New Approaches to the Synthesis and Stabilization of Polymer Microspheres with a Narrow Size Distribution

This article presents the results of investigations on heterophase polymerization of vinyl monomers in the presence of organosilicon compounds of different structures. On the basis of the detailed study of the kinetic and topochemical regularities of the heterophase polymerization of vinyl monomers,...

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Published in:	Polymers Vol. 15; no. 11; p. 2464
Main Authors:	Gritskova, Inessa A, Prokopov, Nikolay I, Ezhova, Anna A, Chalykh, Anatoly E, Gusev, Sergey A, Levachev, Sergey M, Zubov, Vitaly P, Gomzyak, Vitaly I, Skopintsev, Ivan V, Stuzhuk, Alexander N, Kovtun, Ivan D, Shulgin, Anton M, Ivashkevich, Dmitry S, Romanenko, German A, Lakhtin, Valentin G, Chvalun, Sergei N
Format:	Journal Article
Language:	English
Published:	Switzerland MDPI AG 26-05-2023 MDPI
Subjects:	Analysis Chemical synthesis Emulsion polymerization Identification and classification Methods Microemulsions Microspheres Monomers Neutrophils Organosilicon compounds Particle size distribution polymeric microspheres Polymerization Polymers Polyvinyl alcohol Review stabilization Structure surfactant Surfactants Russia stabilization surfactant polymeric microspheres
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Abstract	This article presents the results of investigations on heterophase polymerization of vinyl monomers in the presence of organosilicon compounds of different structures. On the basis of the detailed study of the kinetic and topochemical regularities of the heterophase polymerization of vinyl monomers, the conditions for the synthesis of polymer suspensions with a narrow particle-size distribution using a one-step method have been determined.
AbstractList	This article presents the results of investigations on heterophase polymerization of vinyl monomers in the presence of organosilicon compounds of different structures. On the basis of the detailed study of the kinetic and topochemical regularities of the heterophase polymerization of vinyl monomers, the conditions for the synthesis of polymer suspensions with a narrow particle-size distribution using a one-step method have been determined.
Audience	Academic
Author	Ezhova, Anna A Chalykh, Anatoly E Chvalun, Sergei N Zubov, Vitaly P Ivashkevich, Dmitry S Gritskova, Inessa A Levachev, Sergey M Shulgin, Anton M Romanenko, German A Gomzyak, Vitaly I Kovtun, Ivan D Skopintsev, Ivan V Lakhtin, Valentin G Stuzhuk, Alexander N Gusev, Sergey A Prokopov, Nikolay I
AuthorAffiliation	6 National Research Centre “Kurchatov Institute”, Akademika Kurchatova pl. 1, 123182 Moscow, Russia 5 Faculty of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, 119991 Moscow, Russia 7 Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia 4 Federal State Autonomous Educational Institution of Higher Education “Pirogov Russian National Research Medical University”, Ministry of Health of the Russian Federation, Ostrovitjanova St. 1, 117997 Moscow, Russia 2 Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS), Leninskiy Prospekt 31, 119071 Moscow, Russia 1 Department of Chemistry and Technology of Macromolecular Compounds, MIREA—Russian Technological University (RTU MIREA), 119454 Moscow, Russia 3 Federal Research and Clinical Center of Physical-Chemical Medicine of Federal Medical Biological Agency, Malaya Pirogovskaya 1a, 119435 Moscow, Russia
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Author_xml	– sequence: 1 givenname: Inessa A surname: Gritskova fullname: Gritskova, Inessa A organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 2 givenname: Nikolay I orcidid: 0000-0001-6552-1462 surname: Prokopov fullname: Prokopov, Nikolay I organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 3 givenname: Anna A surname: Ezhova fullname: Ezhova, Anna A organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 4 givenname: Anatoly E orcidid: 0000-0003-3272-2086 surname: Chalykh fullname: Chalykh, Anatoly E organization: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences (IPCE RAS), Leninskiy Prospekt 31, 119071 Moscow, Russia – sequence: 5 givenname: Sergey A surname: Gusev fullname: Gusev, Sergey A organization: Federal State Autonomous Educational Institution of Higher Education "Pirogov Russian National Research Medical University", Ministry of Health of the Russian Federation, Ostrovitjanova St. 1, 117997 Moscow, Russia – sequence: 6 givenname: Sergey M surname: Levachev fullname: Levachev, Sergey M organization: Faculty of Chemistry, Lomonosov Moscow State University, GSP-1, 1-3 Leninskiye Gory, 119991 Moscow, Russia – sequence: 7 givenname: Vitaly P surname: Zubov fullname: Zubov, Vitaly P organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 8 givenname: Vitaly I orcidid: 0000-0001-7468-1062 surname: Gomzyak fullname: Gomzyak, Vitaly I organization: National Research Centre "Kurchatov Institute", Akademika Kurchatova pl. 1, 123182 Moscow, Russia – sequence: 9 givenname: Ivan V surname: Skopintsev fullname: Skopintsev, Ivan V organization: Federal State Autonomous Educational Institution of Higher Education "Pirogov Russian National Research Medical University", Ministry of Health of the Russian Federation, Ostrovitjanova St. 1, 117997 Moscow, Russia – sequence: 10 givenname: Alexander N surname: Stuzhuk fullname: Stuzhuk, Alexander N organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 11 givenname: Ivan D surname: Kovtun fullname: Kovtun, Ivan D organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 12 givenname: Anton M surname: Shulgin fullname: Shulgin, Anton M organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 13 givenname: Dmitry S orcidid: 0009-0009-7693-8509 surname: Ivashkevich fullname: Ivashkevich, Dmitry S organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 14 givenname: German A surname: Romanenko fullname: Romanenko, German A organization: Department of Chemistry and Technology of Macromolecular Compounds, MIREA-Russian Technological University (RTU MIREA), 119454 Moscow, Russia – sequence: 15 givenname: Valentin G surname: Lakhtin fullname: Lakhtin, Valentin G organization: Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky Prospect, 119991 Moscow, Russia – sequence: 16 givenname: Sergei N orcidid: 0000-0001-9405-4509 surname: Chvalun fullname: Chvalun, Sergei N organization: National Research Centre "Kurchatov Institute", Akademika Kurchatova pl. 1, 123182 Moscow, Russia
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Cites_doi	10.1021/la061265f 10.1016/j.progpolymsci.2006.02.001 10.1063/1.1746951 10.1002/0470856424 10.1002/pol.1985.170230409 10.1007/978-94-011-5512-0 10.1016/S0032-3861(00)00765-5 10.1002/app.1991.070490010 10.1146/annurev.pc.43.100192.001231 10.1063/1.1724062 10.1002/hlca.19760590825 10.1007/978-1-4684-1920-7 10.1021/j150538a008 10.1080/00222337308061162 10.1002/macp.200290083 10.1021/ie960361g 10.1002/(SICI)1097-4628(19980103)67:1<71::AID-APP8>3.0.CO;2-L 10.1063/1.1724054 10.1021/ja01180a058 10.1201/9781315371177 10.1021/ma00024a032 10.1080/10601329708011048 10.1021/la800349q 10.1002/pol.1973.170111224 10.1134/S0965545X07030017 10.1016/j.polymer.2007.01.015 10.1002/bip.1969.360080514 10.1021/ie048827f 10.1007/s11172-019-2668-z 10.1016/S1383-7303(01)80001-6 10.1016/0021-9797(69)90216-1 10.1002/pi.4980100304 10.1016/0166-6622(92)80242-T 10.1002/3527602100 10.1007/BF01499486 10.5254/1.3534976 10.1038/174365a0 10.1021/ie50705a006
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Snippet	This article presents the results of investigations on heterophase polymerization of vinyl monomers in the presence of organosilicon compounds of different...
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SubjectTerms	Analysis Chemical synthesis Emulsion polymerization Identification and classification Methods Microemulsions Microspheres Monomers Neutrophils Organosilicon compounds Particle size distribution polymeric microspheres Polymerization Polymers Polyvinyl alcohol Review stabilization Structure surfactant Surfactants
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Title	New Approaches to the Synthesis and Stabilization of Polymer Microspheres with a Narrow Size Distribution
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