Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization
Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged bet...
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| Published in: | Polymer testing Vol. 32; no. 4; pp. 665 - 672 |
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| Main Authors: | , , , , , |
| Format: | Journal Article |
| Language: | English |
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01-06-2013
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| Abstract | Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. |
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| AbstractList | Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m3, depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. Viscoelastic polyurethane (PU) foams based on modified tung oil, ethylene glycol and polymeric MDI, and reinforced with rice husk ash (RHA), were prepared by a free-rise pouring method and characterized in terms of density, compression and dynamic mechanical behavior. The density of foams ranged between 50 and 90 kg/m(3), depending on the position of the sample with respect to the foam rise direction and filler content. As revealed by dynamic mechanical tests, the foams exhibited two different and broad thermal transitions, the temperature of their maxima depending on filler concentration. Compression modulus, compressive strength and storage modulus increase as foam density increases but decreases as rice husk ash concentration increases due to the detrimental changes induced by the filler in the foam cellular structure. However, densification strain exhibits the opposite behavior, indicating that reinforced foams can sustain slightly higher deformations without collapsing, probably due to a reduced reactivity of the components induced by the filler. |
| Author | Coelho da Silva, Mercês Stefani, Pablo M. Yoshida, Maria Irene Mosiewicki, Mirna A. Marcovich, Norma E. Ribeiro da Silva, Virginia |
| Author_xml | – sequence: 1 givenname: Virginia surname: Ribeiro da Silva fullname: Ribeiro da Silva, Virginia organization: Universidade Federal de Minas Gerais, Belo Horizonte, MG 31270-901, Brazil – sequence: 2 givenname: Mirna A. surname: Mosiewicki fullname: Mosiewicki, Mirna A. organization: Institute of Materials Science and Technology (INTEMA), University of Mar del Plata, National Research Council (CONICET), Juan B. Justo 4302, Mar del Plata 7600, Argentina – sequence: 3 givenname: Maria Irene surname: Yoshida fullname: Yoshida, Maria Irene organization: Universidade Federal de Minas Gerais, Belo Horizonte, MG 31270-901, Brazil – sequence: 4 givenname: Mercês surname: Coelho da Silva fullname: Coelho da Silva, Mercês organization: Universidade Federal de Itajubá, Campus Itabira, Itabira, MG 35900-373, Brazil – sequence: 5 givenname: Pablo M. surname: Stefani fullname: Stefani, Pablo M. organization: Institute of Materials Science and Technology (INTEMA), University of Mar del Plata, National Research Council (CONICET), Juan B. Justo 4302, Mar del Plata 7600, Argentina – sequence: 6 givenname: Norma E. surname: Marcovich fullname: Marcovich, Norma E. email: marcovic@fi.mdp.edu.ar organization: Institute of Materials Science and Technology (INTEMA), University of Mar del Plata, National Research Council (CONICET), Juan B. Justo 4302, Mar del Plata 7600, Argentina |
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| Keywords | Tung oil Mechanical properties Polyurethane foam Cell structure Storage modulus Thermal transition Vegetable oil Dispersion reinforced material Compressive strength Experimental study Cellular plastic Rice by product Polyaddition Dynamic mechanical properties Polyurethane Concentration effect Crosslinked polymer Agricultural waste Plastics Rheological properties |
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| SubjectTerms | Applied sciences Ashes Cellular Composites Compressive strength Density Dynamics Exact sciences and technology Fillers Foams Forms of application and semi-finished materials Mechanical properties Polymer industry, paints, wood Polyurethane foam Rice Technology of polymers Tung oil |
| Title | Polyurethane foams based on modified tung oil and reinforced with rice husk ash II: Mechanical characterization |
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