Parallels in Cation and Anion Coordination: A New Class of Cascade Complexes

Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion‐based cascade complex, which mimics the analogous transition‐metal cascade complexes with these ligands.

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 41; no. 13; pp. 2335 - 2338
Main Authors:	Hossain, Md. Alamgir, Llinares, José M., Mason, Susan, Morehouse, Paula, Powell, Douglas, Bowman-James, Kristin
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag GmbH 03-07-2002 WILEY‐VCH Verlag GmbH
Subjects:	anions bridging ligands cascade complex cryptands macrocyclic ligands
Online Access:	Get full text
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Description
Summary:	Two fluoride ions in a single azacryptand: The two fluoride ions are bridged by a water molecule (see structure) to give an anion‐based cascade complex, which mimics the analogous transition‐metal cascade complexes with these ligands.
Bibliography:	ark:/67375/WNG-3FJ69ZFQ-P This research was sponsored by the Environmental Management Science Program, Offices of Science and Environmental Management, U.S. Department of Energy under Grant DE-FG-96ER62307. istex:280675DC8680279BA844F053F80F533F998F92F8 ArticleID:ANIE2335 This research was sponsored by the Environmental Management Science Program, Offices of Science and Environmental Management, U.S. Department of Energy under Grant DE‐FG‐96ER62307. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1433-7851 1521-3773
DOI:	10.1002/1521-3773(20020703)41:13<2335::AID-ANIE2335>3.0.CO;2-3