Preparation of Nano-films by in situ Polymerization of Hydrogen-bonded Macroclusters of N-isopropylacrylamide on Silica Surfaces

Preparation of Nano-films by in situ Polymerization of Hydrogen-bonded Macroclusters of N-isopropylacrylamide on Silica Surfaces

The in situ photopolymerization hydrogen-bonded molecular macroclusters of N-isopropylacrylamide (NIPAAm) formed on silica surfaces in chloroform was performed for generating polymeric nano-films. The ATR–FTIR spectra showed that the structure of NIPAAm underwent a transformation from trans- to cis-...

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Published in:Chemistry letters Vol. 34; no. 2; pp. 228 - 229
Main Authors: Zhong, Guolun, Mizukami, Masashi, Fukuchi, Isao, Miyahara, Takashi, Kurihara, Kazue
Format: Journal Article
Language:English
Published: Tokyo The Chemical Society of Japan 05-02-2005
Chemical Society of Japan
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Abstract The in situ photopolymerization hydrogen-bonded molecular macroclusters of N-isopropylacrylamide (NIPAAm) formed on silica surfaces in chloroform was performed for generating polymeric nano-films. The ATR–FTIR spectra showed that the structure of NIPAAm underwent a transformation from trans- to cis-stereoisomer during polymerization. Changes in the contact angle at temperatures below and above the lower critical solution temperature (LCST) were observed at 35° and 62°, respectively.
AbstractList The in situ photopolymerization hydrogen-bonded molecular macroclusters of N-isopropylacrylamide (NIPAAm) formed on silica surfaces in chloroform was performed for generating polymeric nano-films. The ATR-FTIR spectra showed that the structure of NIPAAm underwent a transformation from trans- to cis-stereoisomer during polymerization. Changes in the contact angle at temperatures below and above the lower critical solution temperature (LCST) were observed at 35° and 62°, respectively.
Author Mizukami, Masashi
Kurihara, Kazue
Fukuchi, Isao
Miyahara, Takashi
Zhong, Guolun
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  organization: 1 Institute of Multidisciplinary Research for Advanced Materials, Tohoku University
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Snippet The in situ photopolymerization hydrogen-bonded molecular macroclusters of N-isopropylacrylamide (NIPAAm) formed on silica surfaces in chloroform was performed...
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Title Preparation of Nano-films by in situ Polymerization of Hydrogen-bonded Macroclusters of N-isopropylacrylamide on Silica Surfaces
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