When VSEPR Fails: Experimental and Theoretical Investigations of the Behavior of Alkaline-Earth-Metal Acetylides

The synthesis, structural, and spectral characterization as well as a theoretical study of a family of alkaline‐earth‐metal acetylides provides insights into synthetic access and the structural and bonding characteristics of this group of highly reactive compounds. Based on our earlier communication...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 15; no. 44; pp. 11842 - 11852
Main Authors:	Guino-o, Marites A., Alexander, Jacob S., McKee, Michael L., Hope, Håkon, Englich, Ulrich B., Ruhlandt-Senge, Karin
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 09-11-2009 WILEY‐VCH Verlag
Subjects:	Acetylene - chemistry acetylides alkaline earth metals Metals, Alkaline Earth - chemistry Models, Chemical Models, Molecular Molecular Conformation Organometallic Compounds - chemistry secondary interactions Spectrophotometry, Infrared structure elucidation structure-determining factors
Online Access:	Get full text
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