Benzimidazolium‐ and Benzimidazolilydene‐Capped Cyclodextrins: New Perspectives in Anion Encapsulation and Gold‐Catalyzed Cycloisomerization of 1,6‐Enynes

A new way of introducing a N‐heterocyclic carbene cap onto cyclodextrins has been devised. The benzimidazolium intermediates were found to behave as receptors towards cavity matching anions. The corresponding C1‐ and C2‐symmetrical regioisomeric carbene gold(I) complexes have been tested in a benchm...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 24; no. 68; pp. 17921 - 17926
Main Authors:	Kaya, Zeyneb, Andna, Lucile, Matt, Dominique, Bentouhami, Embarek, Djukic, Jean‐Pierre, Armspach, Dominique
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 05-12-2018 Wiley-VCH Verlag
Subjects:	Anions catalysis Chemical Sciences Chemistry Cyclodextrin Cyclodextrins Enantiomers Gold Intermediates Isomerization N-heterocyclic carbenes Receptors gold catalysis anions cyclodextrin N-heterocyclic carbenes
Online Access:	Get full text
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