Sorption of Reactive blue 19 onto freshwater algae and seaweed
The potential of freshwater algae (Spirulina platensis) and seaweed (Gracilaria edulis) for removing reactive blue 19 (RB 19) were investigated using batch adsorption techniques. The effects of various experimental parameters (Solution pH, initial dye concentration, contact time, adsorbent dosage, a...
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| Published in: | Desalination and water treatment Vol. 54; no. 9; pp. 2611 - 2624 |
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| Abstract | The potential of freshwater algae (Spirulina platensis) and seaweed (Gracilaria edulis) for removing reactive blue 19 (RB 19) were investigated using batch adsorption techniques. The effects of various experimental parameters (Solution pH, initial dye concentration, contact time, adsorbent dosage, agitation speed, particle size and temperature) have been evaluated and optimal experimental conditions were ascertained. The biomass exhibited maximum dye uptake at acidic pH (pH = 1.5) due to electrostatic interactions between the biomass and the dye particles. Several isotherm models like, Langmuir, Freundlich, Dubinin–Radushkevich and Temkin adsorption isotherms were employed to monitor the adsorption behaviour. The pseudo-first-order model, pseudo-second-order kinetic model, Elovich model and intra-particle diffusion models were applied to the adsorption dynamic data. Pseudo-second-order fitted well in line with experimental data. Temkin adsorption isotherm best suited the adsorption data over the entire range of concentrations compared to other models. |
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| AbstractList | The potential of freshwater algae (Spirulina platensis) and seaweed (Gracilaria edulis) for removing reactive blue 19 (RB 19) were investigated using batch adsorption techniques. The effects of various experimental parameters (Solution pH, initial dye concentration, contact time, adsorbent dosage, agitation speed, particle size and temperature) have been evaluated and optimal experimental conditions were ascertained. The biomass exhibited maximum dye uptake at acidic pH (pH = 1.5) due to electrostatic interactions between the biomass and the dye particles. Several isotherm models like, Langmuir, Freundlich, Dubinin–Radushkevich and Temkin adsorption isotherms were employed to monitor the adsorption behaviour. The pseudo-first-order model, pseudo-second-order kinetic model, Elovich model and intra-particle diffusion models were applied to the adsorption dynamic data. Pseudo-second-order fitted well in line with experimental data. Temkin adsorption isotherm best suited the adsorption data over the entire range of concentrations compared to other models. |
| Author | Murugappan, A. Devi, S. Rajesh Kannan, R. |
| Author_xml | – sequence: 1 givenname: S. surname: Devi fullname: Devi, S. email: degisvinicivil2002@yahoo.co.in organization: Department of Civil Engineering, Annamalai University, Annamalai Nagar, 608 002, Tamil Nadu, India, Tel. +91 94864 20682 – sequence: 2 givenname: A. surname: Murugappan fullname: Murugappan, A. organization: Department of Civil Engineering, Annamalai University, Annamalai Nagar, 608 002, Tamil Nadu, India, Tel. +91 94864 20682 – sequence: 3 givenname: R. surname: Rajesh Kannan fullname: Rajesh Kannan, R. organization: Environmental Engineering Laboratory, Department of Chemical Engineering, Annamalai University, Annamalai Nagar, 608 002, Tamil Nadu, India |
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| Cites_doi | 10.1016/j.jcis.2009.08.021 10.1016/j.cej.2011.05.107 10.4491/eer.2012.17.3.125 10.1016/S1001-0742(09)60250-3 10.1016/S0960-8524(96)00113-7 10.1016/S0923-0467(98)00076-1 10.1016/j.biortech.2011.10.038 10.1016/j.biortech.2006.05.025 10.1016/j.apsusc.2009.12.134 10.1016/j.jhazmat.2006.06.095 10.1097/00010694-198408000-00004 10.1016/j.jcis.2004.04.022 10.1016/S0141-0229(02)00110-2 10.1016/j.cej.2009.04.051 10.1021/ja02268a002 10.1016/S0926-3373(99)00037-5 10.2136/sssaj1980.03615995004400020013x 10.1205/095758298529696 10.1007/s11783-010-0006-7 10.1016/j.jhazmat.2006.08.027 10.1016/j.jenvman.2010.05.003 10.1016/j.crci.2007.04.005 |
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| Keywords | Reactive blue 19 Isotherm Seaweed Biosorption Kinetics Freshwater algae |
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| SubjectTerms | Adsorption Algae Biomass Biosorption Dyes Freshwater algae Gracilaria edulis Isotherm Isotherms Kinetics Mathematical models Reactive blue 19 Seaweed Seaweeds Spirulina platensis |
| Title | Sorption of Reactive blue 19 onto freshwater algae and seaweed |
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