High-performance alkaline water electrolyzers based on Ru-perturbed Cu nanoplatelets cathode

Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm 2 . Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm 2 ) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cat...

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Published in:Nature communications Vol. 14; no. 1; p. 4680
Main Authors: Zuo, Yong, Bellani, Sebastiano, Ferri, Michele, Saleh, Gabriele, Shinde, Dipak V., Zappia, Marilena Isabella, Brescia, Rosaria, Prato, Mirko, De Trizio, Luca, Infante, Ivan, Bonaccorso, Francesco, Manna, Liberato
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Published: London Nature Publishing Group UK 04-08-2023
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Abstract Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm 2 . Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm 2 ) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm 2 at 1.69 V and 3.6 A/cm 2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm 2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kg H2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2–2.5/kg H2 ). Hence, the use of a small amount of Ru in cathodes (~0.04 g Ru per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals. Achieving high-efficiency alkaline water electrolyzer operating at large current densities remains a critical challenge. Here the authors report Ru nanoparticle-perturbed Cu nanoplatelets as cathode for hydrogen evolution reaction coupled with stainless steel anode in alkaline electrolyzer with high performance, long-term stability and relatively low-capital expenditures.
AbstractList Abstract Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm2. Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm2) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm2 at 1.69 V and 3.6 A/cm2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kgH2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2–2.5/kgH2). Hence, the use of a small amount of Ru in cathodes (~0.04 gRu per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals.
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm . Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm ) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm at 1.69 V and 3.6 A/cm at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm for over 300 h) and intermittent modes. A total production cost of US$2.09/kg is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2-2.5/kg ). Hence, the use of a small amount of Ru in cathodes (~0.04 g per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals.
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm2. Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm2) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm2 at 1.69 V and 3.6 A/cm2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kgH2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2-2.5/kgH2). Hence, the use of a small amount of Ru in cathodes (~0.04 gRu per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals.
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm 2 . Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm 2 ) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm 2 at 1.69 V and 3.6 A/cm 2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm 2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kg H2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2–2.5/kg H2 ). Hence, the use of a small amount of Ru in cathodes (~0.04 g Ru per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals. Achieving high-efficiency alkaline water electrolyzer operating at large current densities remains a critical challenge. Here the authors report Ru nanoparticle-perturbed Cu nanoplatelets as cathode for hydrogen evolution reaction coupled with stainless steel anode in alkaline electrolyzer with high performance, long-term stability and relatively low-capital expenditures.
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm2. Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm2) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm2 at 1.69 V and 3.6 A/cm2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kgH2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2–2.5/kgH2). Hence, the use of a small amount of Ru in cathodes (~0.04 gRu per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals.Achieving high-efficiency alkaline water electrolyzer operating at large current densities remains a critical challenge. Here the authors report Ru nanoparticle-perturbed Cu nanoplatelets as cathode for hydrogen evolution reaction coupled with stainless steel anode in alkaline electrolyzer with high performance, long-term stability and relatively low-capital expenditures.
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm 2 . Here, we design a cost-effective and robust cathode, consisting of electrodeposited Ru nanoparticles (mass loading ~ 53 µg/cm 2 ) on vertically oriented Cu nanoplatelet arrays grown on metallic meshes. Such cathode is coupled with an anode based on stacked stainless steel meshes, which outperform NiFe hydroxide catalysts. Our electrolyzers exhibit current densities as high as 1 A/cm 2 at 1.69 V and 3.6 A/cm 2 at 2 V, reaching the performances of proton-exchange membrane electrolyzers. Also, our electrolyzers stably operate in continuous (1 A/cm 2 for over 300 h) and intermittent modes. A total production cost of US$2.09/kg H2 is foreseen for a 1 MW plant (30-year lifetime) based on the proposed electrode technology, meeting the worldwide targets (US$2–2.5/kg H2 ). Hence, the use of a small amount of Ru in cathodes (~0.04 g Ru per kW) is a promising strategy to solve the dichotomy between the capital and operational expenditures of conventional alkaline electrolyzers for high-throughput operation, while facing the scarcity issues of Pt-group metals.
ArticleNumber 4680
Author Bellani, Sebastiano
Prato, Mirko
Saleh, Gabriele
Shinde, Dipak V.
Zappia, Marilena Isabella
Infante, Ivan
Zuo, Yong
Bonaccorso, Francesco
Brescia, Rosaria
De Trizio, Luca
Ferri, Michele
Manna, Liberato
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/37542064$$D View this record in MEDLINE/PubMed
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crossref_primary_10_1038_s41467_023_40319_5
pubmed_primary_37542064
springer_journals_10_1038_s41467_023_40319_5
PublicationCentury 2000
PublicationDate 2023-08-04
PublicationDateYYYYMMDD 2023-08-04
PublicationDate_xml – month: 08
  year: 2023
  text: 2023-08-04
  day: 04
PublicationDecade 2020
PublicationPlace London
PublicationPlace_xml – name: London
– name: England
PublicationTitle Nature communications
PublicationTitleAbbrev Nat Commun
PublicationTitleAlternate Nat Commun
PublicationYear 2023
Publisher Nature Publishing Group UK
Nature Publishing Group
Nature Portfolio
Publisher_xml – name: Nature Publishing Group UK
– name: Nature Publishing Group
– name: Nature Portfolio
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Snippet Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm 2 . Here, we design a cost-effective and robust cathode, consisting of...
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm . Here, we design a cost-effective and robust cathode, consisting of...
Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm2. Here, we design a cost-effective and robust cathode, consisting of...
Abstract Alkaline electrolyzers generally produce hydrogen at current densities below 0.5 A/cm2. Here, we design a cost-effective and robust cathode,...
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SubjectTerms 119/118
140/146
147/135
147/137
147/143
639/301/299
639/4077
639/638/77/886
Alkaline water
Capital expenditures
Catalysts
Cathodes
Copper
Current density
Expenditures
Humanities and Social Sciences
Hydrogen evolution reactions
Iron compounds
Metals
multidisciplinary
Nanoparticles
Nickel compounds
Platelets (materials)
Production costs
Ruthenium
Science
Science (multidisciplinary)
Stainless steel
Stainless steels
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Title High-performance alkaline water electrolyzers based on Ru-perturbed Cu nanoplatelets cathode
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