Fine-Tuning the Electronic Properties of Binuclear Bis(terpyridyl)ruthenium(II) Complexes

Vastly improved photophysical properties of terminal RuII terpyridine‐based chromophores is achieved by insertion of an ethynylene group between the terpyridine ligand and a covalently linked aromatic nucleus. In the case where the aromatic nucleus possesses vacant coordination sites, as shown in 1,...

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Published in:	Angewandte Chemie International Edition Vol. 37; no. 12; pp. 1717 - 1720
Main Authors:	Hissler, Muriel, El-ghayoury, Abdelkrim, Harriman, Anthony, Ziessel, Raymond
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag GmbH 03-07-1998 WILEY‐VCH Verlag GmbH
Subjects:	Coordination modes Luminescence Molecular electronics Photochemistry Ruthenium Molecular electronics Ruthenium Coordination modes Luminescence Photochemistry
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Abstract	Vastly improved photophysical properties of terminal RuII terpyridine‐based chromophores is achieved by insertion of an ethynylene group between the terpyridine ligand and a covalently linked aromatic nucleus. In the case where the aromatic nucleus possesses vacant coordination sites, as shown in 1, complexation of certain cations (e. g., Zn2+, Cd2+, or Ba2+) at the central unit gives a further improvement in the photoproperties due to a better blending of the respective LUMO levels.
AbstractList	Vastly improved photophysical properties of terminal RuII terpyridine-based chromophores is achieved by insertion of an ethynylene group between the terpyridine ligand and a covalently linked aromatic nucleus. In the case where the aromatic nucleus possesses vacant coordination sites, as shown in 1, complexation of certain cations (e. g., Zn2+ , Cd2+ , or Ba2+ ) at the central unit gives a further improvement in the photoproperties due to a better blending of the respective LUMO levels. Vastly improved photophysical properties of terminal Ru terpyridine-based chromophores is achieved by insertion of an ethynylene group between the terpyridine ligand and a covalently linked aromatic nucleus. In the case where the aromatic nucleus possesses vacant coordination sites, as shown in 1, complexation of certain cations (e. g., Zn , Cd , or Ba ) at the central unit gives a further improvement in the photoproperties due to a better blending of the respective LUMO levels.
Author	Ziessel, Raymond Hissler, Muriel Harriman, Anthony El-ghayoury, Abdelkrim
Author_xml	– sequence: 1 givenname: Muriel surname: Hissler fullname: Hissler, Muriel organization: Laboratoire de Chimie, d'Electronique et Photonique Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur, 1, rue Blaise Pascal, F-67008 Strasbourg Cedex (France), Fax: (+33) 388-41-68-25 – sequence: 2 givenname: Abdelkrim surname: El-ghayoury fullname: El-ghayoury, Abdelkrim organization: Laboratoire de Chimie, d'Electronique et Photonique Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur, 1, rue Blaise Pascal, F-67008 Strasbourg Cedex (France), Fax: (+33) 388-41-68-25 – sequence: 3 givenname: Anthony surname: Harriman fullname: Harriman, Anthony email: harriman@chimie.u-strasbg.fr organization: Laboratoire de Chimie, d'Electronique et Photonique Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur, 1, rue Blaise Pascal, F-67008 Strasbourg Cedex (France), Fax: (+33) 388-41-68-25 – sequence: 4 givenname: Raymond surname: Ziessel fullname: Ziessel, Raymond organization: Laboratoire de Chimie, d'Electronique et Photonique Moléculaires, Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Université Louis Pasteur, 1, rue Blaise Pascal, F-67008 Strasbourg Cedex (France), Fax: (+33) 388-41-68-25
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SubjectTerms	Coordination modes Luminescence Molecular electronics Photochemistry Ruthenium
Title	Fine-Tuning the Electronic Properties of Binuclear Bis(terpyridyl)ruthenium(II) Complexes
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