Structural and fluid dynamic characterization of calcium carbonate-based porous ceramics
The aim of this work was to experimentally evaluate the use of calcium carbonate as a pore-generating agent in ceramic compositions. Compositions that contained 50% kaolin, 20% limestone, and different concentrations of quartz and feldspar were prepared by uniaxial pressing. Samples were heat-treate...
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Published in: | Materials research (São Carlos, São Paulo, Brazil) Vol. 16; no. 6; pp. 1439 - 1448 |
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Language: | English Portuguese |
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ABM, ABC, ABPol
01-12-2013
Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) |
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Abstract | The aim of this work was to experimentally evaluate the use of calcium carbonate as a pore-generating agent in ceramic compositions. Compositions that contained 50% kaolin, 20% limestone, and different concentrations of quartz and feldspar were prepared by uniaxial pressing. Samples were heat-treated at a heating rate appropriate to induce calcium carbonate degassing, and they were then sintered at 800, 900, and 1050 [degrees]C. Tests of X-ray fluorescence, thermogravimetric analysis, porosimetry, and air permeation were performed. The composition (wt%) that contained 50% kaolin, 20% limestone, 20% feldspar, and 10% quartz and heat treated at 1050 [degrees]C (k sub(1)= 1.73X10 super(-13) m super(2) and k sub(2)= 1.00x10 super(-8) m) showed the highest level of permeability among the investigated samples. Fluid dynamics simulations showed that the prepared samples would exhibit a pressure drop greater than the range desired for applications that involve the filtration of aerosols, but alternatively would be suitable as substrates for asymmetric membranes in microfiltration applications. |
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AbstractList | The aim of this work was to experimentally evaluate the use of calcium carbonate as a pore-generating agent in ceramic compositions. Compositions that contained 50% kaolin, 20% limestone, and different concentrations of quartz and feldspar were prepared by uniaxial pressing. Samples were heat-treated at a heating rate appropriate to induce calcium carbonate degassing, and they were then sintered at 800, 900, and 1050 ºC. Tests of X-ray fluorescence, thermogravimetric analysis, porosimetry, and air permeation were performed. The composition (wt%) that contained 50% kaolin, 20% limestone, 20% feldspar, and 10% quartz and heat treated at 1050 ºC (k1 = 1.73×10-13 m² and k2 = 1.00×10-8 m) showed the highest level of permeability among the investigated samples. Fluid dynamics simulations showed that the prepared samples would exhibit a pressure drop greater than the range desired for applications that involve the filtration of aerosols, but alternatively would be suitable as substrates for asymmetric membranes in microfiltration applications. The aim of this work was to experimentally evaluate the use of calcium carbonate as a pore-generating agent in ceramic compositions. Compositions that contained 50% kaolin, 20% limestone, and different concentrations of quartz and feldspar were prepared by uniaxial pressing. Samples were heat-treated at a heating rate appropriate to induce calcium carbonate degassing, and they were then sintered at 800, 900, and 1050 [degrees]C. Tests of X-ray fluorescence, thermogravimetric analysis, porosimetry, and air permeation were performed. The composition (wt%) that contained 50% kaolin, 20% limestone, 20% feldspar, and 10% quartz and heat treated at 1050 [degrees]C (k sub(1)= 1.73X10 super(-13) m super(2) and k sub(2)= 1.00x10 super(-8) m) showed the highest level of permeability among the investigated samples. Fluid dynamics simulations showed that the prepared samples would exhibit a pressure drop greater than the range desired for applications that involve the filtration of aerosols, but alternatively would be suitable as substrates for asymmetric membranes in microfiltration applications. |
Author | SIMAO, Lisandro |
AuthorAffiliation | Universidade do Extremo Sul Catarinense Universidade de Ribeirão Preto |
AuthorAffiliation_xml | – name: Universidade do Extremo Sul Catarinense – name: Universidade de Ribeirão Preto |
Author_xml | – sequence: 1 givenname: Lisandro surname: SIMAO fullname: SIMAO, Lisandro |
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CitedBy_id | crossref_primary_10_1007_s41779_023_00918_3 crossref_primary_10_1038_s41598_019_43918_9 crossref_primary_10_3390_ma10101188 crossref_primary_10_1016_j_jclepro_2021_128678 crossref_primary_10_1007_s00723_015_0701_4 crossref_primary_10_1016_j_ceramint_2014_12_031 crossref_primary_10_1016_j_jafrearsci_2019_103620 |
Cites_doi | 10.1016/S0955-2219(98)00063-6 10.1590/S1516-14392009000200014 10.1111/j.1151-2916.2000.tb01426.x 10.1021/la980871a 10.1016/S0009-2509(98)80003-1 10.1016/S0928-4931(00)00134-X 10.1007/s10934-009-9331-2 10.1016/j.sna.2010.11.013 10.1016/j.conbuildmat.2007.09.008 10.1016/j.chroma.2006.06.011 10.1590/S0366-69132003000100002 10.1111/j.1151-2916.2000.tb01677.x 10.1016/j.jeurceramsoc.2006.04.129 10.1016/j.jeurceramsoc.2010.10.009 10.1016/j.jhazmat.2008.05.025 10.1111/j.1151-2916.2002.tb00306.x 10.1590/S0366-69132002000400010 10.1016/S0009-2509(98)00175-4 10.1016/j.memsci.2011.08.003 10.1016/j.ceramint.2010.09.022 10.1111/j.1151-2916.2001.tb00772.x |
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SubjectTerms | Calcium carbonate Ceramics ENGINEERING, CHEMICAL Feldspars Fluid dynamics Heat treatment Kaolin Limestone MATERIALS SCIENCE, MULTIDISCIPLINARY METALLURGY & METALLURGICAL ENGINEERING microporous materials microstructure Quartz |
Title | Structural and fluid dynamic characterization of calcium carbonate-based porous ceramics |
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