Miscibility studies on a copolyester of bisphenol-A with terephthalic and isophthalic acids/bisphenol-A polycarbonate blends

The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was studied in dilute chloroform solutions at 25°C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined fro...

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Published in:	Journal of applied polymer science Vol. 117; no. 1; pp. 309 - 314
Main Authors:	Sakar, Dolunay, Cakar, Fatih, Cankurtaran, Ozlem, Karaman, Ferdane
Format:	Journal Article
Language:	English
Published:	Hoboken Wiley Subscription Services, Inc., A Wiley Company 05-07-2010 Wiley
Subjects:	Applied sciences bisphenol- a polycarbonate blends Differential scanning calorimetry Exact sciences and technology Fourier transforms Infrared spectroscopy Miscibility Organic polymers Physicochemistry of polymers Polyarylate Polycarbonates Polymer blends Properties and characterization Solution and gel properties Viscosity Walls Isophthalate polymer Polymer blends Property composition relationship Intrinsic viscosity Ester polymer Experimental study Terephthalate polymer Organic solution Bisphenol A viscosity Dilute solution Miscibility Specific viscosity Thermodynamic properties Polycarbonate bisphenol- a polycarbonate blends Interaction parameter Rheological properties Polyarylate
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Abstract	The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was studied in dilute chloroform solutions at 25°C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters Δb, Δb′, (Δb)G, Δ[η], α, and β were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy.
AbstractList	The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was studied in dilute chloroform solutions at 25[deg]C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters [Delta]b, [Delta]b', ([Delta]b) super()G [Delta][[eta]], alpha, and beta were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy. 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 The miscibility behavior of the blends of a copolyester of bisphenol‐A with terephthalic and isophthalic acids (PAr) and a bisphenol‐A polycarbonate (PC) was studied in dilute chloroform solutions at 25°C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters Δb, Δb′, (Δb)G, Δ[η], α, and β were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 The miscibility behavior of the blends of a copolyester of bisphenol‐A with terephthalic and isophthalic acids (PAr) and a bisphenol‐A polycarbonate (PC) was studied in dilute chloroform solutions at 25°C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters Δ b , Δ b ′, (Δ b ) G , Δ[η], α, and β were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was studied in dilute chloroform solutions at 25°C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters Δb, Δb′, (Δb)G, Δ[η], α, and β were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy. The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was studied in dilute chloroform solutions at 25 degree C. The intrinsic viscosity and Huggins' parameter of the binary mixtures were determined from the intercept and slope of the linear straight line between specific viscosity and the overall polymer concentration at the studied compositions. From experimental results of the intrinsic viscosities of the mixtures, some miscibility parameters Delta b, Delta b', ( Delta b)G, Delta [ eta ], , and beta were obtained by applying the criteria proposed by the research groups Krigbaum and Wall, Catsiff and Hewett, Garcia et al., Sun et al. and Jiang and Han, respectively. The miscibility of mixtures was also studied by using differential scanning calorimetry and fourier transform infrared spectroscopy. [copy 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
Author	Karaman, Ferdane Cankurtaran, Ozlem Sakar, Dolunay Cakar, Fatih
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Keywords	Isophthalate polymer Polymer blends Property composition relationship Intrinsic viscosity Ester polymer Experimental study Terephthalate polymer Organic solution Bisphenol A viscosity Dilute solution Miscibility Specific viscosity Thermodynamic properties Polycarbonate bisphenol- a polycarbonate blends Interaction parameter Rheological properties Polyarylate
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Snippet	The miscibility behavior of the blends of a copolyester of bisphenol-A with terephthalic and isophthalic acids (PAr) and a bisphenol-A polycarbonate (PC) was... The miscibility behavior of the blends of a copolyester of bisphenol‐A with terephthalic and isophthalic acids (PAr) and a bisphenol‐A polycarbonate (PC) was...
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SubjectTerms	Applied sciences bisphenol- a polycarbonate blends Differential scanning calorimetry Exact sciences and technology Fourier transforms Infrared spectroscopy Miscibility Organic polymers Physicochemistry of polymers Polyarylate Polycarbonates Polymer blends Properties and characterization Solution and gel properties Viscosity Walls
Title	Miscibility studies on a copolyester of bisphenol-A with terephthalic and isophthalic acids/bisphenol-A polycarbonate blends
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