Grafting of alginates on UF/NF ceramic membranes for wastewater treatment

• Published in: Journal of hazardous materials Vol. 182; no. 1; pp. 611 - 623
• Main Authors: Athanasekou, C.P., Romanos, G.E., Kordatos, K., Kasselouri-Rigopoulou, V., Kakizis, N.K., Sapalidis, A.A.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier B.V 15-10-2010; Elsevier
• Subjects: Acidic regeneration; Adsorption; Alginates; Alginates - chemistry; Applied sciences; Binding; Ceramics; Chemical engineering; Crosslinking; Exact sciences and technology; Filtration; General purification processes; Grafting; Liquid-liquid and fluid-solid mechanical separations; Membrane separation (reverse osmosis, dialysis...); Membranes; Membranes, Artificial; Metal retention; Metals, Heavy - isolation & purification; Microscopy, Electron, Scanning; Pollution; Regeneration; Silanes; Solvents; UF/NF membranes; Wastewater treatment; Wastewaters; Water Pollutants, Chemical - isolation & purification; Water treatment and pollution; Silanes; UF/NF membranes; Acidic regeneration; Alginates; Grafting; Metal retention; Filtration; Stability; Induction; Stabilization; Waste treatment; Metal ion; Crossflow; Retention; Heavy metal; Membrane separation; Nanofiltration; Binding capacity; Ultrafiltration; Adsorption; Waste water purification; Ceramic materials; Inorganic membrane
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2010.06.076

The mechanism of heavy metal ion removal in processes involving multi-layered tubular ultrafiltration and nanofiltration (UF/NF) membranes was investigated by conducting retention experiments in both flow-through and cross-flow modes. The prospect of the regeneration of the membranes through an acidic process was also examined and discussed. The UF/NF membranes were functionalised with alginates to develop hybrid inorganic/organic materials for continuous, single pass, wastewater treatment applications. The challenge laid in the induction of additional metal adsorption and improved regeneration capacity. This was accomplished by stabilizing alginates either into the pores or on the top-separating layer of the membrane. The preservation of efficient water fluxes at moderate trans-membrane pressures introduced an additional parameter that was pursued in parallel to the membrane modification process. The deposition and stabilization of alginates was carried out via physical (filtration/cross-linking) and chemical (grafting) procedures. The materials developed by means of the filtration process exhibited a 25–60% enhancement of their Cd
2+ binding capacity, depending on the amount of the filtered alginate solution. The grafting process led to the development of alginate layers with adequate stability under acidic regeneration conditions and metal retention enhancement of 25–180%, depending on the silane involved as grafting agent and the solvent of silanisation.