Photocatalyzed ortho‐Alkylation of Pyridine N‐Oxides through Alkene Cleavage

Photocatalyzed ortho‐Alkylation of Pyridine N‐Oxides through Alkene Cleavage

A photocatalyzed reaction of pyridine N‐oxides with alkenes gives ortho‐alkylated pyridines with cleavage of the carbon–carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot. Leading light: A photocatalyzed reaction of pyridine N‐oxides...

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Bibliographic Details
Published in:Angewandte Chemie International Edition Vol. 57; no. 18; pp. 5139 - 5142
Main Authors: Zhou, Wang, Miura, Tomoya, Murakami, Masahiro
Format: Journal Article
Language:English
Published: Germany Wiley Subscription Services, Inc 23-04-2018
Edition:International ed. in English
Subjects:
Alkenes
Alkylation
Carbon
Cleavage
C−C bond cleavage
ortho-alkylation
Oxides
photocatalysis
pyridine N-oxides
Pyridines
ortho-alkylation
pyridine N-oxides
C−C bond cleavage
alkenes
photocatalysis
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Summary:A photocatalyzed reaction of pyridine N‐oxides with alkenes gives ortho‐alkylated pyridines with cleavage of the carbon–carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot. Leading light: A photocatalyzed reaction of pyridine N‐oxides with alkenes gives ortho‐alkylated pyridines with cleavage of the carbon–carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot.
Bibliography:ObjectType-Article-1
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content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201801305