Synergistic Manganese(I) C−H Activation Catalysis in Continuous Flow: Chemoselective Hydroarylation

Chemoselective hydroarylations were accomplished by a novel synergistic Brønsted acid/manganese(I)‐catalyzed C−H activation manifold. Thus, alkynes bearing O‐leaving groups could, for the first time, be employed for C−H alkenylations without concurrent β‐O elimination, thereby setting the stage for...

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Bibliographic Details

Published in:	Angewandte Chemie International Edition Vol. 56; no. 47; pp. 15063 - 15067
Main Authors:	Wang, Hui, Pesciaioli, Fabio, Oliveira, João C. A., Warratz, Svenja, Ackermann, Lutz
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 20-11-2017
Edition:	International ed. in English
Subjects:	Activation Alkynes Catalysis Continuous flow C−H activation flow chemistry heterocycles Manganese reaction mechanisms reaction mechanisms C−H activation heterocycles manganese flow chemistry
Online Access:	Get full text
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