Catalytic activity of titania polymorphs towards desorption reaction of MgH2
Hydrogen desorption properties of MgH2 ball milled with two different TiO2 polymorphs, rutile and anatase, were studied. Structural characterization has been done by X-ray diffraction (XRD) analysis, particle size analysis (PSD) and scanning electron microscopy (SEM). The mechanism of desorption and...
Saved in:
| Published in: | International journal of hydrogen energy Vol. 41; no. 8; pp. 4703 - 4711 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier Ltd
02-03-2016
|
| Subjects: | |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Abstract | Hydrogen desorption properties of MgH2 ball milled with two different TiO2 polymorphs, rutile and anatase, were studied. Structural characterization has been done by X-ray diffraction (XRD) analysis, particle size analysis (PSD) and scanning electron microscopy (SEM). The mechanism of desorption and the apparent activation energy for desorption were investigated by applying isoconversional kinetic analysis of DTA spectra, while desorbed species were followed by TPD coupled with mass spectroscopy. It has been demonstrate that the addition of rutile TiO2 significantly decrease the apparent activation energy for desorption (Edesa), while addition of anatase titania has negligible influence on Edesa. Such behaviour could be explained in terms of the same crystal structure of rutile TiO2 and MgH2. Further, the mechanism of desorption changes from Avrami–Erofeev n = 3 for pure MgH2 to Avrami–Erofeev n = 4 for composite materials.
•Effect of different TiO2 phases on H desorption from MgH2–TiO2 composite is studied.•Addition of rutile notably reduce the apparent activation energy for desorption.•Such behaviour is due to the same crystal structure of rutile TiO2 and MgH2. |
|---|---|
| AbstractList | Hydrogen desorption properties of MgH2 ball milled with two different TiO2 polymorphs, rutile and anatase, were studied. Structural characterization has been done by X-ray diffraction (XRD) analysis, particle size analysis (PSD) and scanning electron microscopy (SEM). The mechanism of desorption and the apparent activation energy for desorption were investigated by applying isoconversional kinetic analysis of DTA spectra, while desorbed species were followed by TPD coupled with mass spectroscopy. It has been demonstrate that the addition of rutile TiO2 significantly decrease the apparent activation energy for desorption (Edesa), while addition of anatase titania has negligible influence on Edesa. Such behaviour could be explained in terms of the same crystal structure of rutile TiO2 and MgH2. Further, the mechanism of desorption changes from Avrami–Erofeev n = 3 for pure MgH2 to Avrami–Erofeev n = 4 for composite materials.
•Effect of different TiO2 phases on H desorption from MgH2–TiO2 composite is studied.•Addition of rutile notably reduce the apparent activation energy for desorption.•Such behaviour is due to the same crystal structure of rutile TiO2 and MgH2. |
| Author | Matović, Ljiljana Kurko, Sandra Novaković, Nikola Novaković, Jasmina Grbović Mraković, Ana Milošević, Sanja Vujasin, Radojka |
| Author_xml | – sequence: 1 givenname: Radojka surname: Vujasin fullname: Vujasin, Radojka – sequence: 2 givenname: Ana surname: Mraković fullname: Mraković, Ana – sequence: 3 givenname: Sandra surname: Kurko fullname: Kurko, Sandra – sequence: 4 givenname: Nikola surname: Novaković fullname: Novaković, Nikola – sequence: 5 givenname: Ljiljana surname: Matović fullname: Matović, Ljiljana – sequence: 6 givenname: Jasmina Grbović surname: Novaković fullname: Novaković, Jasmina Grbović email: jasnag@vinca.rs – sequence: 7 givenname: Sanja surname: Milošević fullname: Milošević, Sanja |
| BookMark | eNqFkNtKAzEQhoNUsK2-guwL7Dqzm91N7pTiCSre6HVIk6lNaTclCZV9e1Oq18LAHOD7Gb4Zmwx-IMZuESoE7O62ldtuRksDVXXeK8AKZHvBpih6WTZc9BM2haaDskEpr9gsxi0A9sDllC0XOundmJwptEnu6NJY-HWRXNKD08XB78a9D4dNLJL_1sHGwlLMh-T8UAQ6MXnIxNvXS33NLtd6F-nmt8_Z59Pjx-KlXL4_vy4elqXhok2lRuSIskbe9Zw3WmKuGnoAS6RFQx1JUWvRrkhYIw3nKPmqabteCpRgmznrzrkm-BgDrdUhuL0Oo0JQJydqq_6cqJMTBaiykwzen0HK3x0dBRWNo8GQdYFMUta7_yJ-AHbzb-w |
| CitedBy_id | crossref_primary_10_1590_1980_5373_mr_2018_0821 crossref_primary_10_1016_j_cej_2022_136059 crossref_primary_10_3390_hydrogen4030034 crossref_primary_10_1016_j_ijhydene_2016_07_170 crossref_primary_10_1016_j_ijhydene_2019_03_258 crossref_primary_10_1016_j_mtchem_2020_100340 crossref_primary_10_1002_cphc_201801125 crossref_primary_10_1016_j_rineng_2022_100737 crossref_primary_10_1039_C7DT04665K crossref_primary_10_1016_j_nanoen_2023_108536 crossref_primary_10_1016_j_jallcom_2017_03_361 crossref_primary_10_1016_j_jma_2020_04_002 |
| Cites_doi | 10.1016/S0925-8388(03)00530-9 10.1016/S0167-5729(02)00100-0 10.1016/j.jmatprotec.2007.01.040 10.1016/j.jallcom.2011.12.008 10.1007/s10853-010-5113-0 10.1039/B912964B 10.1016/j.ceramint.2012.05.091 10.1140/epjb/e2005-00023-9 10.1016/j.jallcom.2005.09.085 10.1016/j.carbon.2012.12.091 10.1016/j.jallcom.2009.07.042 10.1166/jnn.2013.7516 10.1016/j.ijhydene.2009.01.068 10.1016/j.ijhydene.2013.04.040 10.1016/j.ijhydene.2010.07.022 10.1016/j.electacta.2008.09.025 10.1016/S0925-8388(00)01284-6 10.1016/j.ijhydene.2013.06.083 10.1016/j.ceramint.2011.08.047 10.1016/j.jallcom.2005.08.084 10.1016/j.ceramint.2012.11.029 10.1016/j.jallcom.2006.10.134 10.1016/j.ijhydene.2006.10.068 10.1016/S0925-8388(00)01188-9 10.1007/s10853-011-6203-3 10.1016/S0925-8388(99)00628-3 10.1016/j.apsusc.2005.04.018 10.1016/j.jallcom.2009.10.199 10.1016/S0925-8388(99)00474-0 10.1016/j.cattod.2006.09.028 10.1038/35104634 10.1016/S0925-8388(01)01173-2 10.3390/cryst2030845 10.1021/jp0541563 |
| ContentType | Journal Article |
| Copyright | 2016 Hydrogen Energy Publications, LLC. |
| Copyright_xml | – notice: 2016 Hydrogen Energy Publications, LLC. |
| DBID | AAYXX CITATION |
| DOI | 10.1016/j.ijhydene.2016.01.095 |
| DatabaseName | CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering |
| EISSN | 1879-3487 |
| EndPage | 4711 |
| ExternalDocumentID | 10_1016_j_ijhydene_2016_01_095 S0360319915309460 |
| GroupedDBID | --K --M .~1 0R~ 1B1 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAHCO AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARJD AARLI AAXUO ABFNM ABJNI ABMAC ABYKQ ACDAQ ACGFS ACRLP ADBBV ADECG ADEZE AEBSH AEKER AENEX AEZYN AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHIDL AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BELTK BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG EJD EO8 EO9 EP2 EP3 F5P FDB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HZ~ IHE J1W JARJE KOM LY6 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SCC SDF SDG SES SPC SPCBC SSK SSM SSR SSZ T5K TN5 XPP ZMT ~G- 29J AAQXK AAXKI AAYXX ABXDB ACNNM ADMUD AFJKZ AKRWK ASPBG AVWKF AZFZN CITATION FEDTE FGOYB G-2 HVGLF R2- SAC SCB SEW T9H WUQ |
| ID | FETCH-LOGICAL-c485t-a11411921467443a91a9120700deea83e6e982a85be8dc9c44194b356798190d3 |
| ISSN | 0360-3199 |
| IngestDate | Thu Sep 26 15:49:02 EDT 2024 Fri Feb 23 02:26:37 EST 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 8 |
| Keywords | MgH2 TiO2 polymorphs Catalytic properties Composites Hydrogen storage |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c485t-a11411921467443a91a9120700deea83e6e982a85be8dc9c44194b356798190d3 |
| PageCount | 9 |
| ParticipantIDs | crossref_primary_10_1016_j_ijhydene_2016_01_095 elsevier_sciencedirect_doi_10_1016_j_ijhydene_2016_01_095 |
| PublicationCentury | 2000 |
| PublicationDate | 2016-03-02 |
| PublicationDateYYYYMMDD | 2016-03-02 |
| PublicationDate_xml | – month: 03 year: 2016 text: 2016-03-02 day: 02 |
| PublicationDecade | 2010 |
| PublicationTitle | International journal of hydrogen energy |
| PublicationYear | 2016 |
| Publisher | Elsevier Ltd |
| Publisher_xml | – name: Elsevier Ltd |
| References | Oelerich, Klassen, Bormann (bib10) 2001; 315 Pandey, Bhatnagar, Shahi, Hudson, Singh, Srivastava (bib18) 2013; 13 Milanović, Milošević, Rašković-Lovre, Novaković, Vujasin, Matović (bib36) 2013; 39 Milošević, Milanović, Paskaš Mamula, Ðukić, Rajnović, Pasquini (bib32) 2013; 38 Kubota, Miyaoka, Tsubota, Shimoda, Ichikawa, Kojima (bib22) 2013; 56 Diebold (bib25) 2003; 48 Varin, Czujko, Wronski (bib27) 2009 Kurko, Rašković, Novaković, Paskaš Mamula, Jovanović, Baščarević (bib20) 2011; 36 Hanada, Ichikawa, Hino, Fujii (bib40) 2006; 420 Varin, Czujko, Wasmund, Wronski (bib8) 2007; 446–7 Yu, Zhang, Zhao, Will, Liu (bib15) 2009; 54 Rodríguez-Carvajal J, Fullprof program manual Polanski, Bystrzycki (bib24) 2009; 486 Lj, Kurko, Rašković-Lovre Ž, Milanović, Milošević, Grbović Novaković (bib29) 2012; 37 Yamasaki, Miyazawa, Ohyanagi, Munir (bib39) 2012; 47 Croston, Grant, Walker (bib17) 2010; 492 Giusepponi, Celino (bib38) 2012; 2 Bobet, Even, Nakamura, Akiba, Darriet (bib6) 2000; 298 Barkhordarian, Klassen, Bormann (bib14) 2004; 364 Jung, Kim, Lee, Lee (bib16) 2007; 120 Matthews (bib31) 1976; 61 Andreasen (bib5) 2005 Sadhasivam, Sterlin Leo Hudson, Pandey, Bhatnagar, Singh, Gurunathan (bib3) 2013; 38 Aguey-Zinsou, Ares Fernandez, Klassen, Bormann (bib11) 2007; 32 Gu, Zhu, Li (bib13) 2009; 34 Leardini, Ares, Bodega, Fernandez, Ferrer, Sanchez (bib35) 2010; 12 Hanaor, Sorrell (bib33) 2011; 46 Barkhordarian, Klassen, Bormann (bib21) 2006; B110 Wang, Wang, Zhang, Ding, Hu (bib23) 2000; 313 Milošević, Rašković-Lovre, Kurko, Vujasin, Cvjetićanin, Matović (bib2) 2013; 39 Bassetti, Bonetti, Pasquini, Montone, Grbovic, Antisari (bib4) 2005; 43 . Jung, Lee, Lee (bib9) 2006; 421 Gulicovski, Rašković-Lovre, Kurko, Vujasin, Jovanović, Matović (bib19) 2012; 38 Schlapbach, Zuttel (bib1) 2001; 414 Huot, Liang, Boily, Van Nete, Schulz (bib37) 1999; 293–295 Baricco, Rahman, Livraghi, Castellero, Enzo, Giamello (bib12) 2012; 536 Friedrichs, Sánchez-López, López-Cartés, Dornheim, Klassen, Bormann (bib30) 2006; 252 Galwey, Brown (bib34) 1999 Oelerich, Klassen, Bormann (bib7) 2001; 322 Mahshid, Askari, Ghamsari (bib26) 2007; 189 Milošević (10.1016/j.ijhydene.2016.01.095_bib2) 2013; 39 Sadhasivam (10.1016/j.ijhydene.2016.01.095_bib3) 2013; 38 Jung (10.1016/j.ijhydene.2016.01.095_bib16) 2007; 120 Hanaor (10.1016/j.ijhydene.2016.01.095_bib33) 2011; 46 Barkhordarian (10.1016/j.ijhydene.2016.01.095_bib14) 2004; 364 Varin (10.1016/j.ijhydene.2016.01.095_bib8) 2007; 446–7 Yamasaki (10.1016/j.ijhydene.2016.01.095_bib39) 2012; 47 Milošević (10.1016/j.ijhydene.2016.01.095_bib32) 2013; 38 Wang (10.1016/j.ijhydene.2016.01.095_bib23) 2000; 313 Croston (10.1016/j.ijhydene.2016.01.095_bib17) 2010; 492 Matthews (10.1016/j.ijhydene.2016.01.095_bib31) 1976; 61 Kubota (10.1016/j.ijhydene.2016.01.095_bib22) 2013; 56 Bobet (10.1016/j.ijhydene.2016.01.095_bib6) 2000; 298 Huot (10.1016/j.ijhydene.2016.01.095_bib37) 1999; 293–295 Giusepponi (10.1016/j.ijhydene.2016.01.095_bib38) 2012; 2 Hanada (10.1016/j.ijhydene.2016.01.095_bib40) 2006; 420 Galwey (10.1016/j.ijhydene.2016.01.095_bib34) 1999 Gulicovski (10.1016/j.ijhydene.2016.01.095_bib19) 2012; 38 Oelerich (10.1016/j.ijhydene.2016.01.095_bib7) 2001; 322 Varin (10.1016/j.ijhydene.2016.01.095_bib27) 2009 Bassetti (10.1016/j.ijhydene.2016.01.095_bib4) 2005; 43 Jung (10.1016/j.ijhydene.2016.01.095_bib9) 2006; 421 Polanski (10.1016/j.ijhydene.2016.01.095_bib24) 2009; 486 Mahshid (10.1016/j.ijhydene.2016.01.095_bib26) 2007; 189 Milanović (10.1016/j.ijhydene.2016.01.095_bib36) 2013; 39 Aguey-Zinsou (10.1016/j.ijhydene.2016.01.095_bib11) 2007; 32 Lj (10.1016/j.ijhydene.2016.01.095_bib29) 2012; 37 Friedrichs (10.1016/j.ijhydene.2016.01.095_bib30) 2006; 252 Baricco (10.1016/j.ijhydene.2016.01.095_bib12) 2012; 536 10.1016/j.ijhydene.2016.01.095_bib28 Leardini (10.1016/j.ijhydene.2016.01.095_bib35) 2010; 12 Pandey (10.1016/j.ijhydene.2016.01.095_bib18) 2013; 13 Kurko (10.1016/j.ijhydene.2016.01.095_bib20) 2011; 36 Yu (10.1016/j.ijhydene.2016.01.095_bib15) 2009; 54 Andreasen (10.1016/j.ijhydene.2016.01.095_bib5) 2005 Gu (10.1016/j.ijhydene.2016.01.095_bib13) 2009; 34 Diebold (10.1016/j.ijhydene.2016.01.095_bib25) 2003; 48 Barkhordarian (10.1016/j.ijhydene.2016.01.095_bib21) 2006; B110 Oelerich (10.1016/j.ijhydene.2016.01.095_bib10) 2001; 315 Schlapbach (10.1016/j.ijhydene.2016.01.095_bib1) 2001; 414 |
| References_xml | – year: 2005 ident: bib5 article-title: Hydrogen storage materials with focus on main group I-II elements contributor: fullname: Andreasen – volume: 39 start-page: 4399 year: 2013 end-page: 4405 ident: bib36 article-title: Microstructure and hydrogen storage properties of MgH publication-title: Ceram Int contributor: fullname: Matović – volume: 43 start-page: 19 year: 2005 end-page: 27 ident: bib4 article-title: Hydrogen desorption from ball milled MgH publication-title: Eur Phys J B contributor: fullname: Antisari – volume: 322 start-page: L5 year: 2001 end-page: L9 ident: bib7 article-title: Comparison of the catalytic effects of V, V publication-title: J Alloys Compd contributor: fullname: Bormann – volume: 420 start-page: 46 year: 2006 end-page: 49 ident: bib40 article-title: Remarkable improvement of hydrogen sorption kinetics in magnesium catalyzed with Nb publication-title: J Alloys Compd contributor: fullname: Fujii – volume: 32 start-page: 2400 year: 2007 end-page: 2407 ident: bib11 article-title: Effect of Nb publication-title: Int J Hydrogen Energy contributor: fullname: Bormann – volume: 38 start-page: 12223 year: 2013 end-page: 12229 ident: bib32 article-title: Hydrogen desorption properties of MgH publication-title: Int J Hydrogen Energy contributor: fullname: Pasquini – volume: 37 start-page: 6727 year: 2012 end-page: 6732 ident: bib29 article-title: Assessment of changes in desorption mechanism of MgH publication-title: Int J Hydrogen Energy contributor: fullname: Grbović Novaković – volume: 38 start-page: 7353 year: 2013 end-page: 7362 ident: bib3 article-title: Effects of nano size mischmetal and its oxide on improving the hydrogen sorption behaviour of MgH publication-title: Int J Hydrogen Energy contributor: fullname: Gurunathan – year: 2009 ident: bib27 article-title: Nanomaterials for solid state hydrogen storage contributor: fullname: Wronski – volume: 2 start-page: 845 year: 2012 end-page: 860 ident: bib38 article-title: Hydrogen desorption from Mg hydride: an Ab initio study publication-title: Crystals contributor: fullname: Celino – volume: 293–295 start-page: 495 year: 1999 end-page: 500 ident: bib37 article-title: Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride publication-title: J Alloys Compd contributor: fullname: Schulz – volume: 446–7 start-page: 63 year: 2007 end-page: 66 ident: bib8 article-title: Hydrogen desorption properties of MgH publication-title: J Alloys Compd contributor: fullname: Wronski – volume: 46 start-page: 855 year: 2011 end-page: 874 ident: bib33 article-title: Review of the anatase to rutile phase transformation publication-title: J Mater Sci contributor: fullname: Sorrell – volume: 486 start-page: 697 year: 2009 end-page: 701 ident: bib24 article-title: Comparative studies of the influence of different nano-sized metal oxides on the hydrogen sorption properties of magnesium hydride publication-title: J Alloys Compd contributor: fullname: Bystrzycki – volume: 189 start-page: 296 year: 2007 end-page: 300 ident: bib26 article-title: Synthesis of TiO publication-title: J Mater Process Technol contributor: fullname: Ghamsari – volume: 120 start-page: 270 year: 2007 end-page: 275 ident: bib16 article-title: Hydrogen sorption of magnesium hydride doped with nano-sized TiO publication-title: Catal Today contributor: fullname: Lee – volume: 13 start-page: 5493 year: 2013 end-page: 5499 ident: bib18 article-title: Effect of TiO publication-title: J Nanosci Nanotechnol contributor: fullname: Srivastava – volume: 313 start-page: 218 year: 2000 end-page: 223 ident: bib23 article-title: Hydrogenation characteristics of Mg–TiO publication-title: J Alloys Compd contributor: fullname: Hu – volume: 492 start-page: 251 year: 2010 end-page: 258 ident: bib17 article-title: The catalytic effect of titanium oxide based additives on the dehydrogenation and hydrogenation of milled MgH publication-title: J Alloys Compd contributor: fullname: Walker – volume: 34 start-page: 2654 year: 2009 end-page: 2660 ident: bib13 article-title: Hydrogen storage properties of Mg–Ni–Cu prepared by hydriding combustion synthesis and mechanical milling (HCS + MM) publication-title: Int J Hydrogen Energy contributor: fullname: Li – volume: 252 start-page: 2334 year: 2006 end-page: 2345 ident: bib30 article-title: Chemical and microstructural study of the oxygen passivation behaviour of nanocrystalline Mg and MgH publication-title: Appl Surf Sci contributor: fullname: Bormann – volume: 54 start-page: 1319 year: 2009 end-page: 1324 ident: bib15 article-title: An efficient and low-cost TiO publication-title: Electrochim Acta contributor: fullname: Liu – year: 1999 ident: bib34 article-title: Thermal decomposition of ionic solids contributor: fullname: Brown – volume: 414 start-page: 353 year: 2001 end-page: 358 ident: bib1 article-title: Hydrogen-storage materials for mobile applications publication-title: Nature contributor: fullname: Zuttel – volume: 298 start-page: 279 year: 2000 end-page: 284 ident: bib6 article-title: Synthesis of magnesium and titanium hydride via reactive mechanical alloying. Influence of 3d-metal addition on MgH publication-title: J Alloys Compd contributor: fullname: Darriet – volume: 48 start-page: 53 year: 2003 end-page: 229 ident: bib25 article-title: The surface science of tiutanium dioxide publication-title: Surf Sci Rep contributor: fullname: Diebold – volume: 536 start-page: S216 year: 2012 end-page: S221 ident: bib12 article-title: Effects of BaRuO publication-title: J Alloys Compd contributor: fullname: Giamello – volume: 364 start-page: 242 year: 2004 end-page: 246 ident: bib14 article-title: Effect of Nb publication-title: J Alloys Compd contributor: fullname: Bormann – volume: 47 start-page: 3577 year: 2012 end-page: 3584 ident: bib39 article-title: Accelerated hydrogen desorption from MgH publication-title: J Mater Sci contributor: fullname: Munir – volume: 421 start-page: 179 year: 2006 end-page: 184 ident: bib9 article-title: Catalytic effects of metal oxide on hydrogen absorption of magnesium metal hydride publication-title: J Alloys Compd contributor: fullname: Lee – volume: 38 start-page: 1181 year: 2012 end-page: 1186 ident: bib19 article-title: Influence of vacant CeO publication-title: Ceram Int contributor: fullname: Matović – volume: B110 start-page: 11020 year: 2006 end-page: 11024 ident: bib21 article-title: Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction publication-title: J Phys Chem contributor: fullname: Bormann – volume: 56 start-page: 50 year: 2013 end-page: 55 ident: bib22 article-title: Synthesis and characterization of magnesium–carbon compounds for hydrogen storage publication-title: Carbon contributor: fullname: Kojima – volume: 61 start-page: 419 year: 1976 end-page: 424 ident: bib31 article-title: The crystallization of anatese and rutile from amorphous titanium dioxide under hydrothermal conditions publication-title: Am Mineral contributor: fullname: Matthews – volume: 39 start-page: 51 year: 2013 end-page: 56 ident: bib2 article-title: Influence of VO publication-title: Ceram Int contributor: fullname: Matović – volume: 36 start-page: 549 year: 2011 end-page: 554 ident: bib20 article-title: Hydrogen storage properties of MgH publication-title: Int J Hydrogen Energy contributor: fullname: Baščarević – volume: 12 start-page: 572 year: 2010 end-page: 577 ident: bib35 article-title: Reaction pathways for hydrogen desorption from magnesium hydride/hydroxide composites: bulk and interface effects publication-title: Phys Chem Chem Phys contributor: fullname: Sanchez – volume: 315 start-page: 237 year: 2001 end-page: 242 ident: bib10 article-title: Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials publication-title: J Alloys Compd contributor: fullname: Bormann – volume: 364 start-page: 242 year: 2004 ident: 10.1016/j.ijhydene.2016.01.095_bib14 article-title: Effect of Nb2O5 content on hydrogen reaction kinetics of Mg publication-title: J Alloys Compd doi: 10.1016/S0925-8388(03)00530-9 contributor: fullname: Barkhordarian – volume: 48 start-page: 53 year: 2003 ident: 10.1016/j.ijhydene.2016.01.095_bib25 article-title: The surface science of tiutanium dioxide publication-title: Surf Sci Rep doi: 10.1016/S0167-5729(02)00100-0 contributor: fullname: Diebold – volume: 189 start-page: 296 year: 2007 ident: 10.1016/j.ijhydene.2016.01.095_bib26 article-title: Synthesis of TiO2 nanoparticles by hydrolysis and peptization of titanium isopropoxide solution publication-title: J Mater Process Technol doi: 10.1016/j.jmatprotec.2007.01.040 contributor: fullname: Mahshid – volume: 536 start-page: S216 year: 2012 ident: 10.1016/j.ijhydene.2016.01.095_bib12 article-title: Effects of BaRuO3 addition on hydrogen desorption in MgH2 publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2011.12.008 contributor: fullname: Baricco – volume: 37 start-page: 6727 issue: 22 year: 2012 ident: 10.1016/j.ijhydene.2016.01.095_bib29 article-title: Assessment of changes in desorption mechanism of MgH2 after ion bombardment induced destabilization publication-title: Int J Hydrogen Energy contributor: fullname: Lj – volume: 46 start-page: 855 year: 2011 ident: 10.1016/j.ijhydene.2016.01.095_bib33 article-title: Review of the anatase to rutile phase transformation publication-title: J Mater Sci doi: 10.1007/s10853-010-5113-0 contributor: fullname: Hanaor – volume: 12 start-page: 572 year: 2010 ident: 10.1016/j.ijhydene.2016.01.095_bib35 article-title: Reaction pathways for hydrogen desorption from magnesium hydride/hydroxide composites: bulk and interface effects publication-title: Phys Chem Chem Phys doi: 10.1039/B912964B contributor: fullname: Leardini – volume: 39 start-page: 51 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib2 article-title: Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride publication-title: Ceram Int doi: 10.1016/j.ceramint.2012.05.091 contributor: fullname: Milošević – volume: 43 start-page: 19 year: 2005 ident: 10.1016/j.ijhydene.2016.01.095_bib4 article-title: Hydrogen desorption from ball milled MgH2 catalyzed with Fe publication-title: Eur Phys J B doi: 10.1140/epjb/e2005-00023-9 contributor: fullname: Bassetti – volume: 421 start-page: 179 year: 2006 ident: 10.1016/j.ijhydene.2016.01.095_bib9 article-title: Catalytic effects of metal oxide on hydrogen absorption of magnesium metal hydride publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2005.09.085 contributor: fullname: Jung – ident: 10.1016/j.ijhydene.2016.01.095_bib28 – volume: 56 start-page: 50 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib22 article-title: Synthesis and characterization of magnesium–carbon compounds for hydrogen storage publication-title: Carbon doi: 10.1016/j.carbon.2012.12.091 contributor: fullname: Kubota – volume: 486 start-page: 697 year: 2009 ident: 10.1016/j.ijhydene.2016.01.095_bib24 article-title: Comparative studies of the influence of different nano-sized metal oxides on the hydrogen sorption properties of magnesium hydride publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2009.07.042 contributor: fullname: Polanski – volume: 13 start-page: 5493 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib18 article-title: Effect of TiO2 nanoparticles on the hydrogen sorption characteristics of magnesium hydride publication-title: J Nanosci Nanotechnol doi: 10.1166/jnn.2013.7516 contributor: fullname: Pandey – volume: 34 start-page: 2654 year: 2009 ident: 10.1016/j.ijhydene.2016.01.095_bib13 article-title: Hydrogen storage properties of Mg–Ni–Cu prepared by hydriding combustion synthesis and mechanical milling (HCS + MM) publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2009.01.068 contributor: fullname: Gu – volume: 38 start-page: 7353 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib3 article-title: Effects of nano size mischmetal and its oxide on improving the hydrogen sorption behaviour of MgH2 publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2013.04.040 contributor: fullname: Sadhasivam – volume: 36 start-page: 549 year: 2011 ident: 10.1016/j.ijhydene.2016.01.095_bib20 article-title: Hydrogen storage properties of MgH2 mechanically milled with α and β SiC publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2010.07.022 contributor: fullname: Kurko – volume: 54 start-page: 1319 issue: 4 year: 2009 ident: 10.1016/j.ijhydene.2016.01.095_bib15 article-title: An efficient and low-cost TiO2 compact layer for performance improvement of dye-sensitized solar cells publication-title: Electrochim Acta doi: 10.1016/j.electacta.2008.09.025 contributor: fullname: Yu – volume: 315 start-page: 237 year: 2001 ident: 10.1016/j.ijhydene.2016.01.095_bib10 article-title: Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials publication-title: J Alloys Compd doi: 10.1016/S0925-8388(00)01284-6 contributor: fullname: Oelerich – volume: 38 start-page: 12223 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib32 article-title: Hydrogen desorption properties of MgH2 catalysed with NaNH2 publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2013.06.083 contributor: fullname: Milošević – volume: 38 start-page: 1181 issue: 2 year: 2012 ident: 10.1016/j.ijhydene.2016.01.095_bib19 article-title: Influence of vacant CeO2 nanostructured ceramics on MgH2 hydrogen desorption properties publication-title: Ceram Int doi: 10.1016/j.ceramint.2011.08.047 contributor: fullname: Gulicovski – year: 1999 ident: 10.1016/j.ijhydene.2016.01.095_bib34 contributor: fullname: Galwey – volume: 420 start-page: 46 year: 2006 ident: 10.1016/j.ijhydene.2016.01.095_bib40 article-title: Remarkable improvement of hydrogen sorption kinetics in magnesium catalyzed with Nb2O5 publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2005.08.084 contributor: fullname: Hanada – volume: 39 start-page: 4399 year: 2013 ident: 10.1016/j.ijhydene.2016.01.095_bib36 article-title: Microstructure and hydrogen storage properties of MgH2–TiB2–SiC composites publication-title: Ceram Int doi: 10.1016/j.ceramint.2012.11.029 contributor: fullname: Milanović – volume: 446–7 start-page: 63 year: 2007 ident: 10.1016/j.ijhydene.2016.01.095_bib8 article-title: Hydrogen desorption properties of MgH2 nanocomposites with nano-oxides and Inco micrometric- and nanometric-Ni publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2006.10.134 contributor: fullname: Varin – volume: 32 start-page: 2400 year: 2007 ident: 10.1016/j.ijhydene.2016.01.095_bib11 article-title: Effect of Nb2O5 on MgH2 properties during mechanical milling publication-title: Int J Hydrogen Energy doi: 10.1016/j.ijhydene.2006.10.068 contributor: fullname: Aguey-Zinsou – volume: 313 start-page: 218 year: 2000 ident: 10.1016/j.ijhydene.2016.01.095_bib23 article-title: Hydrogenation characteristics of Mg–TiO2 (rutile) composite publication-title: J Alloys Compd doi: 10.1016/S0925-8388(00)01188-9 contributor: fullname: Wang – volume: 47 start-page: 3577 year: 2012 ident: 10.1016/j.ijhydene.2016.01.095_bib39 article-title: Accelerated hydrogen desorption from MgH2 by high-energy ball-milling with Al2O3 publication-title: J Mater Sci doi: 10.1007/s10853-011-6203-3 contributor: fullname: Yamasaki – volume: 298 start-page: 279 year: 2000 ident: 10.1016/j.ijhydene.2016.01.095_bib6 article-title: Synthesis of magnesium and titanium hydride via reactive mechanical alloying. Influence of 3d-metal addition on MgH2 synthesize publication-title: J Alloys Compd doi: 10.1016/S0925-8388(99)00628-3 contributor: fullname: Bobet – volume: 61 start-page: 419 year: 1976 ident: 10.1016/j.ijhydene.2016.01.095_bib31 article-title: The crystallization of anatese and rutile from amorphous titanium dioxide under hydrothermal conditions publication-title: Am Mineral contributor: fullname: Matthews – volume: 252 start-page: 2334 year: 2006 ident: 10.1016/j.ijhydene.2016.01.095_bib30 article-title: Chemical and microstructural study of the oxygen passivation behaviour of nanocrystalline Mg and MgH2 publication-title: Appl Surf Sci doi: 10.1016/j.apsusc.2005.04.018 contributor: fullname: Friedrichs – volume: 492 start-page: 251 year: 2010 ident: 10.1016/j.ijhydene.2016.01.095_bib17 article-title: The catalytic effect of titanium oxide based additives on the dehydrogenation and hydrogenation of milled MgH2 publication-title: J Alloys Compd doi: 10.1016/j.jallcom.2009.10.199 contributor: fullname: Croston – volume: 293–295 start-page: 495 year: 1999 ident: 10.1016/j.ijhydene.2016.01.095_bib37 article-title: Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride publication-title: J Alloys Compd doi: 10.1016/S0925-8388(99)00474-0 contributor: fullname: Huot – volume: 120 start-page: 270 year: 2007 ident: 10.1016/j.ijhydene.2016.01.095_bib16 article-title: Hydrogen sorption of magnesium hydride doped with nano-sized TiO2 publication-title: Catal Today doi: 10.1016/j.cattod.2006.09.028 contributor: fullname: Jung – year: 2005 ident: 10.1016/j.ijhydene.2016.01.095_bib5 contributor: fullname: Andreasen – volume: 414 start-page: 353 year: 2001 ident: 10.1016/j.ijhydene.2016.01.095_bib1 article-title: Hydrogen-storage materials for mobile applications publication-title: Nature doi: 10.1038/35104634 contributor: fullname: Schlapbach – volume: 322 start-page: L5 year: 2001 ident: 10.1016/j.ijhydene.2016.01.095_bib7 article-title: Comparison of the catalytic effects of V, V2O5, VN, and VC on the hydrogen sorption of nanocrystalline Mg publication-title: J Alloys Compd doi: 10.1016/S0925-8388(01)01173-2 contributor: fullname: Oelerich – year: 2009 ident: 10.1016/j.ijhydene.2016.01.095_bib27 contributor: fullname: Varin – volume: 2 start-page: 845 year: 2012 ident: 10.1016/j.ijhydene.2016.01.095_bib38 article-title: Hydrogen desorption from Mg hydride: an Ab initio study publication-title: Crystals doi: 10.3390/cryst2030845 contributor: fullname: Giusepponi – volume: B110 start-page: 11020 issue: 22 year: 2006 ident: 10.1016/j.ijhydene.2016.01.095_bib21 article-title: Catalytic mechanism of transition-metal compounds on Mg hydrogen sorption reaction publication-title: J Phys Chem doi: 10.1021/jp0541563 contributor: fullname: Barkhordarian |
| SSID | ssj0017049 |
| Score | 2.3007274 |
| Snippet | Hydrogen desorption properties of MgH2 ball milled with two different TiO2 polymorphs, rutile and anatase, were studied. Structural characterization has been... |
| SourceID | crossref elsevier |
| SourceType | Aggregation Database Publisher |
| StartPage | 4703 |
| SubjectTerms | Catalytic properties Composites Hydrogen storage MgH2 TiO2 polymorphs |
| Title | Catalytic activity of titania polymorphs towards desorption reaction of MgH2 |
| URI | https://dx.doi.org/10.1016/j.ijhydene.2016.01.095 |
| Volume | 41 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://sdu.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3db9MwELe67gUeEONDjC_5gTeUkQ8nsR-nUdQN1gc20N4iJ3a2pKhB6Tpp_z13sZ2EqdJACKmKqqucpHe_-H7nnO8IeReUIhJ5XnpCFNxjgAov1zL0FOeSxyHLwy7bYn6WLi74xxmbTSau994g-6-WBhnYGnfO_oW1-5OCAL6DzeEIVofjH9n9CNdjbrsyrIXtDIFpABWQwEpiTwYI9kG3WNgBE2bX75Veg6CDARDIwjHI08t5OGauvy8djgpOXN2qtrnEZgHdNkJnwe-bWq5NgYKvUjX1sp__T1u5bG6qjsamJqmy_-3zpl02ZqV6pdpevGhu7oxZVMvmhxyvWQRJl7Q1RLj9Zpohc8ls4EKXYPolHWgzH_NUeBGzPtlO2KZSlgUmH82-LPWjkScHvxts9RJmwaI-qGpQESgHM_ySrnqrafh5pwL3Gd4Z3hh4B4iGE3-H7IYwr8VTsnt4PLs46V9bpTbecv9ktCV9-9W2s6ERwzl_TB7Z0IQeGkztkYlePSEPRwUrn5IvPbqoQxdtSmrRRQd0UYsuOqCLOnThCETXM_Lt0-z8aO7ZfhxewXh87UmInQOsn4cdalgkRQCfEHyGr7SWPNKJFjyERzzXXBWiAKYtWB7F-KIPeKeKnpPpqlnpF4QmQkGcL4JSgspKFeSJYmXCfCXiMC3LfJ98cHrJfpqyK5nLR6wzp8kMNZn5QQaa3CfCqS-z5NGQwgysfs_Yl_8w9hV5MCD8NZletxv9huys1eatRccvjJ2Vyw |
| link.rule.ids | 315,782,786,27935,27936 |
| linkProvider | Elsevier |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Catalytic+activity+of+titania+polymorphs+towards+desorption+reaction+of+MgH2&rft.jtitle=International+journal+of+hydrogen+energy&rft.au=Vujasin%2C+Radojka&rft.au=Mrakovi%C4%87%2C+Ana&rft.au=Kurko%2C+Sandra&rft.au=Novakovi%C4%87%2C+Nikola&rft.date=2016-03-02&rft.pub=Elsevier+Ltd&rft.issn=0360-3199&rft.eissn=1879-3487&rft.volume=41&rft.issue=8&rft.spage=4703&rft.epage=4711&rft_id=info:doi/10.1016%2Fj.ijhydene.2016.01.095&rft.externalDocID=S0360319915309460 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0360-3199&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0360-3199&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0360-3199&client=summon |