber | 2883 |
Author | Lin, Zhen Sun, Miaolan Dai, Peng Huang, Ling Wu, Tairui Huang, Zheng Wu, Deyin Sun, Shigang Lee, Bruce Chen, Hui Yang, Jian Zhang, Yinggan Huang, Yixin Shi, Chenguang Wang, Chongtai Xie, Yuxiang Hua, Yingjie Liu, Shishi |
Author_xml | – sequence: 1 givenname: Yuxiang surname: Xie fullname: Xie, Yuxiang organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 2 givenname: Yixin surname: Huang fullname: Huang, Yixin organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 3 givenname: Yinggan surname: Zhang fullname: Zhang, Yinggan organization: College of Materials, Xiamen University, Xiamen Key Laboratory of Electronic Ceramic Materials and Devices – sequence: 4 givenname: Tairui surname: Wu fullname: Wu, Tairui organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 5 givenname: Shishi surname: Liu fullname: Liu, Shishi organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 6 givenname: Miaolan surname: Sun fullname: Sun, Miaolan organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 7 givenname: Bruce surname: Lee fullname: Lee, Bruce organization: Reliability Safety Department & Mechanism Simulation, Contemporary Amperex Technology Co., Limited – sequence: 8 givenname: Zhen surname: Lin fullname: Lin, Zhen organization: Reliability Safety Department & Mechanism Simulation, Contemporary Amperex Technology Co., Limited – sequence: 9 givenname: Hui surname: Chen fullname: Chen, Hui organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 10 givenname: Peng surname: Dai fullname: Dai, Peng organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 11 givenname: Zheng surname: Huang fullname: Huang, Zheng organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 12 givenname: Jian surname: Yang fullname: Yang, Jian organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 13 givenname: Chenguang surname: Shi fullname: Shi, Chenguang organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 14 givenname: Deyin orcidid: 0000-0001-5260-2861 surname: Wu fullname: Wu, Deyin organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 15 givenname: Ling orcidid: 0000-0003-2403-1170 surname: Huang fullname: Huang, Ling email: huangl@xmu.edu.cn organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University – sequence: 16 givenname: Yingjie surname: Hua fullname: Hua, Yingjie organization: Hainan Normal University, Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province – sequence: 17 givenname: Chongtai surname: Wang fullname: Wang, Chongtai email: wangct@hainnu.edu.cn organization: Hainan Normal University, Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province – sequence: 18 givenname: Shigang orcidid: 0000-0003-2327-4090 surname: Sun fullname: Sun, Shigang email: sgsun@xmu.edu.cn organization: College of Chemistry and Chemical Engineering, State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University |
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Snippet | The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and dendritic... Abstract The Li metal is an ideal anode material owing to its high theoretical specific capacity and low electrode potential. However, its high reactivity and... |
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Title | Surface modification using heptafluorobutyric acid to produce highly stable Li metal anodes |
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