Remarkably Diastereoselective Synthesis of a Chiral Biphenyl Diphosphine Ligand and Its Application in Asymmetric Hydrogenation

Essentially complete atropdiastereoselectivity was realized in the preparation of biaryl diphosphine dioxide by asymmetric intramolecular Ullmann coupling and oxidative coupling with central-to-axial chirality transfer. A bridged C2-symmetric biphenyl phosphine ligand possessing additional chiral ce...

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Bibliographic Details

Published in:	Proceedings of the National Academy of Sciences - PNAS Vol. 101; no. 16; pp. 5815 - 5820
Main Authors:	Qiu, Liqin, Wu, Jing, Chan, Shusun, Terry T.-L. Au-Yeung, Ji, Jian-Xin, Guo, Rongwei, Pai, Cheng-Chao, Zhou, Zhongyuan, Li, Xingshu, Fan, Qing-Hua, Albert S. C. Chan, Halpern, Jack
Format:	Journal Article
Language:	English
Published:	United States National Academy of Sciences 20-04-2004 National Acad Sciences
Series:	Asymmetric Catalysis Special Feature Part II
Subjects:	Acetates Asymmetric Catalysis Special Feature Part II Chirality Dioxides Hydrogenation Ligands Lithium Organic chemistry Phosphines Physical Sciences Room temperature Solvents Tetrahedrons
Online Access:	Get full text
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