Catalytic wet peroxide oxidation: a route towards the application of hybrid magnetic carbon nanocomposites for the degradation of organic pollutants. A review

• Published in: Applied catalysis. B, Environmental Vol. 187; pp. 428 - 460
• Main Authors: Ribeiro, Rui S., Silva, Adrián M.T., Figueiredo, José L., Faria, Joaquim L., Gomes, Helder T.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15-06-2016
• Subjects: Adsorptivity; Carbon; Carbon materials; Catalysis; Catalysts; Catalytic wet peroxide oxidation (CWPO); Heterogeneous Fenton process; Magnetic nanocomposites; Nanocomposites; Oxidation; Peroxides; Texture; Magnetic nanocomposites; Catalytic wet peroxide oxidation (CWPO); Carbon materials; Heterogeneous Fenton process
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2016.01.033

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•The application of hybrid magnetic carbon nanocomposites in CWPO is reviewed.•Synergisms arise from combining magnetic iron species with carbon-based materials.•Carbon materials promote increased adsorptive interactions and structural stability.•Surface chemistry is shown to influence the activity of carbon materials in CWPO.
Several motivations have prompted the scientific community towards the application of hybrid magnetic carbon nanocomposites in catalytic wet peroxide oxidation (CWPO) processes. The most relevant literature on this topic is reviewed, with a special focus on the synergies that can arise from the combination of highly active and magnetically separable iron species with the easily tuned properties of carbon-based materials. These are mainly ascribed to increased adsorptive interactions, to good structural stability and low leaching levels of the metal species, and to increased regeneration and dispersion of the active sites, which are promoted by the presence of the carbon-based materials in the composites.
The most significant features of carbon materials that may be further explored in the design of improved hybrid magnetic catalysts are also addressed, taking into consideration the experimental knowledge gathered by the authors in their studies and development of carbon-based catalysts for CWPO. The presence of stable metal impurities, basic active sites and sulphur-containing functionalities, as well as high specific surface area, adequate porous texture, adsorptive interactions and structural defects, are shown to increase the activity of carbon materials when applied in CWPO, while the presence of acidic oxygen-containing functionalities has the opposite effect.