Shaping in the Third Direction; Fabrication of Hemispherical Micro-Concavity Array by Using Large Size Polystyrene Spheres as Template for Direct Self-Assembly of Small Size Silica Spheres

Silica and polystyrene spheres with a small size ratio (r = 0.005) form by sequential hanging drop self-assembly, a binary colloidal crystal through which calcination transforms in a silica-ordered concavity array. These arrays are capable of light Bragg diffraction and shape dependent optical pheno...

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Bibliographic Details
Published in:Polymers Vol. 14; no. 11; p. 2158
Main Authors: Sandu, Ion, Fleaca, Claudiu Teodor, Dumitrache, Florian, Sava, Bogdan Alexandru, Urzica, Iuliana, Antohe, Iulia, Brajnicov, Simona, Dumitru, Marius
Format: Journal Article
Language:English
Published: Switzerland MDPI AG 26-05-2022
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Summary:Silica and polystyrene spheres with a small size ratio (r = 0.005) form by sequential hanging drop self-assembly, a binary colloidal crystal through which calcination transforms in a silica-ordered concavity array. These arrays are capable of light Bragg diffraction and shape dependent optical phenomena, and they can be transformed into inverse-opal structures. Hierarchical 2D and 3D super-structures with ordered concavities as structural units were fabricated in this study.
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ISSN:2073-4360
2073-4360
DOI:10.3390/polym14112158